IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v186y2017ip1p13-27.html
   My bibliography  Save this article

Metal-water combustion for clean propulsion and power generation

Author

Listed:
  • Bergthorson, Jeffrey M.
  • Yavor, Yinon
  • Palecka, Jan
  • Georges, William
  • Soo, Michael
  • Vickery, James
  • Goroshin, Samuel
  • Frost, David L.
  • Higgins, Andrew J.

Abstract

Metals are energy-dense fuels that can react exothermically with water to produce hydrogen, and this hydrogen is useful as a propellant for rockets and underwater vehicles or as a fuel for engines and fuel cells. Propulsion systems usually rely on high-temperature combustion (T>3000K) of metal-water propellants, while hydrogen-production systems typically employ low reactor temperatures (T<100°C). This paper reviews the current state of knowledge of both low-temperature and high-temperature metal-water reactions. Low-temperature reactions allow only the chemical energy contained in the hydrogen to be used, with the thermal energy released during the metal-water reaction being wasted. Metal-water propulsion systems typically make use of only the thermal energy of the metal-water reaction, with the hydrogen being exhausted to produce thrust. This paper proposes several novel applications of high-temperature metal-water combustion that allow the full chemical energy within the metal fuel to be harnessed, including high-speed air-breathing engines and high-power, compact, low-emissions power-generation systems. These technologies promise improved performance by maximizing the conversion of the chemical energy, stored within the metal fuel, into useful work at sufficient rates for high-power applications.

