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Economically feasible thermochemical process for methanol production from kenaf

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  • Park, Hoyoung
  • Byun, Jaewon
  • Han, Jeehoon

Abstract

This paper presents a thermochemical process design and techno-economic analysis for the production of methanol (MeOH) from Kenaf cultivated in Korea. The proposed process combines three main subsystems to allow for the processing of 2000 tons of kenaf a day: kenaf-to-syngas, syngas-to-MeOH, and a combined heat and power cycle. In the first subsystem, clean syngas is produced from kenaf via a two-step carbonization and steam gasification process. The clean syngas is then catalytically upgraded to MeOH using a commercial Cu/ZnO/Al2O3 catalyst. The third subsystem allows for the generation of heat and electricity to close the energy balance by combusting the biomass residues. Energy analysis and optimization of the heat exchanger network allowed for all energy requirements to be satisfied internally, high overall energy efficiency (60.6%), and the selling of 3.3 MW of excess electricity. Furthermore, an economic feasibility analysis of the process showed that the minimum selling price of MeOH (99.9 wt%) was 0.413 US$/kgMeOH. Importantly, the process economics could be in the range of the market price with respect to incorporating different types of H2 production technology into the process.

Suggested Citation

  • Park, Hoyoung & Byun, Jaewon & Han, Jeehoon, 2021. "Economically feasible thermochemical process for methanol production from kenaf," Energy, Elsevier, vol. 230(C).
  • Handle: RePEc:eee:energy:v:230:y:2021:i:c:s0360544221009774
    DOI: 10.1016/j.energy.2021.120729
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    References listed on IDEAS

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    1. Byun, Jaewon & Han, Jeehoon, 2016. "Process synthesis and analysis for catalytic conversion of lignocellulosic biomass to fuels: Separate conversion of cellulose and hemicellulose using 2-sec-butylphenol (SBP) solvent," Applied Energy, Elsevier, vol. 171(C), pages 483-490.
    2. Ana Gonçalves & Jaime Filipe Puna & Luís Guerra & José Campos Rodrigues & João Fernando Gomes & Maria Teresa Santos & Diogo Alves, 2019. "Towards the Development of Syngas/Biomethane Electrolytic Production, Using Liquefied Biomass and Heterogeneous Catalyst," Energies, MDPI, vol. 12(19), pages 1-21, October.
    3. Zhang, Hanfei & Wang, Ligang & Pérez-Fortes, Mar & Van herle, Jan & Maréchal, François & Desideri, Umberto, 2020. "Techno-economic optimization of biomass-to-methanol with solid-oxide electrolyzer," Applied Energy, Elsevier, vol. 258(C).
    4. Kim, Juyeon & Han, Jeehoon, 2018. "Simulation study of a strategy to produce gamma-valerolactone from ethyl levulinate," Energy, Elsevier, vol. 163(C), pages 986-991.
    5. Cho, Seong-Heon & Kim, Juyeon & Han, Jeehoon & Lee, Daewon & Kim, Hyung Ju & Kim, Yong Tae & Cheng, Xun & Xu, Ye & Lee, Jechan & Kwon, Eilhann E., 2019. "Bioalcohol production from acidogenic products via a two-step process: A case study of butyric acid to butanol," Applied Energy, Elsevier, vol. 252(C), pages 1-1.
    6. Saba, N. & Jawaid, M. & Hakeem, K.R. & Paridah, M.T. & Khalina, A. & Alothman, O.Y., 2015. "Potential of bioenergy production from industrial kenaf (Hibiscus cannabinus L.) based on Malaysian perspective," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 446-459.
    7. Yi, Qun & Gong, Min-Hui & Huang, Yi & Feng, Jie & Hao, Yan-Hong & Zhang, Ji-Long & Li, Wen-Ying, 2016. "Process development of coke oven gas to methanol integrated with CO2 recycle for satisfactory techno-economic performance," Energy, Elsevier, vol. 112(C), pages 618-628.
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    Cited by:

    1. Kim, Seong-Ju & Kim, Ga-Hee & Um, Byung-Hwan, 2022. "Use of an alkaline catalyst with ethanol-water as a co-solvent in the hydrothermal liquefaction of the Korean native kenaf: An analysis of the light oil and heavy oil characteristics," Energy, Elsevier, vol. 249(C).
    2. Kim, Soosan & Byun, Jaewon & Park, Hoyoung & Lee, Nahyeon & Han, Jeehoon & Lee, Jechan, 2022. "Energy-efficient thermal waste treatment process with no CO2 emission: A case study of waste tea bag," Energy, Elsevier, vol. 241(C).
    3. Kang, Dongseong & Byun, Jaewon & Han, Jee-hoon, 2023. "Environmental impact analysis of steelmaking off-gases on methanol production," Energy, Elsevier, vol. 277(C).

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