IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v102y2013icp272-282.html
   My bibliography  Save this article

Hydrogenation of rapeseed oil for production of liquid bio-chemicals

Author

Listed:
  • Pinto, F.
  • Martins, S.
  • Gonçalves, M.
  • Costa, P.
  • Gulyurtlu, I.
  • Alves, A.
  • Mendes, B.

Abstract

The main objective of rapeseed oil hydrogenation tests was the production of liquid bio-chemicals to be used as renewable raw material for the production of several chemicals and in chemical synthesis to substitute petroleum derived stuff. As, hydrogenation of vegetable oils is already applied for the production of biofuels, the work done focused in producing aromatic compounds, due to their economic value. The effect of experimental conditions on rapeseed oil hydrogenation was studied, namely, reaction temperature and time with the aim of selecting the most favourable conditions to convert rapeseed oil into liquid valuable bio-chemicals. Rapeseed oil was hydrogenated at a hydrogen initial pressure of 1.10MPa. Reaction temperature varied in the range from 200°C to 400°C, while reaction times between 6 and 180min were tested. The performance of a commercial cobalt and molybdenum catalyst was also studied. The highest hydrocarbons yields were obtained at the highest temperature and reaction times tested. At a temperature of 400°C and at the reaction time of 120min hydrocarbons yield was about 92% in catalyst presence, while in the absence of the catalyst this value decreased to 85%. Hydrocarbons yield was even higher when the reaction time of 180min was used in the presence of catalyst, as the yield of 97% was observed. At these conditions hydrocarbons formed had a high content of aromatic compounds, around 50%. For this reason, the viscosity values of hydrogenated oils were lower than that established by EN590, which together with hydrogenated liquids composition prevented its use as direct liquid fuel to substitute fossil gas oil for transport sector. However, hydrocarbons analysis showed the presence of several valuable compounds that encourages their use as a raw material for the production of several chemicals and in chemical synthesis.

