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Ethanolysis of camelina oil under supercritical condition with hexane as a co-solvent

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  • Muppaneni, Tapaswy
  • Reddy, Harvind K.
  • Patil, Prafulla D.
  • Dailey, Peter
  • Aday, Curtis
  • Deng, Shuguang

Abstract

Non-catalytic transesterification of camelina sativa oil under supercritical ethanol (SCE) conditions with hexane as a co-solvent was investigated to study the fatty acid ethyl ester (FAEE) yields. This process enables simultaneous transesterification of triglycerides and ethyl esterification of fatty acids in a shorter reaction of time and may reduce the energy consumption due to simplified separation and purification steps. It was found that the co-solvent plays a vital role in reducing the severity of critical operational parameters and maximizes the biodiesel yield. The important variables affecting the ethyl ester yield during the transesterification reaction are the molar ratio of alcohol/oil, reaction time, reaction temperature and co-solvent to oil ratio. Camelina biodiesel samples were analyzed using FT–IR, GC–MS and thermogravimetric analysis (TGA) methods. The fuel properties of camelina biodiesel produced were compared with those of the regular diesel and found to be conforming to the American Society for Testing and Materials (ASTMs) standards.

Suggested Citation

  • Muppaneni, Tapaswy & Reddy, Harvind K. & Patil, Prafulla D. & Dailey, Peter & Aday, Curtis & Deng, Shuguang, 2012. "Ethanolysis of camelina oil under supercritical condition with hexane as a co-solvent," Applied Energy, Elsevier, vol. 94(C), pages 84-88.
    • Handle: RePEc:eee:appene:v:94:y:2012:i:c:p:84-88
    DOI: 10.1016/j.apenergy.2012.01.023
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    2. Maleki, Esmat & Aroua, Mohamed Kheireddine & Sulaiman, Nik Meriam Nik, 2013. "Improved yield of solvent free enzymatic methanolysis of palm and jatropha oils blended with castor oil," Applied Energy, Elsevier, vol. 104(C), pages 905-909.
    3. Jazzar, Souhir & Olivares-Carrillo, Pilar & Pérez de los Ríos, Antonia & Marzouki, Mohamed Néjib & Acién-Fernández, Francisco Gabriel & Fernández-Sevilla, José María & Molina-Grima, Emilio & Smaali, I, 2015. "Direct supercritical methanolysis of wet and dry unwashed marine microalgae (Nannochloropsis gaditana) to biodiesel," Applied Energy, Elsevier, vol. 148(C), pages 210-219.
    4. Farobie, Obie & Sasanami, Kazuma & Matsumura, Yukihiko, 2015. "A novel spiral reactor for biodiesel production in supercritical ethanol," Applied Energy, Elsevier, vol. 147(C), pages 20-29.
    5. Choi, Oh Kyung & Park, Jo Yong & Kim, Jae-Kon & Lee, Jae Woo, 2019. "Bench-scale production of sewage sludge derived-biodiesel (SSD-BD) and upgrade of its quality," Renewable Energy, Elsevier, vol. 141(C), pages 914-921.
    6. Andreo-Martínez, Pedro & Ortiz-Martínez, Víctor Manuel & García-Martínez, Nuria & de los Ríos, Antonia Pérez & Hernández-Fernández, Francisco José & Quesada-Medina, Joaquín, 2020. "Production of biodiesel under supercritical conditions: State of the art and bibliometric analysis," Applied Energy, Elsevier, vol. 264(C).
    7. Pinto, F. & Martins, S. & Gonçalves, M. & Costa, P. & Gulyurtlu, I. & Alves, A. & Mendes, B., 2013. "Hydrogenation of rapeseed oil for production of liquid bio-chemicals," Applied Energy, Elsevier, vol. 102(C), pages 272-282.
    8. Liu, Chien-Hung & Huang, Chien-Chang & Wang, Yao-Wen & Lee, Duu-Jong & Chang, Jo-Shu, 2012. "Biodiesel production by enzymatic transesterification catalyzed by Burkholderia lipase immobilized on hydrophobic magnetic particles," Applied Energy, Elsevier, vol. 100(C), pages 41-46.

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