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Effect of thermochemically fractionation before hydrothermal liquefaction of herbaceous biomass on biocrude characteristics

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  • Kim, Seong Ju
  • Um, Byung Hwan

Abstract

Hydrothermal liquefaction (HTL) of fractionated two types herbaceous biomass (kenaf and miscanthus) by dilute acid, organosolv, alkaline, or demineralization process was carried out under ethanol water co-solvent at 350 °C for 30 min to examine the biocrude yield and characteristics. The biocrude properties were comprehensively characterized by HPLC, elemental, GC-MS, and TGA analysis. Fractionation technologies before HTL effectively increased biocrude yield up to 38% compared to that of untreated herbaceous biomass (31%), except for organosolv fractionation of miscanthus, especially, HTL after alkaline fractionation showed high yield and energy recovery ratio up to 70%. Elemental analysis showed that HHV of biocrude was negatively affected by hydrolysis reaction of high lignin content after dilute acid fractionation. The GC-MS analysis revealed that carbohydrates-derived compound significantly increased in the biocrude obtained after organosolv and alkaline fractionation due to holocellulose increases through fractionation process. Additionally, TGA results indicated that the ratio of high-boiling-point compounds in biocrude obtained after demineralization was expanded compared with untreated due to ash removal, which could act as a catalyst.

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  • Kim, Seong Ju & Um, Byung Hwan, 2020. "Effect of thermochemically fractionation before hydrothermal liquefaction of herbaceous biomass on biocrude characteristics," Renewable Energy, Elsevier, vol. 160(C), pages 612-622.
    • Handle: RePEc:eee:renene:v:160:y:2020:i:c:p:612-622
    DOI: 10.1016/j.renene.2020.07.002
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    2. Kim, Seong-Ju & Kim, Ga-Hee & Um, Byung-Hwan, 2022. "Use of an alkaline catalyst with ethanol-water as a co-solvent in the hydrothermal liquefaction of the Korean native kenaf: An analysis of the light oil and heavy oil characteristics," Energy, Elsevier, vol. 249(C).
    3. Wu, Haijun & Li, Xinlong & Zhang, Quan & Zhang, Kai & Xu, Xia & Xu, Jian, 2022. "Promoting the conversion of poplar to bio-oil based on the synergistic effect of alkaline hydrogen peroxide," Renewable Energy, Elsevier, vol. 192(C), pages 107-117.
    4. Sharma, Nishesh & Jaiswal, Krishna Kumar & Kumar, Vinod & Vlaskin, Mikhail S. & Nanda, Manisha & Rautela, Indra & Tomar, Mahipal Singh & Ahmad, Waseem, 2021. "Effect of catalyst and temperature on the quality and productivity of HTL bio-oil from microalgae: A review," Renewable Energy, Elsevier, vol. 174(C), pages 810-822.
    5. Wu, Haijun & Shakeel, Usama & Zhang, Quan & Zhang, Kai & Xu, Xia & Yuan, Yamei & Xu, Jian, 2022. "Catalytic degradation of poplar by Na2CO3 and Na2CO3/Fe under various hydrothermal liquefaction processes," Energy, Elsevier, vol. 259(C).
    6. Ayala-Cortés, Alejandro & Arcelus-Arrillaga, Pedro & Millan, Marcos & Okoye, Patrick U. & Arancibia-Bulnes, Camilo A. & Pacheco-Catalán, Daniella Esperanza & Villafán-Vidales, Heidi Isabel, 2022. "Solar hydrothermal processing of agave bagasse: Insights on the effect of operational parameters," Renewable Energy, Elsevier, vol. 192(C), pages 14-23.

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