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Influence of low-temperature electrolyser design on economic and environmental potential of CO and HCOOH production: A techno-economic assessment

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  • Pribyl-Kranewitter, B.
  • Beard, A.
  • Gîjiu, C.L.
  • Dinculescu, D.
  • Schmidt, T.J.

Abstract

The electrochemical conversion of excess CO2 into valuable chemicals, such as carbon monoxide (CO) and formic acid (HCOOH) offers the possibility of combating climate change, while simultaneously providing sustainable raw materials for the chemical industry. The system design choice has large implications for the economic competitiveness of such processes. The impact of low-temperature electrolyser design on the economic potential of CO and HCOOH production was investigated alongside an environmental assessment of the required chemical plants. Six different cell architectures were analysed in a base and an optimistic case scenario with a target production of 75 and 100 tProduct/day, respectively, and a projected plant lifetime of 25 years. While none of the CO architectures managed to operate profitably in the base case, the modelling of both HCOOH architectures yielded a positive economic outcome. The CO producing systems showed an on average 22% greater performance improvement in the optimistic case, compared to HCOOH. The environmental potential to act as a carbon sink was determined through an analysis of the CO2 emissions due to heat and electricity demand as well as the CO2 utilisation of the systems. While HCOOH production requires clean electricity with maximum carbon intensities of 137 gCO2/kWh in the optimistic case, CO production only requires a maximum of 346 gCO2/kWh, which is well above the current EU electricity mix of 235 gCO2/kWh.

Suggested Citation

  • Pribyl-Kranewitter, B. & Beard, A. & Gîjiu, C.L. & Dinculescu, D. & Schmidt, T.J., 2022. "Influence of low-temperature electrolyser design on economic and environmental potential of CO and HCOOH production: A techno-economic assessment," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
  • Handle: RePEc:eee:rensus:v:154:y:2022:i:c:s1364032121010765
    DOI: 10.1016/j.rser.2021.111807
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    as
    1. Cameron Hepburn & Ella Adlen & John Beddington & Emily A. Carter & Sabine Fuss & Niall Mac Dowell & Jan C. Minx & Pete Smith & Charlotte K. Williams, 2019. "The technological and economic prospects for CO2 utilization and removal," Nature, Nature, vol. 575(7781), pages 87-97, November.
    2. Lu, Xu & Leung, Dennis Y.C. & Wang, Huizhi & Xuan, Jin, 2017. "Characterization of a microfluidic reactor for CO2 conversion with electrolyte recycling," Renewable Energy, Elsevier, vol. 102(PA), pages 15-20.
    3. Mohammad Asadi & Bijandra Kumar & Amirhossein Behranginia & Brian A. Rosen & Artem Baskin & Nikita Repnin & Davide Pisasale & Patrick Phillips & Wei Zhu & Richard Haasch & Robert F. Klie & Petr Král &, 2014. "Robust carbon dioxide reduction on molybdenum disulphide edges," Nature Communications, Nature, vol. 5(1), pages 1-8, December.
    4. Ganesh, Ibram, 2016. "Electrochemical conversion of carbon dioxide into renewable fuel chemicals – The role of nanomaterials and the commercialization," Renewable and Sustainable Energy Reviews, Elsevier, vol. 59(C), pages 1269-1297.
    5. Herz, Gregor & Reichelt, Erik & Jahn, Matthias, 2018. "Techno-economic analysis of a co-electrolysis-based synthesis process for the production of hydrocarbons," Applied Energy, Elsevier, vol. 215(C), pages 309-320.
    6. Chuan Xia & Peng Zhu & Qiu Jiang & Ying Pan & Wentao Liang & Eli Stavitski & Husam N. Alshareef & Haotian Wang, 2019. "Continuous production of pure liquid fuel solutions via electrocatalytic CO2 reduction using solid-electrolyte devices," Nature Energy, Nature, vol. 4(9), pages 776-785, September.
    7. Ji Hoon Lee & Shyam Kattel & Zhao Jiang & Zhenhua Xie & Siyu Yao & Brian M. Tackett & Wenqian Xu & Nebojsa S. Marinkovic & Jingguang G. Chen, 2019. "Tuning the activity and selectivity of electroreduction of CO2 to synthesis gas using bimetallic catalysts," Nature Communications, Nature, vol. 10(1), pages 1-8, December.
    8. Jingjie Wu & Sichao Ma & Jing Sun & Jake I. Gold & ChandraSekhar Tiwary & Byoungsu Kim & Lingyang Zhu & Nitin Chopra & Ihab N. Odeh & Robert Vajtai & Aaron Z. Yu & Raymond Luo & Jun Lou & Guqiao Ding , 2016. "A metal-free electrocatalyst for carbon dioxide reduction to multi-carbon hydrocarbons and oxygenates," Nature Communications, Nature, vol. 7(1), pages 1-6, December.
    9. Wen Ju & Alexander Bagger & Guang-Ping Hao & Ana Sofia Varela & Ilya Sinev & Volodymyr Bon & Beatriz Roldan Cuenya & Stefan Kaskel & Jan Rossmeisl & Peter Strasser, 2017. "Understanding activity and selectivity of metal-nitrogen-doped carbon catalysts for electrochemical reduction of CO2," Nature Communications, Nature, vol. 8(1), pages 1-9, December.
    10. Min Wang & Kristian Torbensen & Danielle Salvatore & Shaoxuan Ren & Dorian Joulié & Fabienne Dumoulin & Daniela Mendoza & Benedikt Lassalle-Kaiser & Umit Işci & Curtis P. Berlinguette & Marc Robert, 2019. "CO2 electrochemical catalytic reduction with a highly active cobalt phthalocyanine," Nature Communications, Nature, vol. 10(1), pages 1-8, December.
    11. Jonggeol Na & Bora Seo & Jeongnam Kim & Chan Woo Lee & Hyunjoo Lee & Yun Jeong Hwang & Byoung Koun Min & Dong Ki Lee & Hyung-Suk Oh & Ung Lee, 2019. "General technoeconomic analysis for electrochemical coproduction coupling carbon dioxide reduction with organic oxidation," Nature Communications, Nature, vol. 10(1), pages 1-13, December.
    12. Dohyung Kim & Joaquin Resasco & Yi Yu & Abdullah Mohamed Asiri & Peidong Yang, 2014. "Synergistic geometric and electronic effects for electrochemical reduction of carbon dioxide using gold–copper bimetallic nanoparticles," Nature Communications, Nature, vol. 5(1), pages 1-8, December.
    13. Lu, Xu & Leung, Dennis Y.C. & Wang, Huizhi & Maroto-Valer, M. Mercedes & Xuan, Jin, 2016. "A pH-differential dual-electrolyte microfluidic electrochemical cells for CO2 utilization," Renewable Energy, Elsevier, vol. 95(C), pages 277-285.
    14. Qi Lu & Jonathan Rosen & Yang Zhou & Gregory S. Hutchings & Yannick C. Kimmel & Jingguang G. Chen & Feng Jiao, 2014. "A selective and efficient electrocatalyst for carbon dioxide reduction," Nature Communications, Nature, vol. 5(1), pages 1-6, May.
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