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Development of porous solid reactant for thermal-energy storage and temperature upgrade using carbonation/decarbonation reaction

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  • Aihara, Masahiko
  • Nagai, Toshiyuki
  • Matsushita, Junro
  • Negishi, Yoichi
  • Ohya, Haruhiko

Abstract

Cyclic reaction performances of solid reactants for a CaO-CO2 chemical heat-pump designed for upgrading and storing high-temperature thermal energy were studied. Solid reactants composed of CaO as the reactant and CaTiO3 as the inert framework were prepared using the conventional powder method or the metal alkoxide method. Upon experiments of cyclic operation between CaO carbonation and CaCO3 decarbonation at 1023K, the reaction reversibility of the solid reactants with the inert CaTiO3 framework was steady, whereas that of the solid reactant without the inert framework decreased with sintering of the solid particles during cyclic operation. Reaction rates for the first carbonation and the decarbonation of solid reactant prepared using the alkoxide method were about 1.8 and 2.4 times faster, respectively, than for those prepared by the powder method due to the smaller average diameter of reactant particles derived from the alkoxide method.

Suggested Citation

  • Aihara, Masahiko & Nagai, Toshiyuki & Matsushita, Junro & Negishi, Yoichi & Ohya, Haruhiko, 2001. "Development of porous solid reactant for thermal-energy storage and temperature upgrade using carbonation/decarbonation reaction," Applied Energy, Elsevier, vol. 69(3), pages 225-238, July.
    • Handle: RePEc:eee:appene:v:69:y:2001:i:3:p:225-238
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    4. Masnadi, Mohammad S. & Grace, John R. & Bi, Xiaotao T. & Ellis, Naoko & Lim, C. Jim & Butler, James W., 2015. "Biomass/coal steam co-gasification integrated with in-situ CO2 capture," Energy, Elsevier, vol. 83(C), pages 326-336.
    5. Pardo, P. & Deydier, A. & Anxionnaz-Minvielle, Z. & Rougé, S. & Cabassud, M. & Cognet, P., 2014. "A review on high temperature thermochemical heat energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 32(C), pages 591-610.
    6. Yan, J. & Zhao, C.Y. & Pan, Z.H., 2017. "The effect of CO2 on Ca(OH)2 and Mg(OH)2 thermochemical heat storage systems," Energy, Elsevier, vol. 124(C), pages 114-123.
    7. Zare Ghorbaei, S. & Ale Ebrahim, H., 2022. "Comparison of kinetics and thermochemical energy storage capacities of strontium oxide, calcium oxide, and magnesium oxide during carbonation reaction," Renewable Energy, Elsevier, vol. 184(C), pages 765-775.
    8. Sarah Roger-Lund & Jo Darkwa & Mark Worall & John Calautit & Rabah Boukhanouf, 2024. "A Review of Thermochemical Energy Storage Systems for District Heating in the UK," Energies, MDPI, vol. 17(14), pages 1-28, July.
    9. Li, Caili & Li, Yingjie & Fang, Yi & Zhang, Chunxiao & Ren, Yu, 2024. "TiO2/MnFe2O4 co-modified alkaline papermaking waste for CaO-CaCO3 thermochemical energy storage," Applied Energy, Elsevier, vol. 362(C).
    10. Marias, Foivos & Neveu, Pierre & Tanguy, Gwennyn & Papillon, Philippe, 2014. "Thermodynamic analysis and experimental study of solid/gas reactor operating in open mode," Energy, Elsevier, vol. 66(C), pages 757-765.
    11. Li, Yingjie & Su, Mengying & Xie, Xin & Wu, Shuimu & Liu, Changtian, 2015. "CO2 capture performance of synthetic sorbent prepared from carbide slag and aluminum nitrate hydrate by combustion synthesis," Applied Energy, Elsevier, vol. 145(C), pages 60-68.
    12. Gravogl, Georg & Knoll, Christian & Artner, Werner & Welch, Jan M. & Eitenberger, Elisabeth & Friedbacher, Gernot & Harasek, Michael & Hradil, Klaudia & Werner, Andreas & Weinberger, Peter & Müller, D, 2019. "Pressure effects on the carbonation of MeO (Me = Co, Mn, Pb, Zn) for thermochemical energy storage," Applied Energy, Elsevier, vol. 252(C), pages 1-1.
    13. Ding, Zhixiong & Wu, Wei & Huang, Si-Min & Huang, Hongyu & Bai, Yu & He, Zhaohong, 2023. "A novel compression-assisted energy storage heat transformer for low-grade renewable energy utilization," Energy, Elsevier, vol. 263(PA).
    14. Gong, Xuzhong & Zhang, Tong & Zhang, Junqiang & Wang, Zhi & Liu, Junhao & Cao, Jianwei & Wang, Chuan, 2022. "Recycling and utilization of calcium carbide slag - current status and new opportunities," Renewable and Sustainable Energy Reviews, Elsevier, vol. 159(C).
    15. Chen, Huichao & Zhao, Changsui & Yu, Weiwei, 2013. "Calcium-based sorbent doped with attapulgite for CO2 capture," Applied Energy, Elsevier, vol. 112(C), pages 67-74.
    16. Dizaji, Hossein Beidaghy & Hosseini, Hannaneh, 2018. "A review of material screening in pure and mixed-metal oxide thermochemical energy storage (TCES) systems for concentrated solar power (CSP) applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 98(C), pages 9-26.
    17. Zhao, Y. & Zhao, C.Y. & Markides, C.N. & Wang, H. & Li, W., 2020. "Medium- and high-temperature latent and thermochemical heat storage using metals and metallic compounds as heat storage media: A technical review," Applied Energy, Elsevier, vol. 280(C).
    18. Tiskatine, R. & Eddemani, A. & Gourdo, L. & Abnay, B. & Ihlal, A. & Aharoune, A. & Bouirden, L., 2016. "Experimental evaluation of thermo-mechanical performances of candidate rocks for use in high temperature thermal storage," Applied Energy, Elsevier, vol. 171(C), pages 243-255.

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