IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v202y2017icp365-376.html
   My bibliography  Save this article

Surface and bulk carbonate formation in calcium oxide during CO2 capture

Author

Listed:
  • Mutch, Greg A.
  • Anderson, James A.
  • Vega-Maza, David

Abstract

Calcium looping (CaL), the cyclic carbonation and calcination of limestone, is a prominent carbon capture option considering reduced parasitic energy consumption compared to amine scrubbing. The main issue preventing application is sorbent performance decay during cycling. Therefore hydration and extended carbonation reactivation strategies, as well as synthetic approaches to enhance or sustain reactivity, are of interest. Results of an investigation are presented on the impact of reactivation strategies on carbonate formation through detailed study using in-situ infrared spectroscopy. Surface and bulk carbonate formation regimes were readily distinguished allowing the influence of temporal, hydration and thermodynamic conditions within each regime to be studied. Surface chemistry of CaO during two initial cycles was shown to change. Significantly, it was shown that the CaO surface produced from the calcination of Ca(OH)2 possessed more highly reactive sites compared to the surface produced from CaCO3. The presence of water enhanced bulk carbonate formation at 300°C and influenced the complexation of surface carbonates during looping. The results are of interest in the CaL community, offering molecular scale explanations for macroscale observations, whilst also informing on the role of humidity in direct air capture and sorption enhanced reaction processes.

