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Catalytic pyrolytic platform for scrap tires using CO2 and steel slag

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  • Cho, Seong-Heon
  • Oh, Jeong-Ik
  • Jung, Sungyup
  • Park, Young-Kwon
  • Tsang, Yiu Fai
  • Ok, Yong Sik
  • Kwon, Eilhann E.

Abstract

This study specifically examined CO2-cofeeding pyrolysis of scrap tire (ST) to enhance H2 generation. Thus, volatile pyrolysates (syngas and pyrolytic oil) from the thermolysis of ST in N2 and CO2 were compared to elucidate the mechanistic roles of CO2. To this end, laboratory scale of pyrolysis of ST from N2 and CO2 was conducted in this study. The gaseous effluents from a pyrolyzer showed that enhanced CO evolution only from CO2-cofeeding pyrolysis of ST. Moreover, a substantial decrease in the formation of benzene derivatives (BDs) including polycyclic aromatic hydrocarbons (PAHs) was discovered from CO2-cofeeding pyrolysis of ST. Those findings offered that CO2 could improve pyrolysis of ST by modifying the pyrogenic products, and those enhanced pyrolysis behaviors were ascribed to the homogeneous interaction between CO2 and pyrolysates from the pyrolysis of ST (more CO generation). To advance the identified roles of CO2, catalytic pyrolysis of ST in CO2 was carried out using steel slag (SS) as a catalyst. In the presence of SS, the effectiveness of CO2 on pyrolysis of ST was dramatically enhanced (~400% enhancement at 400 °C). Therefore, this study experimentally justified that the utilization of SS could alleviate the environmental burdens by adopting CO2 in pyrolysis of ST. Also, the CO enhancement by CO2 likely leads to the H2 enhancement when the water-gas-shift (WGS) reaction was also conducted. All experimental findings from this study suggested that the use of CO2 in pyrolysis of ST could be a breakthrough to enhance H2 formation.

Suggested Citation

  • Cho, Seong-Heon & Oh, Jeong-Ik & Jung, Sungyup & Park, Young-Kwon & Tsang, Yiu Fai & Ok, Yong Sik & Kwon, Eilhann E., 2020. "Catalytic pyrolytic platform for scrap tires using CO2 and steel slag," Applied Energy, Elsevier, vol. 259(C).
    • Handle: RePEc:eee:appene:v:259:y:2020:i:c:s0306261919318513
    DOI: 10.1016/j.apenergy.2019.114164
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    References listed on IDEAS

