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Ammonia-fired chemically recuperated gas turbine: Thermodynamic analysis of cycle and recuperation system

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  • Pashchenko, Dmitry
  • Mustafin, Ravil
  • Karpilov, Igor

Abstract

Ammonia is one of the prospective alternatives to hydrocarbon fuels. Currently, there are projects for developing of ammonia fired gas turbines up to 40 MW. The addition of thermochemical exhaust gas heat recuperation systems to ammonia-fired gas turbines could be a promising way to increase their efficiency. In this paper, the concept of an ammonia-fired chemically recuperated gas turbine (CRGT) is thermodynamically analyzed. Gas turbine with thermochemical recuperation by ammonia decomposition is analyzed via Aspen HYSYS for a wide range of operating parameters: turbine inlet temperature of 700–1300 °C, the pressure of 6–21 bar. The thermochemical exhaust heat recuperation system is recovering the exhaust heat in a reformer (for the endothermic reaction of ammonia decomposition), a heater (to preheat ammonia to the temperature of the decomposition reaction), and a regasifier (for regasification of liquid ammonia). The thermochemical exhaust heat recuperation system makes it possible to recover up to 43% of exhaust heat. The maximum efficiency of CRGT is observed at 9 bar for Tin = 700 °C; 12 bar at Tin = 800 °C; 15 bar at Tin = 900 °C; 18 bar at Tin = 1000 °C. In the temperature range above Tin > 1000 °C, when the pressure rises above 15 bar, the efficiency does not increase significantly.

Suggested Citation

  • Pashchenko, Dmitry & Mustafin, Ravil & Karpilov, Igor, 2022. "Ammonia-fired chemically recuperated gas turbine: Thermodynamic analysis of cycle and recuperation system," Energy, Elsevier, vol. 252(C).
    • Handle: RePEc:eee:energy:v:252:y:2022:i:c:s0360544222009847
    DOI: 10.1016/j.energy.2022.124081
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    1. Rafael Estevez & Francisco J. López-Tenllado & Laura Aguado-Deblas & Felipa M. Bautista & Antonio A. Romero & Diego Luna, 2023. "Current Research on Green Ammonia (NH 3 ) as a Potential Vector Energy for Power Storage and Engine Fuels: A Review," Energies, MDPI, vol. 16(14), pages 1-33, July.
    2. Bai, Zhang & Yuan, Yu & Kong, Debin & Zhou, Shengdong & Li, Qi & Wang, Shuoshuo, 2023. "Potential of applying the thermochemical recuperation in combined cooling, heating and power generation: Off-design operation performance," Applied Energy, Elsevier, vol. 348(C).
    3. Su, Bosheng & Huang, Yupeng & Wang, Yilin & Huang, Zhi & Yuan, Shuo & Huang, Qiteng & Xu, Zhilong & Lin, Feng, 2023. "Novel ammonia-driven chemically recuperated gas turbine cycle based on dual fuel mode," Applied Energy, Elsevier, vol. 343(C).
    4. Pashchenko, Dmitry & Mustafin, Ravil & Karpilov, Igor, 2022. "Thermochemical recuperation by steam methane reforming as an efficient alternative to steam injection in the gas turbines," Energy, Elsevier, vol. 258(C).
    5. Pashchenko, Dmitry, 2023. "Hydrogen-rich gas as a fuel for the gas turbines: A pathway to lower CO2 emission," Renewable and Sustainable Energy Reviews, Elsevier, vol. 173(C).
    6. Carlos Arnaiz del Pozo & Ángel Jiménez Álvaro & Schalk Cloete & Jose Antonio García del Pozo Martín de Hijas, 2023. "The Potential of Chemically Recuperated Power Cycles in Markets with High Shares of Variable Renewables," Energies, MDPI, vol. 16(20), pages 1-22, October.
    7. Liaw, Kim Leong & Ong, Khai Chuin & Mohd Ali Zar, Muhammad Aliff B. & Lai, Wen Kang & Muhammad, M. Fadhli B. & Firmansyah, & Kurnia, Jundika C., 2023. "Experimental and numerical investigation of an innovative non-combustion impulse gas turbine for micro-scale electricity generation," Energy, Elsevier, vol. 266(C).

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