IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v211y2018icp1080-1088.html
   My bibliography  Save this article

Carbon dioxide adsorption properties and adsorption/desorption kinetics of amine-functionalized KIT-6

Author

Listed:
  • Liu, Yamin
  • Yu, Xiaojing

Abstract

An amine-functionalized adsorbent was prepared by loading pentaethylenehexamine (PEHA) into the pores of KIT-6 mesoporous silica. Nitrogen adsorption/desorption, thermogravimetric analysis, and X-ray powder diffraction were employed to analyze the structural properties of the prepared adsorbents. The results reveal that the pore size, pore volume, and surface area of the adsorbents decrease after PEHA loading in KIT-6, while the basic KIT-6 pore structure remains unchanged. The CO2 adsorption performance of amine-functionalized KIT-6 was studied by isothermal CO2 adsorption, adsorption/desorption cycle regeneration testing, and multiple cycle tests. The amount of CO2 absorbed increased with increasing temperature in the temperature range of 303–343 K, achieving a maximum adsorption capacity of 3.2 mmol/g-adsorbent at 343 K. For temperatures greater than 343 K, the adsorption capacity decreased with increasing temperature. The amount of CO2 adsorbed remained nearly constant after 10 adsorption/desorption cycles. The CO2 adsorption/desorption kinetics of the PEHA-impregnated KIT-6 were investigated using three kinetics models. The results indicate that the CO2 adsorption process by the amine-functionalized adsorbent is dominated by intra-particle diffusion, and the adsorption rate is restricted by the intra-particle diffusion process. In addition, high CO2 partial pressure facilitates the adsorption of CO2. The CO2 adsorption breakthrough curves obtained by the deactivation model were in good agreement with the results of this study. The adsorbents were regenerated by vacuum and temperature swing adsorption regeneration. The results indicate that increasing the desorption temperature is an effective means of reducing the regeneration time. The absolute value of the activation energy obtained from the Arrhenius equation for CO2 desorption was 81.992 kJ·mol−1, which was greater than that obtained for adsorption.

