IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v293y2021ics0306261921004323.html
   My bibliography  Save this article

Evaluating ammonia as green fuel for power generation: A thermo-chemical perspective

Author

Listed:
  • Sánchez, Antonio
  • Castellano, Elena
  • Martín, Mariano
  • Vega, Pastora

Abstract

Energy storage will be necessary for a future power system with high penetration of renewable sources, mainly, wind and solar, to ensure the stability of the grid. In this context, power-to-chemicals is a promising concept for a medium/long-term storage horizon and a wide range of capacities. Within this alternative, ammonia rises as one of the fuels with the highest potential in a scenario targeting decarbonization. The first step is the production of ammonia using renewable energy sources, followed by its transformation into energy. This second area requires a deeper analysis at process scale in order to introduce this technology into the future power system. In this work, an assessment of an ammonia-based power plant is presented, focusing on the thermo-chemical route. A combined cycle is evaluated, considering different gas clean-up technologies to recover valuable components and comply with environmental restrictions. As a result, the total efficiency of the power facility reaches about 40%, limited by the maximum temperature allowed in the gas turbine. The influence of the price of ammonia is also evaluated due to the paramount importance of this parameter. The production cost ranges from 0.2 to 0.6€/kWh, with the lowest level corresponding to a scenario in which there is a significant reduction in the cost of renewable power generation and electrolysis technology. Therefore, the feasibility of the use of ammonia as an energy storage alternative is demonstrated, providing a powerful platform for the implementation of a power grid with high penetration of fluctuating sources.

