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Design and operation of extractive distillation systems using different class of entrainers for the production of fuel grade tert-butyl Alcohol:A techno-economic assessment

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  • Aniya, Vineet
  • De, Debiparna
  • Singh, Ashish
  • Satyavathi, B.

Abstract

The 21st century beholds interest in biofuels, leading to a key challenge being the production of fuel grade ‘tert butyl alcohol’ (TBA) with reduced economics. As a consequent step in the investigation with a different class of entrainers for TBA dehydration (Aniya et al. 2015, 2016) through extractive distillation (ED), the present study explores the utilization of ionic liquid [emim][Cl] and inorganic salt [MgCl2] as a potent entrainer. A comprehensive approach is proposed with phase-equilibrium measurements, thermodynamic modeling, design and process optimization using Aspen Plus. A techno-economic assessment of all the investigated processes (conventional solvents: CSED, solvent + salt: SEED, designer solvents or ionic liquids: DEED and ionic liquid + salt: DSEED) concluded SEED process to be the most promising with 6%, 18% and 37% savings in TAC and 9%, 23% and 41% savings in SEC as compared to the DSEED, DEED and CSED processes respectively. Further, retrofits (heat integration and thermally coupled schemes) demonstrated 13% and 6% reduction in specific energy consumption respectively thus improving the energy efficiency of ED systems. Heat integration brought in 12% savings in TAC over SEED process. However, thermally coupled schemes resulted in marginal benefit (2% savings) in terms of TAC over SEED process.

Suggested Citation

  • Aniya, Vineet & De, Debiparna & Singh, Ashish & Satyavathi, B., 2018. "Design and operation of extractive distillation systems using different class of entrainers for the production of fuel grade tert-butyl Alcohol:A techno-economic assessment," Energy, Elsevier, vol. 144(C), pages 1013-1025.
    • Handle: RePEc:eee:energy:v:144:y:2018:i:c:p:1013-1025
    DOI: 10.1016/j.energy.2017.12.099
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    References listed on IDEAS

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    1. Vlysidis, Anestis & Binns, Michael & Webb, Colin & Theodoropoulos, Constantinos, 2011. "A techno-economic analysis of biodiesel biorefineries: Assessment of integrated designs for the co-production of fuels and chemicals," Energy, Elsevier, vol. 36(8), pages 4671-4683.
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    1. Chen, Feng & Zhang, Yuhao & Zhao, Liang & Gao, Jinsen & Hao, Pengfei & Meng, Qingfei & Xu, Chunming, 2022. "Research on thermodynamic and simulation method of extractive distillation for desulfurization of FCC naphtha," Energy, Elsevier, vol. 254(PA).
    2. Battisti, Rodrigo & Galeazzi, Andrea & Prifti, Kristiano & Manenti, Flavio & Machado, Ricardo Antonio Francisco & Marangoni, Cintia, 2021. "Techno-economic and energetic assessment of an innovative pilot-scale thermosyphon-assisted falling film distillation unit for sanitizer-grade ethanol recovery," Applied Energy, Elsevier, vol. 297(C).
    3. Geng, Xueli & Yan, Peng & Zhou, Hao & Li, Hong & Gao, Xin, 2023. "Process synthesis and 4E evaluation of hybrid reactive distillation processes for the ethanol and tert-butanol recovery from wastewater," Renewable Energy, Elsevier, vol. 205(C), pages 929-944.
    4. Duan, Cong & Li, Chunli, 2023. "Energy-saving improvement of heat integration for separating dilute azeotropic components in extractive distillation," Energy, Elsevier, vol. 263(PC).

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