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Influence of Specific Power on the Solid and Liquid Products Obtained in the Microwave-Assisted Pyrolysis of End-of-Life Tires

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  • María Teresa Martín

    (Cátedra de Medio Ambiente, Facultad de Ciencias, Universidad de Alcalá, 28871 Alcalá de Henares, Spain
    Environment and Bioproducts Group, Facultad de Ciencias, Universidad de Alcalá, 28871 Alcalá de Henares, Spain)

  • Juan Luis Aguirre

    (Cátedra de Medio Ambiente, Facultad de Ciencias, Universidad de Alcalá, 28871 Alcalá de Henares, Spain
    Environment and Bioproducts Group, Facultad de Ciencias, Universidad de Alcalá, 28871 Alcalá de Henares, Spain)

  • Juan Baena-González

    (Cátedra de Medio Ambiente, Facultad de Ciencias, Universidad de Alcalá, 28871 Alcalá de Henares, Spain
    Environment and Bioproducts Group, Facultad de Ciencias, Universidad de Alcalá, 28871 Alcalá de Henares, Spain)

  • Sergio González

    (Cátedra de Medio Ambiente, Facultad de Ciencias, Universidad de Alcalá, 28871 Alcalá de Henares, Spain
    Environment and Bioproducts Group, Facultad de Ciencias, Universidad de Alcalá, 28871 Alcalá de Henares, Spain)

  • Roberto Pérez-Aparicio

    (Sistema Colectivo de Gestión de Neumáticos Fuera de Uso (SIGNUS), 28033 Madrid, Spain)

  • Leticia Saiz-Rodríguez

    (Sistema Colectivo de Gestión de Neumáticos Fuera de Uso (SIGNUS), 28033 Madrid, Spain)

Abstract

In this work, chemical recycling as an alternative to conventional end-of-life treatments was studied. Two different types of end-of-life tires (ELT), truck tires and mix tires (50:50 mixture of passenger car and truck tires), were pyrolyzed in a batch microwave reactor. The influence of specific power (10, 20, and 30 W/g) on mass distribution was analyzed. The maximum liquid yield was attained at 10 W/g, while the maximum gas yield is obtained at 30 W/g. Liquid fractions were characterized by gas chromatography/quadrupole mass spectrometry (GC/qMS) to identify the main components, and major compounds were quantified. In all samples, limonene (3.76 ± 0.31–6.80 ± 2.37 wt. %) and BTEX (3.83 ± 0.20–1.19 ± 2.80 wt. %) were the main components. Major limonene concentration is obtained in oil produced from truck ELT while higher yields of aromatic compounds are obtained from mix ELT. The maximum BTEX concentration is obtained at 10 W/g being toluene the main compound with a concentration of 2.07 ± 0.42 and 4.63 ± 1.29 for truck and mix ELT, respectively. The separation and purification of these compounds will confer important value to these fractions. Higher yields of the solid fraction are produced when mix tires are pyrolyzed due to the higher concentration of ash in this type of ELT. Recovered carbon black was characterized by measuring the surface area.

Suggested Citation

  • María Teresa Martín & Juan Luis Aguirre & Juan Baena-González & Sergio González & Roberto Pérez-Aparicio & Leticia Saiz-Rodríguez, 2022. "Influence of Specific Power on the Solid and Liquid Products Obtained in the Microwave-Assisted Pyrolysis of End-of-Life Tires," Energies, MDPI, vol. 15(6), pages 1-17, March.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:6:p:2128-:d:771042
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    References listed on IDEAS

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    1. Farooq, Muhammad Zohaib & Zeeshan, Muhammad & Iqbal, Saeed & Ahmed, Naveed & Shah, Syed Asfand Yar, 2018. "Influence of waste tire addition on wheat straw pyrolysis yield and oil quality," Energy, Elsevier, vol. 144(C), pages 200-206.
    2. Hita, Idoia & Arabiourrutia, Miriam & Olazar, Martin & Bilbao, Javier & Arandes, José María & Castaño, Pedro, 2016. "Opportunities and barriers for producing high quality fuels from the pyrolysis of scrap tires," Renewable and Sustainable Energy Reviews, Elsevier, vol. 56(C), pages 745-759.
    3. Suchocki, T. & Witanowski, Ł. & Lampart, P. & Kazimierski, P. & Januszewicz, K. & Gawron, B., 2021. "Experimental investigation of performance and emission characteristics of a miniature gas turbine supplied by blends of kerosene and waste tyre pyrolysis oil," Energy, Elsevier, vol. 215(PA).
    4. Martínez, Juan Daniel & Puy, Neus & Murillo, Ramón & García, Tomás & Navarro, María Victoria & Mastral, Ana Maria, 2013. "Waste tyre pyrolysis – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 23(C), pages 179-213.
    5. Panagiotis Grammelis & Nikolaos Margaritis & Petros Dallas & Dimitrios Rakopoulos & Georgios Mavrias, 2021. "A Review on Management of End of Life Tires (ELTs) and Alternative Uses of Textile Fibers," Energies, MDPI, vol. 14(3), pages 1-20, January.
    6. Alvarez, J. & Lopez, G. & Amutio, M. & Mkhize, N.M. & Danon, B. & van der Gryp, P. & Görgens, J.F. & Bilbao, J. & Olazar, M., 2017. "Evaluation of the properties of tyre pyrolysis oils obtained in a conical spouted bed reactor," Energy, Elsevier, vol. 128(C), pages 463-474.
    7. Song, Zhanlong & Yang, Yaqing & Sun, Jing & Zhao, Xiqiang & Wang, Wenlong & Mao, Yanpeng & Ma, Chunyuan, 2017. "Effect of power level on the microwave pyrolysis of tire powder," Energy, Elsevier, vol. 127(C), pages 571-580.
    8. Su Shiung Lam & Howard A. Chase, 2012. "A Review on Waste to Energy Processes Using Microwave Pyrolysis," Energies, MDPI, vol. 5(10), pages 1-24, October.
    9. Motasemi, F. & Afzal, Muhammad T., 2013. "A review on the microwave-assisted pyrolysis technique," Renewable and Sustainable Energy Reviews, Elsevier, vol. 28(C), pages 317-330.
    10. Czajczyńska, Dina & Krzyżyńska, Renata & Jouhara, Hussam & Spencer, Nik, 2017. "Use of pyrolytic gas from waste tire as a fuel: A review," Energy, Elsevier, vol. 134(C), pages 1121-1131.
    11. Song, Zhanlong & Liu, Li & Yang, Yaqing & Sun, Jing & Zhao, Xiqiang & Wang, Wenlong & Mao, Yanpeng & Yuan, Xueliang & Wang, Qingsong, 2018. "Characteristics of limonene formation during microwave pyrolysis of scrap tires and quantitative analysis," Energy, Elsevier, vol. 142(C), pages 953-961.
    12. Antoniou, N. & Zabaniotou, A., 2013. "Features of an efficient and environmentally attractive used tyres pyrolysis with energy and material recovery," Renewable and Sustainable Energy Reviews, Elsevier, vol. 20(C), pages 539-558.
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