Suggested Citation

  • Sánchez, Antonio & Castellano, Elena & Martín, Mariano & Vega, Pastora, 2021. "Evaluating ammonia as green fuel for power generation: A thermo-chemical perspective," Applied Energy, Elsevier, vol. 293(C).
  • Handle: RePEc:eee:appene:v:293:y:2021:i:c:s0306261921004323
    DOI: 10.1016/j.apenergy.2021.116956
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261921004323
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.apenergy.2021.116956?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Frate, Guido Francesco & Ferrari, Lorenzo & Desideri, Umberto, 2021. "Energy storage for grid-scale applications: Technology review and economic feasibility analysis," Renewable Energy, Elsevier, vol. 163(C), pages 1754-1772.
    2. Keller, Martin & Koshi, Mitsuo & Otomo, Junichiro & Iwasaki, Hiroshi & Mitsumori, Teruo & Yamada, Koichi, 2020. "Thermodynamic evaluation of an ammonia-fueled combined-cycle gas turbine process operated under fuel-rich conditions," Energy, Elsevier, vol. 194(C).
    3. Sadi, M. & Arabkoohsar, A., 2019. "Exergoeconomic analysis of a combined solar-waste driven power plant," Renewable Energy, Elsevier, vol. 141(C), pages 883-893.
    4. Wang, Ligang & Zhang, Yumeng & Pérez-Fortes, Mar & Aubin, Philippe & Lin, Tzu-En & Yang, Yongping & Maréchal, François & Van herle, Jan, 2020. "Reversible solid-oxide cell stack based power-to-x-to-power systems: Comparison of thermodynamic performance," Applied Energy, Elsevier, vol. 275(C).
    5. Mohammadi, Amin & Mehrpooya, Mehdi, 2018. "A comprehensive review on coupling different types of electrolyzer to renewable energy sources," Energy, Elsevier, vol. 158(C), pages 632-655.
    6. Milana Guteša Božo & Agustin Valera-Medina, 2020. "Prediction of Novel Humified Gas Turbine Cycle Parameters for Ammonia/Hydrogen Fuels," Energies, MDPI, vol. 13(21), pages 1-20, November.
    7. Child, Michael & Kemfert, Claudia & Bogdanov, Dmitrii & Breyer, Christian, 2019. "Flexible electricity generation, grid exchange and storage for the transition to a 100% renewable energy system in Europe," EconStor Open Access Articles and Book Chapters, ZBW - Leibniz Information Centre for Economics, vol. 139, pages 80-101.
    8. Zhang, Cong & Greenblatt, Jeffery B. & Wei, Max & Eichman, Josh & Saxena, Samveg & Muratori, Matteo & Guerra, Omar J., 2020. "Flexible grid-based electrolysis hydrogen production for fuel cell vehicles reduces costs and greenhouse gas emissions," Applied Energy, Elsevier, vol. 278(C).
    9. Ehrenstein, Michael & Galán-Martín, Ángel & Tulus, Victor & Guillén-Gosálbez, Gonzalo, 2020. "Optimising fuel supply chains within planetary boundaries: A case study of hydrogen for road transport in the UK," Applied Energy, Elsevier, vol. 276(C).
    10. Matzen, Michael & Alhajji, Mahdi & Demirel, Yaşar, 2015. "Chemical storage of wind energy by renewable methanol production: Feasibility analysis using a multi-criteria decision matrix," Energy, Elsevier, vol. 93(P1), pages 343-353.
    11. Gu, Chun-wei & Wang, Hao & Ji, Xing-xing & Li, Xue-song, 2016. "Development and application of a thermodynamic-cycle performance analysis method of a three-shaft gas turbine," Energy, Elsevier, vol. 112(C), pages 307-321.
    12. Cesaro, Zac & Ives, Matthew & Nayak-Luke, Richard & Mason, Mike & Bañares-Alcántara, René, 2021. "Ammonia to power: Forecasting the levelized cost of electricity from green ammonia in large-scale power plants," Applied Energy, Elsevier, vol. 282(PA).
    13. Ezzat, M.F. & Dincer, I., 2020. "Energy and exergy analyses of a novel ammonia combined power plant operating with gas turbine and solid oxide fuel cell systems," Energy, Elsevier, vol. 194(C).
    14. Meroueh, Laureen & Chen, Gang, 2020. "Thermal energy storage radiatively coupled to a supercritical Rankine cycle for electric grid support," Renewable Energy, Elsevier, vol. 145(C), pages 604-621.
    15. Guerras, Lidia S. & Martín, Mariano, 2019. "Optimal gas treatment and coal blending for reduced emissions in power plants: A case study in Northwest Spain," Energy, Elsevier, vol. 169(C), pages 739-749.
    16. Al-Qahtani, Amjad & González-Garay, Andrés & Bernardi, Andrea & Galán-Martín, Ángel & Pozo, Carlos & Dowell, Niall Mac & Chachuat, Benoit & Guillén-Gosálbez, Gonzalo, 2020. "Electricity grid decarbonisation or green methanol fuel? A life-cycle modelling and analysis of today′s transportation-power nexus," Applied Energy, Elsevier, vol. 265(C).
