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CO-tolerance behaviors of proton exchange membrane fuel cell stacks with impure hydrogen fuel

Author

Listed:
  • Wang, Mingkai
  • Pei, Pucheng
  • Xu, Yiming
  • Fan, Tengbo
  • Ren, Peng
  • Zhu, Zijing
  • Chen, Dongfang
  • Fu, Xi
  • Song, Xin
  • Wang, He

Abstract

Carbon monoxide poisoning poses a significant challenge for proton exchange membrane (PEM) fuel cells operating with CO-containing hydrogen. One established solution involves air bleeding, a process that enhances the oxidation of carbon monoxide at the anode side of the fuel cell by blending a small quantity of air with the impure hydrogen before its introduction into the fuel cell. However, researchers have raised concerns regarding durability issues about catalyst sintering and membrane decomposition induced by air bleeding. The effects and underlying mechanisms of air bleeding on PEM fuel cells have yet to be comprehensively elucidated. To address this, this study conducts a detailed durability test to quantitatively evaluate the effects of air bleeding on the CO-containing hydrogen-fueled PEM fuel cells via the micro-current excitation method. The investigation substantiates that the PtRu/C catalysts significantly enhance both the performance and durability of fuel cells when air bleeding is employed, exhibiting different CO-tolerance and decay behaviors compared to the Pt/C anode catalyst. Furthermore, the evolution of MEA parameters indicates that the advantageous behaviors of PtRu/C catalysts can be attributed to their CO-tolerance capabilities, alleviated anodic catalyst sintering and loss, and decreased chemical carbon support corrosion and membrane decomposition through diminished hydrogen peroxide generation. This study contributes critical insights and empirical evidence for researchers focusing on CO-tolerant catalyst materials, the durability of PEM fuel cells, and the conversion and utilization of impure hydrogen energy derived from fossil fuels.

Suggested Citation

  • Wang, Mingkai & Pei, Pucheng & Xu, Yiming & Fan, Tengbo & Ren, Peng & Zhu, Zijing & Chen, Dongfang & Fu, Xi & Song, Xin & Wang, He, 2024. "CO-tolerance behaviors of proton exchange membrane fuel cell stacks with impure hydrogen fuel," Applied Energy, Elsevier, vol. 366(C).
  • Handle: RePEc:eee:appene:v:366:y:2024:i:c:s0306261924007098
    DOI: 10.1016/j.apenergy.2024.123326
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    References listed on IDEAS

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    1. Huu Linh Nguyen & Jeasu Han & Xuan Linh Nguyen & Sangseok Yu & Young-Mo Goo & Duc Dung Le, 2021. "Review of the Durability of Polymer Electrolyte Membrane Fuel Cell in Long-Term Operation: Main Influencing Parameters and Testing Protocols," Energies, MDPI, vol. 14(13), pages 1-34, July.
    2. Wu, Ziyao & Pei, Pucheng & Xu, Huachi & Jia, Xiaoning & Ren, Peng & Wang, Bozheng, 2019. "Study on the effect of membrane electrode assembly parameters on polymer electrolyte membrane fuel cell performance by galvanostatic charging method," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    3. Ren, Peng & Pei, Pucheng & Chen, Dongfang & Li, Yuehua & Wu, Ziyao & Zhang, Lu & Li, Zizhao & Wang, Mingkai & Wang, He & Wang, Bozheng & Wang, Xizhong, 2022. "Novel analytic method of membrane electrode assembly parameters for fuel cell consistency evaluation by micro-current excitation," Applied Energy, Elsevier, vol. 306(PB).
    4. Kui Jiao & Jin Xuan & Qing Du & Zhiming Bao & Biao Xie & Bowen Wang & Yan Zhao & Linhao Fan & Huizhi Wang & Zhongjun Hou & Sen Huo & Nigel P. Brandon & Yan Yin & Michael D. Guiver, 2021. "Designing the next generation of proton-exchange membrane fuel cells," Nature, Nature, vol. 595(7867), pages 361-369, July.
    5. Li, Zheng & Wang, Yameng & Mu, Yongbiao & Wu, Buke & Jiang, Yuting & Zeng, Lin & Zhao, Tianshou, 2023. "Recent advances in the anode catalyst layer for proton exchange membrane fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 176(C).
    6. Ren, Peng & Meng, Yining & Pei, Pucheng & Fu, Xi & Chen, Dongfang & Li, Yuehua & Zhu, Zijing & Zhang, Lu & Wang, Mingkai, 2023. "Rapid synchronous state-of-health diagnosis of membrane electrode assemblies in fuel cell stacks," Applied Energy, Elsevier, vol. 330(PA).
    7. Liu, Zhao & Chen, Huicui & Zhang, Tong, 2022. "Review on system mitigation strategies for start-stop degradation of automotive proton exchange membrane fuel cell," Applied Energy, Elsevier, vol. 327(C).
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