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    1. Kim, Jung-Hun & Oh, Jeong-Ik & Lee, Jechan & Kwon, Eilhann E., 2019. "Valorization of sewage sludge via a pyrolytic platform using carbon dioxide as a reactive gas medium," Energy, Elsevier, vol. 179(C), pages 163-172.
    2. Mokrzycki, Eugeniusz & Uliasz-Bochenczyk, Alicja & Sarna, Mieczyslaw, 2003. "Use of alternative fuels in the Polish cement industry," Applied Energy, Elsevier, vol. 74(1-2), pages 101-111, January.
    3. Choi, Gyung-Goo & Oh, Seung-Jin & Kim, Joo-Sik, 2016. "Scrap tire pyrolysis using a new type two-stage pyrolyzer: Effects of dolomite and olivine on producing a low-sulfur pyrolysis oil," Energy, Elsevier, vol. 114(C), pages 457-464.
    4. Porzio, Giacomo Filippo & Colla, Valentina & Fornai, Barbara & Vannucci, Marco & Larsson, Mikael & Stripple, Håkan, 2016. "Process integration analysis and some economic-environmental implications for an innovative environmentally friendly recovery and pre-treatment of steel scrap," Applied Energy, Elsevier, vol. 161(C), pages 656-672.
    5. Hita, Idoia & Arabiourrutia, Miriam & Olazar, Martin & Bilbao, Javier & Arandes, José María & Castaño, Pedro, 2016. "Opportunities and barriers for producing high quality fuels from the pyrolysis of scrap tires," Renewable and Sustainable Energy Reviews, Elsevier, vol. 56(C), pages 745-759.
    6. Kumaravel, S.T. & Murugesan, A. & Kumaravel, A., 2016. "Tyre pyrolysis oil as an alternative fuel for diesel engines – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 60(C), pages 1678-1685.
    7. Mokrzycki, Eugeniusz & Uliasz- Bochenczyk, Alicja, 2003. "Alternative fuels for the cement industry," Applied Energy, Elsevier, vol. 74(1-2), pages 95-100, January.
    8. Sharma, V. K. & Fortuna, F. & Mincarini, M. & Berillo, M. & Cornacchia, G., 2000. "Disposal of waste tyres for energy recovery and safe environment," Applied Energy, Elsevier, vol. 65(1-4), pages 381-394, April.
    9. Lee, Jong Min & Lee, Jung Soo & Kim, Jung Rae & Kim, Sang Done, 1995. "Pyrolysis of waste tires with partial oxidation in a fluidized-bed reactor," Energy, Elsevier, vol. 20(10), pages 969-976.
    10. Erans, María & Manovic, Vasilije & Anthony, Edward J., 2016. "Calcium looping sorbents for CO2 capture," Applied Energy, Elsevier, vol. 180(C), pages 722-742.
    11. Czajczyńska, Dina & Krzyżyńska, Renata & Jouhara, Hussam & Spencer, Nik, 2017. "Use of pyrolytic gas from waste tire as a fuel: A review," Energy, Elsevier, vol. 134(C), pages 1121-1131.
    12. Martínez, Juan Daniel & Puy, Neus & Murillo, Ramón & García, Tomás & Navarro, María Victoria & Mastral, Ana Maria, 2013. "Waste tyre pyrolysis – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 23(C), pages 179-213.
    13. Policella, Matteo & Wang, Zhiwei & Burra, Kiran. G. & Gupta, Ashwani K., 2019. "Characteristics of syngas from pyrolysis and CO2-assisted gasification of waste tires," Applied Energy, Elsevier, vol. 254(C).
    14. Choi, Gyung-Goo & Oh, Seung-Jin & Kim, Joo-Sik, 2016. "Non-catalytic pyrolysis of scrap tires using a newly developed two-stage pyrolyzer for the production of a pyrolysis oil with a low sulfur content," Applied Energy, Elsevier, vol. 170(C), pages 140-147.
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    2. Song, Weiming & Huang, Yifeng & Chen, Xiaoqing & Jiang, Rui & Li, Yujie & Zhou, Jianan, 2023. "CO2 gasification of dry quenching dust ash catalyzed in situ by soot," Renewable Energy, Elsevier, vol. 211(C), pages 595-606.
    3. Di Gao & Fu-Ping Wang & Yi-Tong Wang & Ya-Nan Zeng, 2020. "Sustainable Utilization of Steel Slag from Traditional Industry and Agriculture to Catalysis," Sustainability, MDPI, vol. 12(21), pages 1-9, November.
    4. Wang, Chi-Hwa & Ok, Yong Sik & You, Siming & Wang, Xiaonan, 2020. "The research and development of waste-to-hydrogen technologies and systems," Applied Energy, Elsevier, vol. 268(C).
    5. Pedro Mora & Arturo Alarcón & Sandra Tercero & Bernardo Llamas, 2021. "Method to assess biomass in scrap tires: Spanish cement sector as a case study," Environment, Development and Sustainability: A Multidisciplinary Approach to the Theory and Practice of Sustainable Development, Springer, vol. 23(6), pages 8524-8541, June.
    6. Arabiourrutia, Miriam & Lopez, Gartzen & Artetxe, Maite & Alvarez, Jon & Bilbao, Javier & Olazar, Martin, 2020. "Waste tyre valorization by catalytic pyrolysis – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 129(C).

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