Suggested Citation

  • Liu, Yamin & Yu, Xiaojing, 2018. "Carbon dioxide adsorption properties and adsorption/desorption kinetics of amine-functionalized KIT-6," Applied Energy, Elsevier, vol. 211(C), pages 1080-1088.
    • Handle: RePEc:eee:appene:v:211:y:2018:i:c:p:1080-1088
    DOI: 10.1016/j.apenergy.2017.12.016
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261917317294
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2017.12.016?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Mondal, Monoj Kumar & Balsora, Hemant Kumar & Varshney, Prachi, 2012. "Progress and trends in CO2 capture/separation technologies: A review," Energy, Elsevier, vol. 46(1), pages 431-441.
    2. Zhu, Xuancan & Shi, Yixiang & Cai, Ningsheng, 2016. "Integrated gasification combined cycle with carbon dioxide capture by elevated temperature pressure swing adsorption," Applied Energy, Elsevier, vol. 176(C), pages 196-208.
    3. Ho Yuh-Shan, 2004. "Citation review of Lagergren kinetic rate equation on adsorption reactions," Scientometrics, Springer;Akadémiai Kiadó, vol. 59(1), pages 171-177, January.
    4. Dang Viet Quang & Abdallah Dindi & Aravind V Rayer & Nabil El Hadri & Abdurahim Abdulkadir & Mohammad R.M. Abu‐Zahra, 2015. "Effect of moisture on the heat capacity and the regeneration heat required for CO 2 capture process using PEI impregnated mesoporous precipitated silica," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 5(1), pages 91-101, February.
    5. Guo, Yafei & Zhao, Chuanwen & Chen, Xiaoping & Li, Changhai, 2015. "CO2 capture and sorbent regeneration performances of some wood ash materials," Applied Energy, Elsevier, vol. 137(C), pages 26-36.
    6. Ben-Mansour, R. & Habib, M.A. & Bamidele, O.E. & Basha, M. & Qasem, N.A.A. & Peedikakkal, A. & Laoui, T. & Ali, M., 2016. "Carbon capture by physical adsorption: Materials, experimental investigations and numerical modeling and simulations – A review," Applied Energy, Elsevier, vol. 161(C), pages 225-255.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Guo, Baihe & Zhang, Jingchao & Wang, Yanlin & Qiao, Xiaolei & Xiang, Jun & Jin, Yan, 2023. "Study on CO2 adsorption capacity and kinetic mechanism of CO2 adsorbent prepared from fly ash," Energy, Elsevier, vol. 263(PB).
    2. Lou, Feijian & Zhang, Anfeng & Zhang, Guanghui & Ren, Limin & Guo, Xinwen & Song, Chunshan, 2020. "Enhanced kinetics for CO2 sorption in amine-functionalized mesoporous silica nanosphere with inverted cone-shaped pore structure," Applied Energy, Elsevier, vol. 264(C).
    3. Yan, Shuren & Zhu, Ding & Zhang, Zhiyong & Li, Hai & Chen, Guangjin & Liu, Bei, 2019. "A pilot-scale experimental study on CO2 capture using Zeolitic imidazolate framework-8 slurry under normal pressure," Applied Energy, Elsevier, vol. 248(C), pages 104-114.
    4. Gao, Jubao & Liu, Yida & Hoshino, Yu & Inoue, Gen, 2019. "Amine-containing nanogel particles supported on porous carriers for enhanced carbon dioxide capture," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    5. Yudong Ding & Liheng Guo & Xiaoqiang Li & Qiang Liao & Xun Zhu & Hong Wang, 2021. "CO2 absorption of anhydrous colloidal suspension based silica nanospheres with different microstructures," Energy & Environment, , vol. 32(8), pages 1437-1456, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Qasem, Naef A.A. & Ben-Mansour, Rached & Habib, Mohamed A., 2018. "An efficient CO2 adsorptive storage using MOF-5 and MOF-177," Applied Energy, Elsevier, vol. 210(C), pages 317-326.
    2. Zhao, Ruikai & Zhao, Li & Deng, Shuai & Song, Chunfeng & He, Junnan & Shao, Yawei & Li, Shuangjun, 2017. "A comparative study on CO2 capture performance of vacuum-pressure swing adsorption and pressure-temperature swing adsorption based on carbon pump cycle," Energy, Elsevier, vol. 137(C), pages 495-509.
    3. Bhatia, Shashi Kant & Bhatia, Ravi Kant & Jeon, Jong-Min & Kumar, Gopalakrishnan & Yang, Yung-Hun, 2019. "Carbon dioxide capture and bioenergy production using biological system – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 110(C), pages 143-158.
    4. A. G. Olabi & Tabbi Wilberforce & Enas Taha Sayed & Nabila Shehata & Abdul Hai Alami & Hussein M. Maghrabie & Mohammad Ali Abdelkareem, 2022. "Prospect of Post-Combustion Carbon Capture Technology and Its Impact on the Circular Economy," Energies, MDPI, vol. 15(22), pages 1-38, November.
