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A high-performance tri-electrolyte aluminum-air microfluidic cell with a co-laminar-flow-and-bridging-electrolyte configuration

Author

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  • Feng, Shan
  • Yang, Guandong
  • Zheng, Dawei
  • Rauf, Abdur
  • Khan, Ubaid
  • Cheng, Rui
  • Wang, Lei
  • Wang, Wentao
  • Liu, Fude

Abstract

The aluminum-air cell is one of the most promising candidates for next-generation power sources due to its high theoretical energy density. In particular, a tri-electrolyte aluminum-air cell shows high stability and cell voltage. However, the output power density is limited because of the increased internal resistance. Here, we demonstrate a tri-electrolyte aluminum-air microfluidic cell, which takes advantages of the bridging electrolyte and the co-laminar flow to separate the alkaline anolyte from the acidic catholyte. The novel cell structure helps to maintain high ion exchange efficiency, minimize the electrolyte neutralization, and improve the cell stability. The short-circuit current density and maximum power density at the first electrolyte cycle are up to 367.46 mA cm−2 and 189.22 mW cm−2, respectively; after 10 electrolyte cycles, the variation is less than 2.85% and 4.69%, respectively. The cell internal resistivity is 5.42, 5.41, and 5.55 Ω cm2 at cycle 1 under flow rates of 0.5, 1.0 and 2.0 ml min−1, respectively, which demonstrates the cell stability under flowing electrolytes. An integrated cell system assembled with 24 cells is further fabricated and evaluated. The short-circuit current only drops to half at cell electrolyte cycle 156 theoretically. Therefore, this work provides an alternative strategy for economical and long-lasting aluminum-air cells as less-frequent power sources.

Suggested Citation

  • Feng, Shan & Yang, Guandong & Zheng, Dawei & Rauf, Abdur & Khan, Ubaid & Cheng, Rui & Wang, Lei & Wang, Wentao & Liu, Fude, 2022. "A high-performance tri-electrolyte aluminum-air microfluidic cell with a co-laminar-flow-and-bridging-electrolyte configuration," Applied Energy, Elsevier, vol. 307(C).
  • Handle: RePEc:eee:appene:v:307:y:2022:i:c:s0306261921014409
    DOI: 10.1016/j.apenergy.2021.118168
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    References listed on IDEAS

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    1. Chen, Binbin & Leung, Dennis Y.C. & Xuan, Jin & Wang, Huizhi, 2017. "A mixed-pH dual-electrolyte microfluidic aluminum–air cell with high performance," Applied Energy, Elsevier, vol. 185(P2), pages 1303-1308.
    2. Shkolnikov, E.I. & Zhuk, A.Z. & Vlaskin, M.S., 2011. "Aluminum as energy carrier: Feasibility analysis and current technologies overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(9), pages 4611-4623.
    3. Jaechan Ryu & Haeseong Jang & Joohyuk Park & Youngshin Yoo & Minjoon Park & Jaephil Cho, 2018. "Seed-mediated atomic-scale reconstruction of silver manganate nanoplates for oxygen reduction towards high-energy aluminum-air flow batteries," Nature Communications, Nature, vol. 9(1), pages 1-10, December.
    4. Pemika Teabnamang & Wathanyu Kao-ian & Mai Thanh Nguyen & Tetsu Yonezawa & Rongrong Cheacharoen & Soorathep Kheawhom, 2020. "High-Capacity Dual-Electrolyte Aluminum–Air Battery with Circulating Methanol Anolyte," Energies, MDPI, vol. 13(9), pages 1-14, May.
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    1. Wei, Manhui & Wang, Keliang & Pei, Pucheng & Zuo, Yayu & Zhong, Liping & Shang, Nuo & Wang, Hengwei & Chen, Junfeng & Zhang, Pengfei & Chen, Zhuo, 2022. "An enhanced-performance Al-air battery optimizing the alkaline electrolyte with a strong Lewis acid ZnCl2," Applied Energy, Elsevier, vol. 324(C).
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