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A novel spiral reactor for biodiesel production in supercritical ethanol

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  • Farobie, Obie
  • Sasanami, Kazuma
  • Matsumura, Yukihiko

Abstract

A spiral reactor is proposed as a novel reactor design for biodiesel production under supercritical conditions. Since the spiral reactor serves as a heat exchanger, it offers the advantage of reduced apparatus space compared to conventional supercritical equipment. Experimental investigations were carried out at reaction temperatures of 270–400°C, pressure of 20MPa, oil-to-ethanol molar ratio of 1:40, and reaction times of 3–30min. An FAEE yield of 0.937mol/mol was obtained in a short reaction time of 30min at 350°C and oil-to-ethanol molar ratio of 1:40 under a reactor pressure of 20MPa. The spiral reactor was not only as effective as conventional reactor in terms of transesterification reactor but also was superior in terms of heat recovery. A second-order kinetic model describing the transesterification of canola oil in supercritical ethanol was proposed, and the reaction was observed to follow Arrhenius behavior. The corresponding reaction rate constants and the activation energies as well as pre-exponential factors were determined.

Suggested Citation

  • Farobie, Obie & Sasanami, Kazuma & Matsumura, Yukihiko, 2015. "A novel spiral reactor for biodiesel production in supercritical ethanol," Applied Energy, Elsevier, vol. 147(C), pages 20-29.
    • Handle: RePEc:eee:appene:v:147:y:2015:i:c:p:20-29
    DOI: 10.1016/j.apenergy.2015.02.033
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    1. Oliveira, João Felipe G. & Lucena, Izabelly Larissa & Saboya, Rosana M. Alves & Rodrigues, Marcelo L. & Torres, Antonio Eurico B. & Fernandes, Fabiano A. Narciso & Cavalcante, Célio L. & Parente, Expe, 2010. "Biodiesel production from waste coconut oil by esterification with ethanol: The effect of water removal by adsorption," Renewable Energy, Elsevier, vol. 35(11), pages 2581-2584.
    2. Muppaneni, Tapaswy & Reddy, Harvind K. & Patil, Prafulla D. & Dailey, Peter & Aday, Curtis & Deng, Shuguang, 2012. "Ethanolysis of camelina oil under supercritical condition with hexane as a co-solvent," Applied Energy, Elsevier, vol. 94(C), pages 84-88.
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    1. Tran, Dang-Thuan & Chang, Jo-Shu & Lee, Duu-Jong, 2017. "Recent insights into continuous-flow biodiesel production via catalytic and non-catalytic transesterification processes," Applied Energy, Elsevier, vol. 185(P1), pages 376-409.
    2. Olalekan Alade & Dhafer Al Shehri & Mohamed Mahmoud & Kyuro Sasaki, 2019. "Viscosity–Temperature–Pressure Relationship of Extra-Heavy Oil (Bitumen): Empirical Modelling versus Artificial Neural Network (ANN)," Energies, MDPI, vol. 12(12), pages 1-13, June.
    3. Karmakar, Bisheswar & Pal, Sucharita & Gopikrishna, Konga & Tiwari, Onkar Nath & Halder, Gopinath, 2022. "Injection of superheated C1 and C3 alcohols in non-edible Pongamia pinnata oil for semi-continuous uncatalyzed biodiesel synthesis," Renewable Energy, Elsevier, vol. 185(C), pages 850-861.
    4. Sina Faizollahzadeh Ardabili & Bahman Najafi & Meysam Alizamir & Amir Mosavi & Shahaboddin Shamshirband & Timon Rabczuk, 2018. "Using SVM-RSM and ELM-RSM Approaches for Optimizing the Production Process of Methyl and Ethyl Esters," Energies, MDPI, vol. 11(11), pages 1-19, October.
    5. Andreo-Martínez, Pedro & Ortiz-Martínez, Víctor Manuel & García-Martínez, Nuria & de los Ríos, Antonia Pérez & Hernández-Fernández, Francisco José & Quesada-Medina, Joaquín, 2020. "Production of biodiesel under supercritical conditions: State of the art and bibliometric analysis," Applied Energy, Elsevier, vol. 264(C).
    6. Laskar, Ikbal Bahar & Deshmukhya, Tuhin & Bhanja, Piyali & Paul, Bappi & Gupta, Rajat & Chatterjee, Sushovan, 2020. "Transesterification of soybean oil at room temperature using biowaste as catalyst; an experimental investigation on the effect of co-solvent on biodiesel yield," Renewable Energy, Elsevier, vol. 162(C), pages 98-111.
    7. Verma, Puneet & Sharma, M.P. & Dwivedi, Gaurav, 2016. "Impact of alcohol on biodiesel production and properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 56(C), pages 319-333.
    8. Živković, Snežana B. & Veljković, Milan V. & Banković-Ilić, Ivana B. & Krstić, Ivan M. & Konstantinović, Sandra S. & Ilić, Slavica B. & Avramović, Jelena M. & Stamenković, Olivera S. & Veljković, Vlad, 2017. "Technological, technical, economic, environmental, social, human health risk, toxicological and policy considerations of biodiesel production and use," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 222-247.

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