    5. Chen, S.J. & Zhu, M. & Fu, Y. & Huang, Y.X. & Tao, Z.C. & Li, W.L., 2017. "Using 13X, LiX, and LiPdAgX zeolites for CO2 capture from post-combustion flue gas," Applied Energy, Elsevier, vol. 191(C), pages 87-98.
    6. Qasem, Naef A.A. & Ben-Mansour, Rached, 2018. "Energy and productivity efficient vacuum pressure swing adsorption process to separate CO2 from CO2/N2 mixture using Mg-MOF-74: A CFD simulation," Applied Energy, Elsevier, vol. 209(C), pages 190-202.
    7. Zhai, Jihua & Burke, Ian T. & Stewart, Douglas I., 2021. "Beneficial management of biomass combustion ashes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 151(C).
    8. Narukulla, Ramesh & Chaturvedi, Krishna Raghav & Ojha, Umaprasana & Sharma, Tushar, 2022. "Carbon dioxide capturing evaluation of polyacryloyl hydrazide solutions via rheological analysis for carbon utilization applications," Energy, Elsevier, vol. 241(C).
    9. Gu, Zhenhua & Zhang, Ling & Lu, Chunqiang & Qing, Shan & Li, Kongzhai, 2020. "Enhanced performance of copper ore oxygen carrier by red mud modification for chemical looping combustion," Applied Energy, Elsevier, vol. 277(C).
    10. Chu, Fengming & Yang, Lijun & Du, Xiaoze & Yang, Yongping, 2017. "Mass transfer and energy consumption for CO2 absorption by ammonia solution in bubble column," Applied Energy, Elsevier, vol. 190(C), pages 1068-1080.
    11. Kim, Soyoung & Choi, Sung-Deuk & Seo, Yongwon, 2017. "CO2 capture from flue gas using clathrate formation in the presence of thermodynamic promoters," Energy, Elsevier, vol. 118(C), pages 950-956.
    12. Majeda Khraisheh & Khadija M. Zadeh & Abedalkhader I. Alkhouzaam & Dorra Turki & Mohammad K. Hassan & Fares Al Momani & Syed M. J. Zaidi, 2020. "Characterization of polysulfone/diisopropylamine 1‐alkyl‐3‐methylimidazolium ionic liquid membranes: high pressure gas separation applications," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 10(4), pages 795-808, August.
    13. Wei, Wei & Liu, Feng & Wang, Jianhui & Chen, Laijun & Mei, Shengwei & Yuan, Tiejiang, 2016. "Robust environmental-economic dispatch incorporating wind power generation and carbon capture plants," Applied Energy, Elsevier, vol. 183(C), pages 674-684.
    14. Magoua Mbeugang, Christian Fabrice & Li, Bin & Lin, Dan & Xie, Xing & Wang, Shuaijun & Wang, Shuang & Zhang, Shu & Huang, Yong & Liu, Dongjing & Wang, Qian, 2021. "Hydrogen rich syngas production from sorption enhanced gasification of cellulose in the presence of calcium oxide," Energy, Elsevier, vol. 228(C).
    15. Georgios Varvoutis & Athanasios Lampropoulos & Evridiki Mandela & Michalis Konsolakis & George E. Marnellos, 2022. "Recent Advances on CO 2 Mitigation Technologies: On the Role of Hydrogenation Route via Green H 2," Energies, MDPI, vol. 15(13), pages 1-38, June.
    16. Xie, Heping & Wu, Yifan & Liu, Tao & Wang, Fuhuan & Chen, Bin & Liang, Bin, 2020. "Low-energy-consumption electrochemical CO2 capture driven by biomimetic phenazine derivatives redox medium," Applied Energy, Elsevier, vol. 259(C).
    17. Li, Shuangjun & Deng, Shuai & Zhao, Li & Zhao, Ruikai & Yuan, Xiangzhou, 2021. "Thermodynamic carbon pump 2.0: Elucidating energy efficiency through the thermodynamic cycle," Energy, Elsevier, vol. 215(PB).
    18. Zhang, Xiaowen & Zhang, Xin & Liu, Helei & Li, Wensheng & Xiao, Min & Gao, Hongxia & Liang, Zhiwu, 2017. "Reduction of energy requirement of CO2 desorption from a rich CO2-loaded MEA solution by using solid acid catalysts," Applied Energy, Elsevier, vol. 202(C), pages 673-684.
    19. Arnob Das & Susmita Datta Peu, 2022. "A Comprehensive Review on Recent Advancements in Thermochemical Processes for Clean Hydrogen Production to Decarbonize the Energy Sector," Sustainability, MDPI, vol. 14(18), pages 1-42, September.
    20. Peydayesh, Mohammad & Mohammadi, Toraj & Bakhtiari, Omid, 2017. "Effective hydrogen purification from methane via polyimide Matrimid® 5218- Deca-dodecasil 3R type zeolite mixed matrix membrane," Energy, Elsevier, vol. 141(C), pages 2100-2107.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:211:y:2018:i:c:p:1080-1088. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.