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Use of an alkaline catalyst with ethanol-water as a co-solvent in the hydrothermal liquefaction of the Korean native kenaf: An analysis of the light oil and heavy oil characteristics

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  • Kim, Seong-Ju
  • Kim, Ga-Hee
  • Um, Byung-Hwan

Abstract

Hydrothermal liquefaction of the Korean native kenaf, with ethanol–water as a co-solvent at 275–350 °C for 30 min with and without 1 wt% of the alkaline catalysts Ca(OH)2, Na2CO3, K2CO3, and KOH, was investigated to identify the effect of the alkaline catalyst addition on the characteristics of the light and heavy oil produced. Component, elemental, ICP-ASE, and GC-MS analyses were conducted to determine the characteristics of the light oil, heavy oil, and solid residue. The highest bio-crude oil yield of 61.81% at 275 °C was found using ethanol–water without an alkaline catalyst. The addition of alkaline catalysts prompted the decomposition of both the heavy oil and light oil fractions, and re-polymerization reactions were suppressed. In addition, there were increases in the area percentages of ketone and phenolics derived from holocellulose and monolignols, respectively. Calcium ion was mainly detected in the aqueous phase, while sodium and potassium existed as solids in the solid residue. The results show that the addition of a calcium-based alkaline catalyst in the hydrothermal liquefaction of kenaf can enhance the energy recovery ratio to 58% and calorific value to 32.27 MJ/kg of the light oil at 350 °C.

Suggested Citation

  • Kim, Seong-Ju & Kim, Ga-Hee & Um, Byung-Hwan, 2022. "Use of an alkaline catalyst with ethanol-water as a co-solvent in the hydrothermal liquefaction of the Korean native kenaf: An analysis of the light oil and heavy oil characteristics," Energy, Elsevier, vol. 249(C).
  • Handle: RePEc:eee:energy:v:249:y:2022:i:c:s0360544222004121
    DOI: 10.1016/j.energy.2022.123509
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    References listed on IDEAS

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    1. Kim, Seong Ju & Um, Byung Hwan, 2020. "Effect of thermochemically fractionation before hydrothermal liquefaction of herbaceous biomass on biocrude characteristics," Renewable Energy, Elsevier, vol. 160(C), pages 612-622.
    2. Tzanetis, Konstantinos F. & Posada, John A. & Ramirez, Andrea, 2017. "Analysis of biomass hydrothermal liquefaction and biocrude-oil upgrading for renewable jet fuel production: The impact of reaction conditions on production costs and GHG emissions performance," Renewable Energy, Elsevier, vol. 113(C), pages 1388-1398.
    3. Komeil Kohansal & Kamaldeep Sharma & Saqib Sohail Toor & Eliana Lozano Sanchez & Joscha Zimmermann & Lasse Aistrup Rosendahl & Thomas Helmer Pedersen, 2021. "Bio-Crude Production Improvement during Hydrothermal Liquefaction of Biopulp by Simultaneous Application of Alkali Catalysts and Aqueous Phase Recirculation," Energies, MDPI, vol. 14(15), pages 1-21, July.
    4. Tahir H. Seehar & Saqib S. Toor & Ayaz A. Shah & Thomas H. Pedersen & Lasse A. Rosendahl, 2020. "Biocrude Production from Wheat Straw at Sub and Supercritical Hydrothermal Liquefaction," Energies, MDPI, vol. 13(12), pages 1-18, June.
    5. Aghbashlo, Mortaza & Khounani, Zahra & Hosseinzadeh-Bandbafha, Homa & Gupta, Vijai Kumar & Amiri, Hamid & Lam, Su Shiung & Morosuk, Tatiana & Tabatabaei, Meisam, 2021. "Exergoenvironmental analysis of bioenergy systems: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 149(C).
    6. Brand, Steffen & Kim, Jaehoon, 2015. "Liquefaction of major lignocellulosic biomass constituents in supercritical ethanol," Energy, Elsevier, vol. 80(C), pages 64-74.
    7. Park, Hoyoung & Byun, Jaewon & Han, Jeehoon, 2021. "Economically feasible thermochemical process for methanol production from kenaf," Energy, Elsevier, vol. 230(C).
    8. Déniel, Maxime & Haarlemmer, Geert & Roubaud, Anne & Weiss-Hortala, Elsa & Fages, Jacques, 2016. "Energy valorisation of food processing residues and model compounds by hydrothermal liquefaction," Renewable and Sustainable Energy Reviews, Elsevier, vol. 54(C), pages 1632-1652.
    9. Feng, Shanghuan & Wei, Rufei & Leitch, Mathew & Xu, Chunbao Charles, 2018. "Comparative study on lignocellulose liquefaction in water, ethanol, and water/ethanol mixture: Roles of ethanol and water," Energy, Elsevier, vol. 155(C), pages 234-241.
    10. Ankit Mathanker & Snehlata Das & Deepak Pudasainee & Monir Khan & Amit Kumar & Rajender Gupta, 2021. "A Review of Hydrothermal Liquefaction of Biomass for Biofuels Production with a Special Focus on the Effect of Process Parameters, Co-Solvents, and Extraction Solvents," Energies, MDPI, vol. 14(16), pages 1-60, August.
    11. Qinglei Meng & Minqiang Hou & Huizhen Liu & Jinliang Song & Buxing Han, 2017. "Synthesis of ketones from biomass-derived feedstock," Nature Communications, Nature, vol. 8(1), pages 1-8, April.
    12. Chen, Congjin & Zhu, Jingxian & Jia, Shuang & Mi, Shuai & Tong, Zhangfa & Li, Zhixia & Li, Mingfei & Zhang, Yanjuan & Hu, Yuhua & Huang, Zuqiang, 2018. "Effect of ethanol on Mulberry bark hydrothermal liquefaction and bio-oil chemical compositions," Energy, Elsevier, vol. 162(C), pages 460-475.
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