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Optimizing the structural design of cathode catalyst layer for PEM fuel cells for improving mass-specific power density

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  • Lin, Rui
  • Wang, Hong
  • Zhu, Yu

Abstract

The design of cathode catalyst layers (CCLs) is essential for enhanced charge transfer and mass transport of proton exchange membrane fuel cells (PEMFCs). In this work, CCLs are designed to constitute the three sub-layers with different polytetrafluoroethylene (PTFE) loadings for each sub-layer. The improper addition of PTFE in the different CCL positions can increase the gas-liquid phase’s mass transfer resistance through the triple-phase boundary. Low PTFE content leads to an inefficient hydrophobic nanoparticle distribution. However, excessive PTFE causes active site losses. The high voltage loss is a common result of unsuitable PTFE content, especially within the high current density operation condition. The membrane electrode assembly (MEA) contains 10 wt% PTFE loading in the out layer (faced to the gas diffusion layer), shows the best performance. At potentials of 700 mV and 600 mV, the output current densities approach 710 and 1120 mA/cm2, respectively. Furthermore, using Electrochemical impedance spectroscopy (EIS), the effect of PTFE sub-layers position on the charging transfer impedance and the mass transfer impedance has also been analyzed in this study. It is confirmed that the performance of MEA with an appropriate PTFE gradient design is improved significantly.

Suggested Citation

  • Lin, Rui & Wang, Hong & Zhu, Yu, 2021. "Optimizing the structural design of cathode catalyst layer for PEM fuel cells for improving mass-specific power density," Energy, Elsevier, vol. 221(C).
    • Handle: RePEc:eee:energy:v:221:y:2021:i:c:s0360544221001584
    DOI: 10.1016/j.energy.2021.119909
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    1. Roudbari, Mohsen Najafi & Ojani, Reza & Raoof, Jahan Bakhsh, 2019. "Performance improvement of polymer fuel cell by simultaneously inspection of catalyst loading, catalyst content and ionomer using home-made cathodic half-cell and response surface method," Energy, Elsevier, vol. 173(C), pages 151-161.
    2. Thepkaew, Jarupuk & Therdthianwong, Apichai & Therdthianwong, Supaporn, 2008. "Key parameters of active layers affecting proton exchange membrane (PEM) fuel cell performance," Energy, Elsevier, vol. 33(12), pages 1794-1800.
    3. Afra, Mehran & Nazari, Mohsen & Kayhani, Mohammad Hasan & Sharifpur, M. & Meyer, J.P., 2019. "3D experimental visualization of water flooding in proton exchange membrane fuel cells," Energy, Elsevier, vol. 175(C), pages 967-977.
    4. Beltrán-Gastélum, M. & Salazar-Gastélum, M.I. & Flores-Hernández, J.R. & Botte, G.G. & Pérez-Sicairos, S. & Romero-Castañon, T. & Reynoso-Soto, E. & Félix-Navarro, R.M., 2019. "Pt-Au nanoparticles on graphene for oxygen reduction reaction: Stability and performance on proton exchange membrane fuel cell," Energy, Elsevier, vol. 181(C), pages 1225-1234.
    5. Avasarala, Bharat & Haldar, Pradeep, 2013. "Durability and degradation mechanism of titanium nitride based electrocatalysts for PEM (proton exchange membrane) fuel cell applications," Energy, Elsevier, vol. 57(C), pages 545-553.
    6. Ijaodola, O.S. & El- Hassan, Zaki & Ogungbemi, E. & Khatib, F.N. & Wilberforce, Tabbi & Thompson, James & Olabi, A.G., 2019. "Energy efficiency improvements by investigating the water flooding management on proton exchange membrane fuel cell (PEMFC)," Energy, Elsevier, vol. 179(C), pages 246-267.
    7. Xing, Lei & Shi, Weidong & Su, Huaneng & Xu, Qian & Das, Prodip K. & Mao, Baodong & Scott, Keith, 2019. "Membrane electrode assemblies for PEM fuel cells: A review of functional graded design and optimization," Energy, Elsevier, vol. 177(C), pages 445-464.
    8. Park, Jin Young & Lim, In Seop & Choi, Eun Jung & Kim, Min Soo, 2021. "Fault diagnosis of thermal management system in a polymer electrolyte membrane fuel cell," Energy, Elsevier, vol. 214(C).
    9. Liu, Guicheng & Ding, Xianan & Zhou, Hongwei & Chen, Ming & Wang, Manxiang & Zhao, Zhenxuan & Yin, Zhuang & Wang, Xindong, 2015. "Structure optimization of cathode microporous layer for direct methanol fuel cells," Applied Energy, Elsevier, vol. 147(C), pages 396-401.
    10. Majlan, E.H. & Rohendi, D. & Daud, W.R.W. & Husaini, T. & Haque, M.A., 2018. "Electrode for proton exchange membrane fuel cells: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 89(C), pages 117-134.
    11. Hu, Junming & Li, Jianqiu & Xu, Liangfei & Huang, Fusen & Ouyang, Minggao, 2016. "Analytical calculation and evaluation of water transport through a proton exchange membrane fuel cell based on a one-dimensional model," Energy, Elsevier, vol. 111(C), pages 869-883.
    12. Laoun, Brahim & Kasat, Harshal A. & Ahmad, Riaz & Kannan, Arunachala M., 2018. "Gas diffusion layer development using design of experiments for the optimization of a proton exchange membrane fuel cell performance," Energy, Elsevier, vol. 151(C), pages 689-695.
    13. Alipour Moghaddam, Jafar & Parnian, Mohammad Javad & Rowshanzamir, Soosan, 2018. "Preparation, characterization, and electrochemical properties investigation of recycled proton exchange membrane for fuel cell applications," Energy, Elsevier, vol. 161(C), pages 699-709.
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