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Characteristics of the products of hydrothermal liquefaction combined with cellulosic bio-ethanol process

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  • Li, Rundong
  • Xie, Yinghui
  • Yang, Tianhua
  • Li, Bingshuo
  • Zhang, Yang
  • Kai, Xingping

Abstract

The integration utilization of fermentation residues from cellulosic bio-ethanol has attracted a great deal of attention to balance the total cost of bio-ethanol production while simultaneously dealing with bio-ethanol wastewater. A process of hydrothermal liquefaction (HTL) of intact materials from cellulosic bio-ethanol in a batch reactor was proposed. The effects of the reaction temperature and time on the liquefaction characteristics were examined. The optimum condition for liquefaction fermentation residues was 370 °C (21.25 MPa) and 30 min with a bio-oil yield of 40.79 wt%. GC-MS results indicated that the major chemical species in the bio-oil were phenols, ketones, long-chain hydrocarbons and fatty acids. Supercritical conditions (375 °C, 23.50 MPa) was favored for the low-molecular-weight species formation compared to subcritical conditions (370 °C, 21.25 MPa), as some long-chain species decreased. This work thus can provide a novel idea for bio-oil production from HTL of cellulosic bio-ethanol fermentation residues.

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  • Li, Rundong & Xie, Yinghui & Yang, Tianhua & Li, Bingshuo & Zhang, Yang & Kai, Xingping, 2016. "Characteristics of the products of hydrothermal liquefaction combined with cellulosic bio-ethanol process," Energy, Elsevier, vol. 114(C), pages 862-867.
    • Handle: RePEc:eee:energy:v:114:y:2016:i:c:p:862-867
    DOI: 10.1016/j.energy.2016.08.033
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    2. Wu, Xiao-Fei & Yin, Shuang-Shuang & Zhou, Qian & Li, Ming-Fei & Peng, Feng & Xiao, Xiao, 2019. "Subcritical liquefaction of lignocellulose for the production of bio-oils in ethanol/water system," Renewable Energy, Elsevier, vol. 136(C), pages 865-872.
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    4. Kumar, Mayank & Olajire Oyedun, Adetoyese & Kumar, Amit, 2018. "A review on the current status of various hydrothermal technologies on biomass feedstock," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P2), pages 1742-1770.

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