    17. Götz, Manuel & Lefebvre, Jonathan & Mörs, Friedemann & McDaniel Koch, Amy & Graf, Frank & Bajohr, Siegfried & Reimert, Rainer & Kolb, Thomas, 2016. "Renewable Power-to-Gas: A technological and economic review," Renewable Energy, Elsevier, vol. 85(C), pages 1371-1390.
    18. United Nations UN, 2015. "Transforming our World: the 2030 Agenda for Sustainable Development," Working Papers id:7559, eSocialSciences.
    19. Elishav, Oren & Lewin, Daniel R. & Shter, Gennady E. & Grader, Gideon S., 2017. "The nitrogen economy: Economic feasibility analysis of nitrogen-based fuels as energy carriers," Applied Energy, Elsevier, vol. 185(P1), pages 183-188.
    20. Fúnez Guerra, C. & Reyes-Bozo, L. & Vyhmeister, E. & Jaén Caparrós, M. & Salazar, José Luis & Clemente-Jul, C., 2020. "Technical-economic analysis for a green ammonia production plant in Chile and its subsequent transport to Japan," Renewable Energy, Elsevier, vol. 157(C), pages 404-414.
    21. Sonja Renssen, 2020. "The hydrogen solution?," Nature Climate Change, Nature, vol. 10(9), pages 799-801, September.
    22. Davis, William & Martín, Mariano, 2014. "Optimal year-round operation for methane production from CO2 and water using wind energy," Energy, Elsevier, vol. 69(C), pages 497-505.
    23. Valera-Medina, Agustin & Marsh, Richard & Runyon, Jon & Pugh, Daniel & Beasley, Paul & Hughes, Timothy & Bowen, Phil, 2017. "Ammonia–methane combustion in tangential swirl burners for gas turbine power generation," Applied Energy, Elsevier, vol. 185(P2), pages 1362-1371.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Rafael Estevez & Francisco J. López-Tenllado & Laura Aguado-Deblas & Felipa M. Bautista & Antonio A. Romero & Diego Luna, 2023. "Current Research on Green Ammonia (NH 3 ) as a Potential Vector Energy for Power Storage and Engine Fuels: A Review," Energies, MDPI, vol. 16(14), pages 1-33, July.
    2. Blanco, Elena C. & Sánchez, Antonio & Martín, Mariano & Vega, Pastora, 2023. "Methanol and ammonia as emerging green fuels: Evaluation of a new power generation paradigm," Renewable and Sustainable Energy Reviews, Elsevier, vol. 175(C).
    3. Zhao, Fei & Li, Yalou & Zhou, Xiaoxin & Wang, Dandan & Wei, Yawei & Li, Fang, 2023. "Co-optimization of decarbonized operation of coal-fired power plants and seasonal storage based on green ammonia co-firing," Applied Energy, Elsevier, vol. 341(C).
    4. García-Anteportalatina, Víctor Manuel & Martín, Mariano, 2022. "Process synthesis for the valorisation of low-grade heat: Geothermal brines and industrial waste streams," Renewable Energy, Elsevier, vol. 198(C), pages 733-748.
    5. Hookyung Lee & Min-Jung Lee, 2021. "Recent Advances in Ammonia Combustion Technology in Thermal Power Generation System for Carbon Emission Reduction," Energies, MDPI, vol. 14(18), pages 1-29, September.
    6. Grubert, E. & Zacarias, M., 2022. "Paradigm shifts for environmental assessment of decarbonizing energy systems: Emerging dominance of embodied impacts and design-oriented decision support needs," Renewable and Sustainable Energy Reviews, Elsevier, vol. 159(C).
    7. Pashchenko, Dmitry, 2023. "Hydrogen-rich gas as a fuel for the gas turbines: A pathway to lower CO2 emission," Renewable and Sustainable Energy Reviews, Elsevier, vol. 173(C).
    8. Georgi Todorov & Ivan Kralov & Ivailo Koprev & Hristo Vasilev & Iliyana Naydenova, 2024. "Coal Share Reduction Options for Power Generation during the Energy Transition: A Bulgarian Perspective," Energies, MDPI, vol. 17(4), pages 1-26, February.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Blanco, Elena C. & Sánchez, Antonio & Martín, Mariano & Vega, Pastora, 2023. "Methanol and ammonia as emerging green fuels: Evaluation of a new power generation paradigm," Renewable and Sustainable Energy Reviews, Elsevier, vol. 175(C).
    2. Sánchez, Antonio & Martín, Mariano & Zhang, Qi, 2021. "Optimal design of sustainable power-to-fuels supply chains for seasonal energy storage," Energy, Elsevier, vol. 234(C).
    3. Ayaz, S.Kagan & Altuntas, Onder & Caliskan, Hakan, 2021. "Enhanced life cycle modelling of a micro gas turbine fuelled with various fuels for sustainable electricity production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 149(C).