Suggested Citation

  • Bergthorson, Jeffrey M. & Yavor, Yinon & Palecka, Jan & Georges, William & Soo, Michael & Vickery, James & Goroshin, Samuel & Frost, David L. & Higgins, Andrew J., 2017. "Metal-water combustion for clean propulsion and power generation," Applied Energy, Elsevier, vol. 186(P1), pages 13-27.
  • Handle: RePEc:eee:appene:v:186:y:2017:i:p1:p:13-27
    DOI: 10.1016/j.apenergy.2016.10.033
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261916314726
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.apenergy.2016.10.033?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Long, Huiling & Li, Xiaobing & Wang, Hong & Jia, Jingdun, 2013. "Biomass resources and their bioenergy potential estimation: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 26(C), pages 344-352.
    2. Wang, Huizhi & Leung, Dennis Y.C. & Leung, Michael K.H., 2012. "Energy analysis of hydrogen and electricity production from aluminum-based processes," Applied Energy, Elsevier, vol. 90(1), pages 100-105.
    3. Bergthorson, Jeffrey M. & Thomson, Murray J., 2015. "A review of the combustion and emissions properties of advanced transportation biofuels and their impact on existing and future engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1393-1417.
    4. Igobo, Opubo N. & Davies, Philip A., 2014. "Review of low-temperature vapour power cycle engines with quasi-isothermal expansion," Energy, Elsevier, vol. 70(C), pages 22-34.
    5. Schiemann, Martin & Bergthorson, Jeffrey & Fischer, Peter & Scherer, Viktor & Taroata, Dan & Schmid, Günther, 2016. "A review on lithium combustion," Applied Energy, Elsevier, vol. 162(C), pages 948-965.
    6. Kongtragool, Bancha & Wongwises, Somchai, 2003. "A review of solar-powered Stirling engines and low temperature differential Stirling engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 7(2), pages 131-154, April.
    7. Mazloomi, Kaveh & Gomes, Chandima, 2012. "Hydrogen as an energy carrier: Prospects and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 3024-3033.
    8. Jacobson, Mark Z. & Delucchi, Mark A., 2011. "Providing all global energy with wind, water, and solar power, Part I: Technologies, energy resources, quantities and areas of infrastructure, and materials," Energy Policy, Elsevier, vol. 39(3), pages 1154-1169, March.
    9. Menten, Fabio & Chèze, Benoît & Patouillard, Laure & Bouvart, Frédérique, 2013. "A review of LCA greenhouse gas emissions results for advanced biofuels: The use of meta-regression analysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 26(C), pages 108-134.
    10. Hammerschlag, Roel & Mazza, Patrick, 2005. "Questioning hydrogen," Energy Policy, Elsevier, vol. 33(16), pages 2039-2043, November.
    11. Budzianowski, Wojciech M., 2012. "Negative carbon intensity of renewable energy technologies involving biomass or carbon dioxide as inputs," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(9), pages 6507-6521.
    12. Shkolnikov, E.I. & Zhuk, A.Z. & Vlaskin, M.S., 2011. "Aluminum as energy carrier: Feasibility analysis and current technologies overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(9), pages 4611-4623.
    13. Denholm, Paul & Margolis, Robert M., 2008. "Land-use requirements and the per-capita solar footprint for photovoltaic generation in the United States," Energy Policy, Elsevier, vol. 36(9), pages 3531-3543, September.
    14. Bergthorson, J.M. & Goroshin, S. & Soo, M.J. & Julien, P. & Palecka, J. & Frost, D.L. & Jarvis, D.J., 2015. "Direct combustion of recyclable metal fuels for zero-carbon heat and power," Applied Energy, Elsevier, vol. 160(C), pages 368-382.
    15. Wang, H.Z. & Leung, D.Y.C. & Leung, M.K.H. & Ni, M., 2009. "A review on hydrogen production using aluminum and aluminum alloys," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(4), pages 845-853, May.
    16. Dunham, Marc T. & Iverson, Brian D., 2014. "High-efficiency thermodynamic power cycles for concentrated solar power systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 30(C), pages 758-770.
    17. Auner, Norbert & Holl, Sven, 2006. "Silicon as energy carrier—Facts and perspectives," Energy, Elsevier, vol. 31(10), pages 1395-1402.
    18. Zhou, Li, 2005. "Progress and problems in hydrogen storage methods," Renewable and Sustainable Energy Reviews, Elsevier, vol. 9(4), pages 395-408, August.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Janicka, J. & Debiagi, P. & Scholtissek, A. & Dreizler, A. & Epple, B. & Pawellek, R. & Maltsev, A. & Hasse, C., 2023. "The potential of retrofitting existing coal power plants: A case study for operation with green iron," Applied Energy, Elsevier, vol. 339(C).
    2. Bozorg, Mehdi Vahabzadeh & Doranehgard, Mohammad Hossein & Hong, Kun & Xiong, Qingang & Li, Larry K.B., 2020. "A numerical study on discrete combustion of polydisperse magnesium aero-suspensions," Energy, Elsevier, vol. 194(C).
    3. Li, Chaolong & Xia, Zhixun & Ma, Likun & Chen, Binbin & Feng, Yunchao & Zhang, Jiarui & Duan, Yifan, 2023. "Performance analysis on the specific impulse and specific thrust of scramjet with a quasi-one-dimensional model," Energy, Elsevier, vol. 267(C).
    4. Liangchuan Wei & Bing Guo & Nanyi Li & Zhonghao Heng, 2023. "Design and Internal Flow Characteristic Investigation of High-Temperature H 2 /Steam-Mixed Working Fluid Turbine," Energies, MDPI, vol. 16(13), pages 1-19, June.
    5. Maas, Pascal & Schiemann, Martin & Scherer, Viktor & Fischer, Peter & Taroata, Dan & Schmid, Günther, 2018. "Lithium as energy carrier: CFD simulations of LI combustion in a 100MW slag tap furnace," Applied Energy, Elsevier, vol. 227(C), pages 506-515.
    6. Oruc, Onur & Dincer, Ibrahim, 2021. "Development and performance assessment power generating systems using clean hydrogen," Energy, Elsevier, vol. 215(PB).
    7. Xinyue Gao & Chang’an Wang & Wengang Bai & Yujie Hou & Defu Che, 2022. "Aluminum-Based Fuels as Energy Carriers for Controllable Power and Hydrogen Generation—A Review," Energies, MDPI, vol. 16(1), pages 1-22, December.
