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Role of the nanoparticles of Cu-Co alloy derived from perovskite in dry reforming of methane

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  • Touahra, Fouzia
  • Chebout, Redouane
  • Lerari, Djahida
  • Halliche, Djamila
  • Bachari, Khaldoun

Abstract

Enhanced the carbon resistance and sintering of the metal-active site of catalysts for the dry reforming of methane (DRM) can be achieved by the metal-perovskite interaction. Perovskite-based catalysts LaCoO3 and LaCu0.55Co0.45O3 were prepared using the sol-gel citrate method. The products obtained, after heat treatment under air at 800 °C, were characterized by several techniques such as: inductively coupled plasma atomic emission spectroscopy (ICP-AES), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Brunauere Emmette Teller method (BET), scanning electron microscopy (SEM-EDX), transmission electron microscopy (TEM) and temperature-programmed reduction (TPR). After reduction, the catalysts were evaluated in the reforming of methane reaction under continuous flow with CH4/CO2 ratio equal to 1, at atmospheric pressure and temperature ranging from 400 to 700 °C. LaCu0.55Co0.45O3 catalyst exhibit higher activity compared to LaCoO3. According to the catalytic and characterization results before and after reaction, the higher activity obtained in the case of LaCu0.55Co0.45O3 can be explained by the lower Co particle size and formation of Cu-Co alloy during the reduction which prevents the CoO formation.

Suggested Citation

  • Touahra, Fouzia & Chebout, Redouane & Lerari, Djahida & Halliche, Djamila & Bachari, Khaldoun, 2019. "Role of the nanoparticles of Cu-Co alloy derived from perovskite in dry reforming of methane," Energy, Elsevier, vol. 171(C), pages 465-474.
  • Handle: RePEc:eee:energy:v:171:y:2019:i:c:p:465-474
    DOI: 10.1016/j.energy.2019.01.085
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    References listed on IDEAS

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    1. Usman, Muhammad & Wan Daud, W.M.A. & Abbas, Hazzim F., 2015. "Dry reforming of methane: Influence of process parameters—A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 45(C), pages 710-744.
    2. Aramouni, Nicolas Abdel Karim & Touma, Jad G. & Tarboush, Belal Abu & Zeaiter, Joseph & Ahmad, Mohammad N., 2018. "Catalyst design for dry reforming of methane: Analysis review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2570-2585.
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    1. Bian, Zhoufeng & Wang, Zhigang & Jiang, Bo & Hongmanorom, Plaifa & Zhong, Wenqi & Kawi, Sibudjing, 2020. "A review on perovskite catalysts for reforming of methane to hydrogen production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 134(C).
    2. Xie, Xuanlan & Li, Chang & Lu, Zhiheng & Wang, Yishuang & Yang, Wenqiang & Chen, Mingqiang & Li, Wenzhi, 2024. "Noble metal modified copper-exchanged mordenite zeolite (Cu-ex-MOR) catalysts for catalyzing the methane efficient gas-phase synthesis methanol," Energy, Elsevier, vol. 300(C).
    3. Cheng, Yoke Wang & Chong, Chi Cheng & Lee, Soon Poh & Lim, Jun Wei & Wu, Ta Yeong & Cheng, Chin Kui, 2020. "Syngas from palm oil mill effluent (POME) steam reforming over lanthanum cobaltite: Effects of net-basicity," Renewable Energy, Elsevier, vol. 148(C), pages 349-362.
    4. Jiaqi Yu & Tien Le & Dapeng Jing & Eli Stavitski & Nicholas Hunter & Kanika Lalit & Denis Leshchev & Daniel E. Resasco & Edward H. Sargent & Bin Wang & Wenyu Huang, 2023. "Balancing elementary steps enables coke-free dry reforming of methane," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    5. Chein, Rei-Yu & Hsu, Wen-Huai, 2019. "Thermodynamic analysis of syngas production via chemical looping dry reforming of methane," Energy, Elsevier, vol. 180(C), pages 535-547.

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