    4. Perčić, Maja & Vladimir, Nikola & Jovanović, Ivana & Koričan, Marija, 2022. "Application of fuel cells with zero-carbon fuels in short-sea shipping," Applied Energy, Elsevier, vol. 309(C).
    5. Andrea J. Boero & Kevin Kardux & Marina Kovaleva & Daniel A. Salas & Jacco Mooijer & Syed Mashruk & Michael Townsend & Kevin Rouwenhorst & Agustin Valera-Medina & Angel D. Ramirez, 2021. "Environmental Life Cycle Assessment of Ammonia-Based Electricity," Energies, MDPI, vol. 14(20), pages 1-20, October.
    6. Wen, Du & Aziz, Muhammad, 2022. "Techno-economic analyses of power-to-ammonia-to-power and biomass-to-ammonia-to-power pathways for carbon neutrality scenario," Applied Energy, Elsevier, vol. 319(C).
    7. Rafael Estevez & Francisco J. López-Tenllado & Laura Aguado-Deblas & Felipa M. Bautista & Antonio A. Romero & Diego Luna, 2023. "Current Research on Green Ammonia (NH 3 ) as a Potential Vector Energy for Power Storage and Engine Fuels: A Review," Energies, MDPI, vol. 16(14), pages 1-33, July.
    8. Byun, Manhee & Lim, Dongjun & Lee, Boreum & Kim, Ayeon & Lee, In-Beum & Brigljević, Boris & Lim, Hankwon, 2022. "Economically feasible decarbonization of the Haber-Bosch process through supercritical CO2 Allam cycle integration," Applied Energy, Elsevier, vol. 307(C).
    9. Mewafy, Abdelrahman & Ismael, Islam & Kaddah, Sahar S. & Hu, Weihao & Chen, Zhe & Abulanwar, Sayed, 2024. "Optimal design of multiuse hybrid microgrids power by green hydrogen–ammonia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 192(C).
    10. Ikäheimo, Jussi & Lindroos, Tomi J. & Kiviluoma, Juha, 2023. "Impact of climate and geological storage potential on feasibility of hydrogen fuels," Applied Energy, Elsevier, vol. 342(C).
    11. Iribarren, Diego & Martín-Gamboa, Mario & Navas-Anguita, Zaira & García-Gusano, Diego & Dufour, Javier, 2020. "Influence of climate change externalities on the sustainability-oriented prioritisation of prospective energy scenarios," Energy, Elsevier, vol. 196(C).
    12. Laslett, Dean & Carter, Craig & Creagh, Chris & Jennings, Philip, 2017. "A large-scale renewable electricity supply system by 2030: Solar, wind, energy efficiency, storage and inertia for the South West Interconnected System (SWIS) in Western Australia," Renewable Energy, Elsevier, vol. 113(C), pages 713-731.
    13. Johnathon, Chris & Agalgaonkar, Ashish Prakash & Planiden, Chayne & Kennedy, Joel, 2023. "A proposed hedge-based energy market model to manage renewable intermittency," Renewable Energy, Elsevier, vol. 207(C), pages 376-384.
    14. Muhammad Aziz & Agung Tri Wijayanta & Asep Bayu Dani Nandiyanto, 2020. "Ammonia as Effective Hydrogen Storage: A Review on Production, Storage and Utilization," Energies, MDPI, vol. 13(12), pages 1-25, June.
    15. Brynolf, Selma & Taljegard, Maria & Grahn, Maria & Hansson, Julia, 2018. "Electrofuels for the transport sector: A review of production costs," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P2), pages 1887-1905.
    16. Meylan, Frédéric D. & Moreau, Vincent & Erkman, Suren, 2016. "Material constraints related to storage of future European renewable electricity surpluses with CO2 methanation," Energy Policy, Elsevier, vol. 94(C), pages 366-376.
    17. Jafari, Mehdi & Botterud, Audun & Sakti, Apurba, 2022. "Decarbonizing power systems: A critical review of the role of energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 158(C).
    18. Skabelund, Brent B. & Stechel, Ellen B. & Milcarek, Ryan J., 2023. "Thermodynamic analysis of a gas turbine utilizing ternary CH4/H2/NH3 fuel blends," Energy, Elsevier, vol. 282(C).
    19. Hookyung Lee & Min-Jung Lee, 2021. "Recent Advances in Ammonia Combustion Technology in Thermal Power Generation System for Carbon Emission Reduction," Energies, MDPI, vol. 14(18), pages 1-29, September.
    20. Tawalbeh, Muhammad & Murtaza, Sana Z.M. & Al-Othman, Amani & Alami, Abdul Hai & Singh, Karnail & Olabi, Abdul Ghani, 2022. "Ammonia: A versatile candidate for the use in energy storage systems," Renewable Energy, Elsevier, vol. 194(C), pages 955-977.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:293:y:2021:i:c:s0306261921004323. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.