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Investigation of external heating-induced failure propagation behaviors in large-size cell modules with different phase change materials

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  • Wang, Zhi
  • Wang, Jian

Abstract

The effect of phase change material (PCM) on thermal runaway (TR) and failure propagation in cell modules is investigated. Two PCMs, paraffin (PPCM) and graphene-enhanced hybrid (GHPCM) are considered. Each module is composed of three fully charged 50 Ah LiNixCoyMn1-x-yO2/graphite cells isolated by air or PCM. The onset TR times of cell 1 are around 812, 801, and 942 s in modules without PCM, with PPCM and with GHPCM, respectively. The propagation time from cell 1 (cell 2) to cell 2 (cell 3) is reduced (delayed) from 638 s (168 s) in modules without PCM to 394 s (178 s) in GHPCM modules and 536 s (493 s) in PPCM modules. The PPCM module accompanied by a considerable amount of gas can relieve TR propagation because of less heat feedback from the flame, while the GHPCM module is prone to facilitating propagation due to strong heat transfer between adjacent cells. The module without PCM may delay TR propagation owing to limited heat transfer through contact walls. Compared to modules without PCM and with PPCM, the GHPCM module presents a higher maximum surface temperature (885 °C) and more heat release (7614 kJ). Finally, residue and physical damage are also examined.

Suggested Citation

  • Wang, Zhi & Wang, Jian, 2020. "Investigation of external heating-induced failure propagation behaviors in large-size cell modules with different phase change materials," Energy, Elsevier, vol. 204(C).
    • Handle: RePEc:eee:energy:v:204:y:2020:i:c:s0360544220310537
    DOI: 10.1016/j.energy.2020.117946
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    3. Zhang, Jiangyun & Shao, Dan & Jiang, Liqin & Zhang, Guoqing & Wu, Hongwei & Day, Rodney & Jiang, Wenzhao, 2022. "Advanced thermal management system driven by phase change materials for power lithium-ion batteries: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 159(C).
    4. Lin, Shao & Ling, Ziye & Li, Suimin & Cai, Chuyue & Zhang, Zhengguo & Fang, Xiaoming, 2023. "Mitigation of lithium-ion battery thermal runaway and inhibition of thermal runaway propagation using inorganic salt hydrate with integrated latent heat and thermochemical storage," Energy, Elsevier, vol. 266(C).

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