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Toward to efficient CO2 capture solvent design by analyzing the effect of substituent type connected to N-atom

Author

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  • Zhang, Rui
  • Yang, Qi
  • Yu, Bing
  • Yu, Hai
  • Liang, Zhiwu

Abstract

In this work, 3-Dimethylaminopropylamine (DMAPA), 3-Diethylaminopropylamine (DEAPA) and 3-Piperidinopropylamine (3PDPA) were selected to investigate the influence of substituent type to the CO2 capture performance. The molecular structure of selected diamines can be described as H2NCH2CH2CH2N-R2 (R = CH3, CH2CH3 and (CH2)5). The experimental results shows that the CH2CH3 as a substituent connected to N-atom is better than CH3 and (CH2)5 for the higher CO2 equilibrium solubility, more bicarbonate formation, lower heat of CO2 absorption, higher CO2 cyclic capacity, faster CO2 initial release rate and higher CO2 removal efficiency. In addition, the mass transfer performance of DEAPA and DMAPA also are investigated by using a wetted wall column and the results displays that both of them shows better mass transfer performance compared to MEA and MEA-DMEA, MEA-DEEA and MEA-AMP and it further reveal that the CH2CH3 is better than CH3 as a substituent on N-atom for CO2 transfer. DEAPA has a lower heat of absorption and higher CO2 solubility than most conventional amines and that suggests DEAPA has a potential to be an alternative solvent for the CO2 capture. Therefore, it can conclude that the CH2CH3 has more advantages than CH3 and (CH2)5 as a substituent at N-atom for designing an efficient CO2 capture solvent.

Suggested Citation

  • Zhang, Rui & Yang, Qi & Yu, Bing & Yu, Hai & Liang, Zhiwu, 2018. "Toward to efficient CO2 capture solvent design by analyzing the effect of substituent type connected to N-atom," Energy, Elsevier, vol. 144(C), pages 1064-1072.
  • Handle: RePEc:eee:energy:v:144:y:2018:i:c:p:1064-1072
    DOI: 10.1016/j.energy.2017.12.095
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    References listed on IDEAS

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    1. Xiao, Min & Liu, Helei & Idem, Raphael & Tontiwachwuthikul, Paitoon & Liang, Zhiwu, 2016. "A study of structure–activity relationships of commercial tertiary amines for post-combustion CO2 capture," Applied Energy, Elsevier, vol. 184(C), pages 219-229.
    2. El Hadri, Nabil & Quang, Dang Viet & Goetheer, Earl L.V. & Abu Zahra, Mohammad R.M., 2017. "Aqueous amine solution characterization for post-combustion CO2 capture process," Applied Energy, Elsevier, vol. 185(P2), pages 1433-1449.
    3. Chu, Fengming & Yang, Lijun & Du, Xiaoze & Yang, Yongping, 2016. "CO2 capture using MEA (monoethanolamine) aqueous solution in coal-fired power plants: Modeling and optimization of the absorbing columns," Energy, Elsevier, vol. 109(C), pages 495-505.
    4. Bassani, Andrea & Pirola, Carlo & Maggio, Enrico & Pettinau, Alberto & Frau, Caterina & Bozzano, Giulia & Pierucci, Sauro & Ranzi, Eliseo & Manenti, Flavio, 2016. "Acid Gas to Syngas (AG2S™) technology applied to solid fuel gasification: Cutting H2S and CO2 emissions by improving syngas production," Applied Energy, Elsevier, vol. 184(C), pages 1284-1291.
    5. Nimmanterdwong, Prathana & Chalermsinsuwan, Benjapon & Piumsomboon, Pornpote, 2017. "Emergy analysis of three alternative carbon dioxide capture processes," Energy, Elsevier, vol. 128(C), pages 101-108.
    6. Yaumi, A.L. & Bakar, M.Z. Abu & Hameed, B.H., 2017. "Recent advances in functionalized composite solid materials for carbon dioxide capture," Energy, Elsevier, vol. 124(C), pages 461-480.
    7. Zhang, Rui & Zhang, Xiaowen & Yang, Qi & Yu, Hai & Liang, Zhiwu & Luo, Xiao, 2017. "Analysis of the reduction of energy cost by using MEA-MDEA-PZ solvent for post-combustion carbon dioxide capture (PCC)," Applied Energy, Elsevier, vol. 205(C), pages 1002-1011.
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    Cited by:

    1. Vega, F. & Baena-Moreno, F.M. & Gallego Fernández, Luz M. & Portillo, E. & Navarrete, B. & Zhang, Zhien, 2020. "Current status of CO2 chemical absorption research applied to CCS: Towards full deployment at industrial scale," Applied Energy, Elsevier, vol. 260(C).
    2. Chen, Dan & Pei, Haoyi & Zhou, Ningli & Xiao, Zhixing, 2024. "CO2 reduction to CH4 by Methanosarcina barkeri and a mixed methanogenic culture using humin as sole electron donor," Energy, Elsevier, vol. 294(C).
    3. Kim, Junghwan & Lee, Jisook & Lee, Yunje & Kim, Huiyong & Kim, Eunseok & Lee, Kwang Soon, 2019. "Evaluation of aqueous polyamines as CO2 capture solvents," Energy, Elsevier, vol. 187(C).
    4. Han, Siyu & Meng, Yuan & Aihemaiti, Aikelaimu & Gao, Yuchen & Ju, Tongyao & Xiang, Honglin & Jiang, Jianguo, 2022. "Biogas upgrading with various single and blended amines solutions: Capacities and kinetics," Energy, Elsevier, vol. 253(C).

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