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Towards highly efficient electrochemical CO2 reduction: Cell designs, membranes and electrocatalysts

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  • Tufa, Ramato Ashu
  • Chanda, Debabrata
  • Ma, Ming
  • Aili, David
  • Demissie, Taye Beyene
  • Vaes, Jan
  • Li, Qingfeng
  • Liu, Shanhu
  • Pant, Deepak

Abstract

An increase in atmospheric CO2 concentration is directly associated with the rising concerns of climate change and energy issues. The development of effective technologies for capture and utilization of atmospheric CO2 is required to mitigate these global challenges. Electrochemical CO2 reduction (eCO2R) is one of the most promising approaches for the conversion of excess renewable energy sources into storable fuels and value-added chemicals. This field has recently advanced enormously with impressive research achievements aiming at bringing the technology on the brink of commercial realization. Herein, we present a comprehensive review analyzing the recent progress and opportunities of using different cell designs with the main focus on membrane-based flow cells for eCO2R, along with the required system-level strategies for optimal engineering to enhance electrocatalytic selectivity and efficiency. Research advance on the use of different polymer electrolyte membranes for CO2 electrolyzers is updated. Main achievements in new catalyst discoveries are assessed in terms of activity, selectivity, stability together with CO2R reaction kinetics. This was supported by the analysis of the computational studies performed to devise the effective catalyst design routes and to understand the pathways for CO2Rs. The interactive effect of the design of reactors and gas diffusion electrodes with catalysts is analyzed for different operating conditions (like pH, temperature and pressure) of CO2 electrolyzers. Finally, an outlook on future research directions in terms of material and process design for a breakthrough in eCO2R technologies is provided.

Suggested Citation

  • Tufa, Ramato Ashu & Chanda, Debabrata & Ma, Ming & Aili, David & Demissie, Taye Beyene & Vaes, Jan & Li, Qingfeng & Liu, Shanhu & Pant, Deepak, 2020. "Towards highly efficient electrochemical CO2 reduction: Cell designs, membranes and electrocatalysts," Applied Energy, Elsevier, vol. 277(C).
    • Handle: RePEc:eee:appene:v:277:y:2020:i:c:s0306261920310692
    DOI: 10.1016/j.apenergy.2020.115557
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    1. Pranav P. Sharma & Xiao‐Dong Zhou, 2017. "Electrocatalytic conversion of carbon dioxide to fuels: a review on the interaction between CO2 and the liquid electrolyte," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 6(4), July.
    2. Vincent, Immanuel & Bessarabov, Dmitri, 2018. "Low cost hydrogen production by anion exchange membrane electrolysis: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P2), pages 1690-1704.
    3. Lu, Xu & Leung, Dennis Y.C. & Wang, Huizhi & Xuan, Jin, 2018. "Microfluidics-based pH-differential reactor for CO2 utilization: A mathematical study," Applied Energy, Elsevier, vol. 227(C), pages 525-532.
    4. Wang, Huizhi & Leung, Dennis Y.C. & Xuan, Jin, 2013. "Modeling of a microfluidic electrochemical cell for CO2 utilization and fuel production," Applied Energy, Elsevier, vol. 102(C), pages 1057-1062.
    5. Chuan Xia & Peng Zhu & Qiu Jiang & Ying Pan & Wentao Liang & Eli Stavitski & Husam N. Alshareef & Haotian Wang, 2019. "Continuous production of pure liquid fuel solutions via electrocatalytic CO2 reduction using solid-electrolyte devices," Nature Energy, Nature, vol. 4(9), pages 776-785, September.
    6. Del Castillo, A. & Alvarez-Guerra, M. & Solla-Gullón, J. & Sáez, A. & Montiel, V. & Irabien, A., 2015. "Electrocatalytic reduction of CO2 to formate using particulate Sn electrodes: Effect of metal loading and particle size," Applied Energy, Elsevier, vol. 157(C), pages 165-173.
    7. Christina W. Li & Jim Ciston & Matthew W. Kanan, 2014. "Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper," Nature, Nature, vol. 508(7497), pages 504-507, April.
    8. Fu, Yishu & Li, Yanan & Zhang, Xia & Liu, Yuyu & Qiao, Jinli & Zhang, Jiujun & Wilkinson, David P., 2016. "Novel hierarchical SnO2 microsphere catalyst coated on gas diffusion electrode for enhancing energy efficiency of CO2 reduction to formate fuel," Applied Energy, Elsevier, vol. 175(C), pages 536-544.
    9. Marcel Schreier & Florent Héroguel & Ludmilla Steier & Shahzada Ahmad & Jeremy S. Luterbacher & Matthew T. Mayer & Jingshan Luo & Michael Grätzel, 2017. "Solar conversion of CO2 to CO using Earth-abundant electrocatalysts prepared by atomic layer modification of CuO," Nature Energy, Nature, vol. 2(7), pages 1-9, July.
    10. Lu, Xu & Leung, Dennis Y.C. & Wang, Huizhi & Maroto-Valer, M. Mercedes & Xuan, Jin, 2016. "A pH-differential dual-electrolyte microfluidic electrochemical cells for CO2 utilization," Renewable Energy, Elsevier, vol. 95(C), pages 277-285.
    11. Nikiforov, A.V. & Petrushina, I.M. & Christensen, E. & Berg, R.W. & Bjerrum, N.J., 2020. "Voltammetric study of one-step electrochemical methane production during water and CO2 co-electrolysis in molten CsH2PO4," Renewable Energy, Elsevier, vol. 145(C), pages 508-513.
    12. Grace, Andrews Nirmala & Choi, Song Yi & Vinoba, Mari & Bhagiyalakshmi, Margandan & Chu, Dae Hyun & Yoon, Yeoil & Nam, Sung Chan & Jeong, Soon Kwan, 2014. "Electrochemical reduction of carbon dioxide at low overpotential on a polyaniline/Cu2O nanocomposite based electrode," Applied Energy, Elsevier, vol. 120(C), pages 85-94.
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    1. Fu, Hongming & Xue, Kaili & Li, Zhaohao & Zhang, Heng & Gao, Dan & Chen, Haiping, 2023. "Study on the performance of CO2 capture from flue gas with ceramic and PTFE membrane contactors," Energy, Elsevier, vol. 263(PA).
    2. Zhou, Chenyang & Zhang, Chen & Zhang, Teng & Zhang, Jingfeng & Ma, Pengfei & Yu, Yunsong & Zhang, Zaoxiao & Wang, Geoff G.X., 2023. "Single-atom solutions promote carbon dioxide capture," Applied Energy, Elsevier, vol. 332(C).
    3. Chai, Rukuan & Liu, Yuetian & Wang, Jingru & Liu, Qianjun & Rui, Zhenhua, 2022. "CO2 utilization and sequestration in Reservoir: Effects and mechanisms of CO2 electrochemical reduction," Applied Energy, Elsevier, vol. 323(C).
    4. Lowy, Daniel A. & Melendez, Jesus R. & Mátyás, Bence, 2024. "Electroreduction of carbon dioxide to liquid fuels: A low-cost, sustainable technology," Renewable and Sustainable Energy Reviews, Elsevier, vol. 194(C).
    5. Agliuzza, Matteo & Mezza, Alessio & Sacco, Adriano, 2023. "Solar-driven integrated carbon capture and utilization: Coupling CO2 electroreduction toward CO with capture or photovoltaic systems," Applied Energy, Elsevier, vol. 334(C).

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