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Economically feasible decarbonization of the Haber-Bosch process through supercritical CO2 Allam cycle integration

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  • Byun, Manhee
  • Lim, Dongjun
  • Lee, Boreum
  • Kim, Ayeon
  • Lee, In-Beum
  • Brigljević, Boris
  • Lim, Hankwon

Abstract

The well-established Haber-Bosch (HB) process (industrial ammonia production) is a significant contributor to the world’s carbon emissions as it is a major consumer of natural gas as well as being energy-intensive in general. This work addresses the challenge of decarbonizing the HB process in a novel way as it, for the first time, presents a conceptual process integration with a supercritical CO2 Allam power cycle, therefore transforming gaseous CO2 emissions into a valuable side product in a form of liquid CO2. Detailed process design and flowsheet simulation using Aspen Plus ® was used as a basis for scale-up and techno-economic assessment of two cases (electrical grid dependent and independent). The results indicated that using this process design NH3 production reaches profitability at scales larger than 2 ton h−1 to 5.4 ton h−1 and at current global NH3 prices, the cost of manufacturing decrease, due to scale-up stabilizes at ∼ 30 ton h−1. Finally, this novel process integration achieves a significant reduction in gaseous CO2 emissions (compared to conventional HB process) of 68 % to 96 %, which indicates great potential for economically feasible green NH3.

Suggested Citation

  • Byun, Manhee & Lim, Dongjun & Lee, Boreum & Kim, Ayeon & Lee, In-Beum & Brigljević, Boris & Lim, Hankwon, 2022. "Economically feasible decarbonization of the Haber-Bosch process through supercritical CO2 Allam cycle integration," Applied Energy, Elsevier, vol. 307(C).
    • Handle: RePEc:eee:appene:v:307:y:2022:i:c:s0306261921014549
    DOI: 10.1016/j.apenergy.2021.118183
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    1. Fabrizio Reale, 2023. "The Allam Cycle: A Review of Numerical Modeling Approaches," Energies, MDPI, vol. 16(22), pages 1-22, November.

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