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Template-free synthesis of three-dimensional nanoporous N-doped graphene for high performance fuel cell oxygen reduction reaction in alkaline media

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  • Tang, Sheng
  • Zhou, Xuejun
  • Xu, Nengneng
  • Bai, Zhengyu
  • Qiao, Jinli
  • Zhang, Jiujun

Abstract

Three-dimensional nanoporous nitrogen-doped graphene (3D-PNG) has been synthesized through a facial one-step synthesis method without additional silica template. The as-prepared 3D-PNGwas used as an electrocatalyst for the oxygen reduction reaction (ORR), which shows excellent electrochemistry performance, demonstrated by half-cell electrochemical evaluation in 0.1M KOH including prominent ORR activity, four electron-selectivity and remarkable methanol poisoning stability compared to commercial 20%Pt/C catalyst. The physical and surface properties of 3D-PNG catalyst were characterized by scanning electron microscopy (SEM), high-resolution transmission electron microscopy (TEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and BET surface area analysis. The experiments show that 3D-PNG catalyst possesses super-large specific surface area reaching 920m2g−1, which is superior to our most recently reported 3D-PNG synthesized by silica template (670m2g−1) and other doped graphene catalysts in literature. When used for constructing a zinc–air battery cathode, such an 3D-PNG catalyst can give a discharge peak power density of 275mWcm−2. All the results announce a unique procedure to product high-efficiency graphene-based non-noble metal catalyst materials for electrochemical energy devices including both fuel cells and metal–air batteries.

Suggested Citation

  • Tang, Sheng & Zhou, Xuejun & Xu, Nengneng & Bai, Zhengyu & Qiao, Jinli & Zhang, Jiujun, 2016. "Template-free synthesis of three-dimensional nanoporous N-doped graphene for high performance fuel cell oxygen reduction reaction in alkaline media," Applied Energy, Elsevier, vol. 175(C), pages 405-413.
    • Handle: RePEc:eee:appene:v:175:y:2016:i:c:p:405-413
    DOI: 10.1016/j.apenergy.2016.04.074
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    References listed on IDEAS

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    1. Trongchuankij, Wiruyn & Pruksathorn, Kejvalee & Hunsom, Mali, 2011. "Preparation of a high performance Pt-Co/C electrocatalyst for oxygen reduction in PEM fuel cell via a combined process of impregnation and seeding," Applied Energy, Elsevier, vol. 88(3), pages 974-980, March.
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    Cited by:

    1. Pei, Pucheng & Huang, Shangwei & Chen, Dongfang & Li, Yuehua & Wu, Ziyao & Ren, Peng & Wang, Keliang & Jia, Xiaoning, 2019. "A high-energy-density and long-stable-performance zinc-air fuel cell system," Applied Energy, Elsevier, vol. 241(C), pages 124-129.
    2. Yuan, Rong-hua & He, Yun & He, Wei & Ni, Meng & Leung, Michael K.H., 2019. "Bifunctional electrocatalytic activity of La0.8Sr0.2MnO3-based perovskite with the A-site deficiency for oxygen reduction and evolution reactions in alkaline media," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    3. Nandan, Ravi & Goswami, Gopal Krishna & Nanda, Karuna Kar, 2017. "Direct synthesis of Pt-free catalyst on gas diffusion layer of fuel cell and usage of high boiling point fuels for efficient utilization of waste heat," Applied Energy, Elsevier, vol. 205(C), pages 1050-1058.
    4. Ghosh, Arpita & Chandran, Priji & Ramaprabhu, S., 2017. "Palladium-nitrogen coordinated cobalt alloy towards hydrogen oxidation and oxygen reduction reactions with high catalytic activity in renewable energy generations of proton exchange membrane fuel cell," Applied Energy, Elsevier, vol. 208(C), pages 37-48.
    5. Liu, Zhenning & Li, Zhiyuan & Ma, Jian & Dong, Xu & Ku, Wen & Wang, Mi & Sun, Hang & Liang, Song & Lu, Guolong, 2018. "Nitrogen and cobalt-doped porous biocarbon materials derived from corn stover as efficient electrocatalysts for aluminum-air batteries," Energy, Elsevier, vol. 162(C), pages 453-459.
    6. Zhong, Kengqiang & Li, Meng & Yang, Yue & Zhang, Hongguo & Zhang, Bopeng & Tang, Jinfeng & Yan, Jia & Su, Minhua & Yang, Zhiquan, 2019. "Nitrogen-doped biochar derived from watermelon rind as oxygen reduction catalyst in air cathode microbial fuel cells," Applied Energy, Elsevier, vol. 242(C), pages 516-525.
    7. She, Yiyi & Chen, Jinfan & Zhang, Chengxu & Lu, Zhouguang & Ni, Meng & Sit, Patrick H.-L. & Leung, Michael K.H., 2018. "Nitrogen-doped graphene derived from ionic liquid as metal-free catalyst for oxygen reduction reaction and its mechanisms," Applied Energy, Elsevier, vol. 225(C), pages 513-521.

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