Suggested Citation

  • Pinto, F. & Martins, S. & Gonçalves, M. & Costa, P. & Gulyurtlu, I. & Alves, A. & Mendes, B., 2013. "Hydrogenation of rapeseed oil for production of liquid bio-chemicals," Applied Energy, Elsevier, vol. 102(C), pages 272-282.
  • Handle: RePEc:eee:appene:v:102:y:2013:i:c:p:272-282
    DOI: 10.1016/j.apenergy.2012.04.008
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261912002942
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.apenergy.2012.04.008?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Demirbas, Ayhan, 2011. "Competitive liquid biofuels from biomass," Applied Energy, Elsevier, vol. 88(1), pages 17-28, January.
    2. Muppaneni, Tapaswy & Reddy, Harvind K. & Patil, Prafulla D. & Dailey, Peter & Aday, Curtis & Deng, Shuguang, 2012. "Ethanolysis of camelina oil under supercritical condition with hexane as a co-solvent," Applied Energy, Elsevier, vol. 94(C), pages 84-88.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Capuano, D. & Costa, M. & Di Fraia, S. & Massarotti, N. & Vanoli, L., 2017. "Direct use of waste vegetable oil in internal combustion engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 69(C), pages 759-770.
    2. Shirazi, Yaser & Viamajala, Sridhar & Varanasi, Sasidhar, 2016. "High-yield production of fuel- and oleochemical-precursors from triacylglycerols in a novel continuous-flow pyrolysis reactor," Applied Energy, Elsevier, vol. 179(C), pages 755-764.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Bharathiraja, B. & Jayamuthunagai, J. & Sudharsanaa, T. & Bharghavi, A. & Praveenkumar, R. & Chakravarthy, M. & Yuvaraj, D., 2017. "Biobutanol – An impending biofuel for future: A review on upstream and downstream processing tecniques," Renewable and Sustainable Energy Reviews, Elsevier, vol. 68(P1), pages 788-807.
    2. Vasaki E, Madhu & Karri, Rama Rao & Ravindran, Gobinath & Paramasivan, Balasubramanian, 2021. "Predictive capability evaluation and optimization of sustainable biodiesel production from oleaginous biomass grown on pulp and paper industrial wastewater," Renewable Energy, Elsevier, vol. 168(C), pages 204-215.
    3. Wang, Zhi & Liu, Hui & Long, Yan & Wang, Jianxin & He, Xin, 2015. "Comparative study on alcohols–gasoline and gasoline–alcohols dual-fuel spark ignition (DFSI) combustion for high load extension and high fuel efficiency," Energy, Elsevier, vol. 82(C), pages 395-405.
    4. Jin, Wenxiang & Chen, Ling & Hu, Meng & Sun, Dan & Li, Ao & Li, Ying & Hu, Zhen & Zhou, Shiguang & Tu, Yuanyuan & Xia, Tao & Wang, Yanting & Xie, Guosheng & Li, Yanbin & Bai, Baowei & Peng, Liangcai, 2016. "Tween-80 is effective for enhancing steam-exploded biomass enzymatic saccharification and ethanol production by specifically lessening cellulase absorption with lignin in common reed," Applied Energy, Elsevier, vol. 175(C), pages 82-90.
    5. Magdeldin, Mohamed & Kohl, Thomas & Järvinen, Mika, 2017. "Techno-economic assessment of the by-products contribution from non-catalytic hydrothermal liquefaction of lignocellulose residues," Energy, Elsevier, vol. 137(C), pages 679-695.
    6. Jiheon Jun & Yi-Feng Su & James R. Keiser & John E. Wade & Michael D. Kass & Jack R. Ferrell & Earl Christensen & Mariefel V. Olarte & Dino Sulejmanovic, 2022. "Corrosion Compatibility of Stainless Steels and Nickel in Pyrolysis Biomass-Derived Oil at Elevated Storage Temperatures," Sustainability, MDPI, vol. 15(1), pages 1-16, December.
    7. Huang, Y. & McIlveen-Wright, D.R. & Rezvani, S. & Huang, M.J. & Wang, Y.D. & Roskilly, A.P. & Hewitt, N.J., 2013. "Comparative techno-economic analysis of biomass fuelled combined heat and power for commercial buildings," Applied Energy, Elsevier, vol. 112(C), pages 518-525.
    8. Tan, Raymond R. & Aviso, Kathleen B. & Barilea, Ivan U. & Culaba, Alvin B. & Cruz, Jose B., 2012. "A fuzzy multi-regional input–output optimization model for biomass production and trade under resource and footprint constraints," Applied Energy, Elsevier, vol. 90(1), pages 154-160.
    9. Talebian-Kiakalaieh, Amin & Amin, Nor Aishah Saidina & Mazaheri, Hossein, 2013. "A review on novel processes of biodiesel production from waste cooking oil," Applied Energy, Elsevier, vol. 104(C), pages 683-710.
    10. Kasivisvanathan, Harresh & Barilea, Ivan Dale U. & Ng, Denny K.S. & Tan, Raymond R., 2013. "Optimal operational adjustment in multi-functional energy systems in response to process inoperability," Applied Energy, Elsevier, vol. 102(C), pages 492-500.
    11. Makarfi Isa, Yusuf & Ganda, Elvis Tinashe, 2018. "Bio-oil as a potential source of petroleum range fuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P1), pages 69-75.
    12. McCarty, Tanner & Sesmero, Juan, 2014. "Uncertainty, Irreversibility, and Investment in Second-Generation Biofuels," 2014 Annual Meeting, July 27-29, 2014, Minneapolis, Minnesota 179201, Agricultural and Applied Economics Association.
    13. Xu, Donghai & Lin, Guike & Guo, Shuwei & Wang, Shuzhong & Guo, Yang & Jing, Zefeng, 2018. "Catalytic hydrothermal liquefaction of algae and upgrading of biocrude: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 97(C), pages 103-118.
    14. Maity, Sunil K., 2015. "Opportunities, recent trends and challenges of integrated biorefinery: Part II," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 1446-1466.
    15. Arodudu, Oludunsin Tunrayo & Helming, Katharina & Voinov, Alexey & Wiggering, Hubert, 2017. "Integrating agronomic factors into energy efficiency assessment of agro-bioenergy production – A case study of ethanol and biogas production from maize feedstock," Applied Energy, Elsevier, vol. 198(C), pages 426-439.
    16. Li, Yu & Kesharwani, Rajkamal & Sun, Zeyi & Qin, Ruwen & Dagli, Cihan & Zhang, Meng & Wang, Donghai, 2020. "Economic viability and environmental impact investigation for the biofuel supply chain using co-fermentation technology," Applied Energy, Elsevier, vol. 259(C).
    17. Tzanetis, Konstantinos F. & Posada, John A. & Ramirez, Andrea, 2017. "Analysis of biomass hydrothermal liquefaction and biocrude-oil upgrading for renewable jet fuel production: The impact of reaction conditions on production costs and GHG emissions performance," Renewable Energy, Elsevier, vol. 113(C), pages 1388-1398.
    18. Tian, Zhen-Yu & Chafik, Tarik & Assebban, Mhamed & Harti, Sanae & Bahlawane, Naoufal & Mountapmbeme Kouotou, Patrick & Kohse-Höinghaus, Katharina, 2013. "Towards biofuel combustion with an easily extruded clay as a natural catalyst," Applied Energy, Elsevier, vol. 107(C), pages 149-156.
    19. Kyriakou, Maria & Patsalou, Maria & Xiaris, Nikolas & Tsevis, Athanasios & Koutsokeras, Loukas & Constantinides, Georgios & Koutinas, Michalis, 2020. "Enhancing bioproduction and thermotolerance in Saccharomyces cerevisiae via cell immobilization on biochar: Application in a citrus peel waste biorefinery," Renewable Energy, Elsevier, vol. 155(C), pages 53-64.
    20. Carolin Nuortila & Riikka Help & Katriina Sirviö & Helena Suopanki & Sonja Heikkilä & Seppo Niemi, 2020. "Selected Fuel Properties of Alcohol and Rapeseed Oil Blends," Energies, MDPI, vol. 13(15), pages 1-11, July.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:102:y:2013:i:c:p:272-282. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.