    8. Yuan, Yupeng & Wang, Jixiang & Yan, Xinping & Shen, Boyang & Long, Teng, 2020. "A review of multi-energy hybrid power system for ships," Renewable and Sustainable Energy Reviews, Elsevier, vol. 132(C).
    9. Trowell, K.A. & Goroshin, S. & Frost, D.L. & Bergthorson, J.M., 2020. "Aluminum and its role as a recyclable, sustainable carrier of renewable energy," Applied Energy, Elsevier, vol. 275(C).
    10. Debiagi, P. & Rocha, R.C. & Scholtissek, A. & Janicka, J. & Hasse, C., 2022. "Iron as a sustainable chemical carrier of renewable energy: Analysis of opportunities and challenges for retrofitting coal-fired power plants," Renewable and Sustainable Energy Reviews, Elsevier, vol. 165(C).
    11. Zhuk, A.Z. & Shkolnikov, E.I. & Borodina, T.I. & Valiano, G.E. & Dolzhenko, A.V. & Kiseleva, E.A. & Kochanova, S.A. & Filippov, E.D. & Semenova, V.A., 2023. "Aluminium – Water hydrogen generator for domestic and mobile application," Applied Energy, Elsevier, vol. 334(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Bergthorson, J.M. & Goroshin, S. & Soo, M.J. & Julien, P. & Palecka, J. & Frost, D.L. & Jarvis, D.J., 2015. "Direct combustion of recyclable metal fuels for zero-carbon heat and power," Applied Energy, Elsevier, vol. 160(C), pages 368-382.
    2. Maas, Pascal & Schiemann, Martin & Scherer, Viktor & Fischer, Peter & Taroata, Dan & Schmid, Günther, 2018. "Lithium as energy carrier: CFD simulations of LI combustion in a 100MW slag tap furnace," Applied Energy, Elsevier, vol. 227(C), pages 506-515.
    3. Trowell, K.A. & Goroshin, S. & Frost, D.L. & Bergthorson, J.M., 2020. "Aluminum and its role as a recyclable, sustainable carrier of renewable energy," Applied Energy, Elsevier, vol. 275(C).
    4. Schiemann, Martin & Bergthorson, Jeffrey & Fischer, Peter & Scherer, Viktor & Taroata, Dan & Schmid, Günther, 2016. "A review on lithium combustion," Applied Energy, Elsevier, vol. 162(C), pages 948-965.
    5. Bergthorson, Jeffrey M. & Thomson, Murray J., 2015. "A review of the combustion and emissions properties of advanced transportation biofuels and their impact on existing and future engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1393-1417.
    6. Garra, Patxi & Leyssens, Gontrand & Allgaier, Olivier & Schönnenbeck, Cornelius & Tschamber, Valérie & Brilhac, Jean-François & Tahtouh, Toni & Guézet, Olivier & Allano, Sylvain, 2017. "Magnesium/air combustion at pilot scale and subsequent PM and NOx emissions," Applied Energy, Elsevier, vol. 189(C), pages 578-587.
    7. Fayaz, H. & Saidur, R. & Razali, N. & Anuar, F.S. & Saleman, A.R. & Islam, M.R., 2012. "An overview of hydrogen as a vehicle fuel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(8), pages 5511-5528.
    8. Debiagi, P. & Rocha, R.C. & Scholtissek, A. & Janicka, J. & Hasse, C., 2022. "Iron as a sustainable chemical carrier of renewable energy: Analysis of opportunities and challenges for retrofitting coal-fired power plants," Renewable and Sustainable Energy Reviews, Elsevier, vol. 165(C).
    9. Janicka, J. & Debiagi, P. & Scholtissek, A. & Dreizler, A. & Epple, B. & Pawellek, R. & Maltsev, A. & Hasse, C., 2023. "The potential of retrofitting existing coal power plants: A case study for operation with green iron," Applied Energy, Elsevier, vol. 339(C).
    10. Wang, Hongqi & Wang, Zhi & Shi, Zhihao & Gong, Xuzhong & Cao, Jianwei & Wang, Mingyong, 2017. "Facile hydrogen production from Al-water reaction promoted by choline hydroxide," Energy, Elsevier, vol. 131(C), pages 98-105.
    11. Yang, Weijuan & Zhang, Tianyou & Liu, Jianzhong & Wang, Zhihua & Zhou, Junhu & Cen, Kefa, 2015. "Experimental researches on hydrogen generation by aluminum with adding lithium at high temperature," Energy, Elsevier, vol. 93(P1), pages 451-457.
    12. Shkolnikov, E.I. & Zhuk, A.Z. & Vlaskin, M.S., 2011. "Aluminum as energy carrier: Feasibility analysis and current technologies overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(9), pages 4611-4623.
    13. Gai, Wei-Zhuo & Deng, Zhen-Yan, 2024. "Enhanced hydrogen production from Al-water reaction: Strategies, performances, mechanisms and applications," Renewable Energy, Elsevier, vol. 226(C).
    14. Haller, Michel Y. & Amstad, Dominik & Dudita, Mihaela & Englert, Alexander & Häberle, Andreas, 2021. "Combined heat and power production based on renewable aluminium-water reaction," Renewable Energy, Elsevier, vol. 174(C), pages 879-893.
    15. Yang, Weijuan & Zhang, Tianyou & Zhou, Junhu & Shi, Wei & Liu, Jianzhong & Cen, Kefa, 2015. "Experimental study on the effect of low melting point metal additives on hydrogen production in the aluminum–water reaction," Energy, Elsevier, vol. 88(C), pages 537-543.
    16. Alizadeh, Reza & Lund, Peter D. & Soltanisehat, Leili, 2020. "Outlook on biofuels in future studies: A systematic literature review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 134(C).
    17. Wang, Yifei & Kwok, Holly Y.H. & Pan, Wending & Zhang, Huimin & Lu, Xu & Leung, Dennis Y.C., 2019. "Parametric study and optimization of a low-cost paper-based Al-air battery with corrosion inhibition ability," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    18. Bennett, Carly & Blanchet, Jocelyn & Trowell, Keena & Bergthorson, Jeffrey, 2023. "Decarbonizing Canada’s energy supply and exports with solar PV and e-fuels," Renewable Energy, Elsevier, vol. 217(C).
    19. Capellán-Pérez, Iñigo & de Castro, Carlos & Arto, Iñaki, 2017. "Assessing vulnerabilities and limits in the transition to renewable energies: Land requirements under 100% solar energy scenarios," Renewable and Sustainable Energy Reviews, Elsevier, vol. 77(C), pages 760-782.
    20. Pérez-Denicia, Eduardo & Fernández-Luqueño, Fabián & Vilariño-Ayala, Darnes & Manuel Montaño-Zetina, Luis & Alfonso Maldonado-López, Luis, 2017. "Renewable energy sources for electricity generation in Mexico: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 78(C), pages 597-613.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:186:y:2017:i:p1:p:13-27. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.