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The thermal runaway analysis on LiFePO4 electrical energy storage packs with different venting areas and void volumes

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  • Qin, Peng
  • Jia, Zhuangzhuang
  • Wu, Jingyun
  • Jin, Kaiqiang
  • Duan, Qiangling
  • Jiang, Lihua
  • Sun, Jinhua
  • Ding, Jinghu
  • Shi, Cheng
  • Wang, Qingsong

Abstract

With increasingly more electrochemical energy storage systems installed, the safety issues of lithium batteries, such as fire explosions, have aroused greater concerns. In this study, the thermal runaway behaviors of two different structures of lithium–iron-phosphate battery packs were compared. A fire explosion occurred in battery pack I, which had a small venting area and void volume, but battery pack II with a large venting area and the void volume kept safe. To explain these phenomena, a new experimental method coupling multiple measurements was proposed in this study to survey the velocity, composition, and temperature of venting gas. The venting gas velocity had two peaks, with its maximum value reaching about 270 m/s. Besides, the venting gas was mainly composed of hydrogen and carbon dioxide, accounting for around 30.33% and 38.86%, respectively. With the experimental data used as boundary conditions in a mathematical model, the diffusion behaviors of the venting gas within these two battery packs were derived. By comparing the flammable gas concentration with their lower explosion limits and upper limits, this study found that the high concentration of hydrogen and ethylene might bear the main responsibility for the fire explosion in battery pack I.

Suggested Citation

  • Qin, Peng & Jia, Zhuangzhuang & Wu, Jingyun & Jin, Kaiqiang & Duan, Qiangling & Jiang, Lihua & Sun, Jinhua & Ding, Jinghu & Shi, Cheng & Wang, Qingsong, 2022. "The thermal runaway analysis on LiFePO4 electrical energy storage packs with different venting areas and void volumes," Applied Energy, Elsevier, vol. 313(C).
    • Handle: RePEc:eee:appene:v:313:y:2022:i:c:s0306261922002185
    DOI: 10.1016/j.apenergy.2022.118767
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    2. Jia, Zhuangzhuang & Song, Laifeng & Mei, Wenxin & Yu, Yin & Meng, Xiangdong & Jin, Kaiqiang & Sun, Jinhua & Wang, Qingsong, 2022. "The preload force effect on the thermal runaway and venting behaviors of large-format prismatic LiFePO4 batteries," Applied Energy, Elsevier, vol. 327(C).
    3. Jing, Qi & Wang, Dan & Shi, Congling, 2023. "Effects of aluminum powder additives on deflagration and detonation performance of JP-10/DEE mixed fuel under weak and strong ignition conditions," Applied Energy, Elsevier, vol. 331(C).
    4. Hao Chen & Kai Yang & Youwei Liu & Mingjie Zhang & Hao Liu & Jialiang Liu & Zhanzhan Qu & Yilin Lai, 2023. "Experimental Investigation of Thermal Runaway Behavior and Hazards of a 1440 Ah LiFePO 4 Battery Pack," Energies, MDPI, vol. 16(8), pages 1-14, April.
    5. Wang, Gongquan & Kong, Depeng & Ping, Ping & He, Xiaoqin & Lv, Hongpeng & Zhao, Hengle & Hong, Wanru, 2023. "Modeling venting behavior of lithium-ion batteries during thermal runaway propagation by coupling CFD and thermal resistance network," Applied Energy, Elsevier, vol. 334(C).
    6. Wei, Gang & Huang, Ranjun & Zhang, Guangxu & Jiang, Bo & Zhu, Jiangong & Guo, Yangyang & Han, Guangshuai & Wei, Xuezhe & Dai, Haifeng, 2023. "A comprehensive insight into the thermal runaway issues in the view of lithium-ion battery intrinsic safety performance and venting gas explosion hazards," Applied Energy, Elsevier, vol. 349(C).
    7. Zhou, Zhizuan & Zhou, Xiaodong & Li, Maoyu & Cao, Bei & Liew, K.M. & Yang, Lizhong, 2022. "Experimentally exploring prevention of thermal runaway propagation of large-format prismatic lithium-ion battery module," Applied Energy, Elsevier, vol. 327(C).
    8. Zhang, Yue & Cheng, Siyuan & Mei, Wenxin & Jiang, Lihua & Jia, Zhuangzhuang & Cheng, Zhixiang & Sun, Jinhua & Wang, Qingsong, 2023. "Understanding of thermal runaway mechanism of LiFePO4 battery in-depth by three-level analysis," Applied Energy, Elsevier, vol. 336(C).

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