Suggested Citation

  • Mutch, Greg A. & Anderson, James A. & Vega-Maza, David, 2017. "Surface and bulk carbonate formation in calcium oxide during CO2 capture," Applied Energy, Elsevier, vol. 202(C), pages 365-376.
  • Handle: RePEc:eee:appene:v:202:y:2017:i:c:p:365-376
    DOI: 10.1016/j.apenergy.2017.05.130
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261917306712
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.apenergy.2017.05.130?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Antzara, Andy & Heracleous, Eleni & Lemonidou, Angeliki A., 2015. "Improving the stability of synthetic CaO-based CO2 sorbents by structural promoters," Applied Energy, Elsevier, vol. 156(C), pages 331-343.
    2. Erans, María & Manovic, Vasilije & Anthony, Edward J., 2016. "Calcium looping sorbents for CO2 capture," Applied Energy, Elsevier, vol. 180(C), pages 722-742.
    3. Ridha, Firas N. & Manovic, Vasilije & Macchi, Arturo & Anthony, Edward J., 2015. "CO2 capture at ambient temperature in a fixed bed with CaO-based sorbents," Applied Energy, Elsevier, vol. 140(C), pages 297-303.
    4. Hanak, Dawid P. & Kolios, Athanasios J. & Manovic, Vasilije, 2016. "Comparison of probabilistic performance of calcium looping and chemical solvent scrubbing retrofits for CO2 capture from coal-fired power plant," Applied Energy, Elsevier, vol. 172(C), pages 323-336.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Bin Shao & Zhi-Qiang Wang & Xue-Qing Gong & Honglai Liu & Feng Qian & P. Hu & Jun Hu, 2023. "Synergistic promotions between CO2 capture and in-situ conversion on Ni-CaO composite catalyst," Nature Communications, Nature, vol. 14(1), pages 1-10, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Abanades, Stéphane & André, Laurie, 2018. "Design and demonstration of a high temperature solar-heated rotary tube reactor for continuous particles calcination," Applied Energy, Elsevier, vol. 212(C), pages 1310-1320.
    2. Hanak, Dawid P. & Jenkins, Barrie G. & Kruger, Tim & Manovic, Vasilije, 2017. "High-efficiency negative-carbon emission power generation from integrated solid-oxide fuel cell and calciner," Applied Energy, Elsevier, vol. 205(C), pages 1189-1201.
    3. Zhang, Wan & Li, Yingjie & He, Zirui & Ma, Xiaotong & Song, Haiping, 2017. "CO2 capture by carbide slag calcined under high-concentration steam and energy requirement in calcium looping conditions," Applied Energy, Elsevier, vol. 206(C), pages 869-878.
    4. Erans, María & Jeremias, Michal & Zheng, Liya & Yao, Joseph G. & Blamey, John & Manovic, Vasilije & Fennell, Paul S. & Anthony, Edward J., 2018. "Pilot testing of enhanced sorbents for calcium looping with cement production," Applied Energy, Elsevier, vol. 225(C), pages 392-401.
    5. Ma, Xiaotong & Li, Yingjie & Shi, Lei & He, Zirui & Wang, Zeyan, 2016. "Fabrication and CO2 capture performance of magnesia-stabilized carbide slag by by-product of biodiesel during calcium looping process," Applied Energy, Elsevier, vol. 168(C), pages 85-95.
    6. Chi, Changyun & Li, Yingjie & Zhang, Wan & Wang, Zeyan, 2019. "Synthesis of a hollow microtubular Ca/Al sorbent with high CO2 uptake by hard templating," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    7. Su, Chenglin & Duan, Lunbo & Donat, Felix & Anthony, Edward John, 2018. "From waste to high value utilization of spent bleaching clay in synthesizing high-performance calcium-based sorbent for CO2 capture," Applied Energy, Elsevier, vol. 210(C), pages 117-126.
    8. Ma, Xiaotong & Li, Yingjie & Duan, Lunbo & Anthony, Edward & Liu, Hantao, 2018. "CO2 capture performance of calcium-based synthetic sorbent with hollow core-shell structure under calcium looping conditions," Applied Energy, Elsevier, vol. 225(C), pages 402-412.
    9. Benitez-Guerrero, Monica & Valverde, Jose Manuel & Perejon, Antonio & Sanchez-Jimenez, Pedro E. & Perez-Maqueda, Luis A., 2018. "Low-cost Ca-based composites synthesized by biotemplate method for thermochemical energy storage of concentrated solar power," Applied Energy, Elsevier, vol. 210(C), pages 108-116.
    10. Antzaras, Andy N. & Lemonidou, Angeliki A., 2022. "Recent advances on materials and processes for intensified production of blue hydrogen," Renewable and Sustainable Energy Reviews, Elsevier, vol. 155(C).
    11. Shi, Jiewen & Li, Yingjie & Zhang, Qing & Ma, Xiaotong & Duan, Lunbo & Zhou, Xingang, 2017. "CO2 capture performance of a novel synthetic CaO/sepiolite sorbent at calcium looping conditions," Applied Energy, Elsevier, vol. 203(C), pages 412-421.
    12. Vyacheslav V. Rodaev & Svetlana S. Razlivalova, 2021. "Performance and Durability of the Zr-Doped CaO Sorbent under Cyclic Carbonation–Decarbonation at Different Operating Parameters," Energies, MDPI, vol. 14(16), pages 1-9, August.
    13. Han, Rui & Gao, Jihui & Wei, Siyu & Su, Yanlin & Sun, Fei & Zhao, Guangbo & Qin, Yukun, 2018. "Strongly coupled calcium carbonate/antioxidative graphite nanosheets composites with high cycling stability for thermochemical energy storage," Applied Energy, Elsevier, vol. 231(C), pages 412-422.
    14. Wang, Ke & Zhou, Zhongyun & Zhao, Pengfei & Yin, Zeguang & Su, Zhen & Sun, Ji, 2017. "Molten sodium-fluoride-promoted high-performance Li4SiO4-based CO2 sorbents at low CO2 concentrations," Applied Energy, Elsevier, vol. 204(C), pages 403-412.
    15. Akbari-Emadabadi, S. & Rahimpour, M.R. & Hafizi, A. & Keshavarz, P., 2017. "Production of hydrogen-rich syngas using Zr modified Ca-Co bifunctional catalyst-sorbent in chemical looping steam methane reforming," Applied Energy, Elsevier, vol. 206(C), pages 51-62.
    16. Rubens C. Toledo & Gretta L. A. F. Arce & João A. Carvalho & Ivonete Ávila, 2023. "Experimental Development of Calcium Looping Carbon Capture Processes: An Overview of Opportunities and Challenges," Energies, MDPI, vol. 16(9), pages 1-27, April.
    17. Wang, Ke & Zhou, Zhongyun & Zhao, Pengfei & Yin, Zeguang & Su, Zhen & Sun, Ji, 2016. "Synthesis of a highly efficient Li4SiO4 ceramic modified with a gluconic acid-based carbon coating for high-temperature CO2 capture," Applied Energy, Elsevier, vol. 183(C), pages 1418-1427.
    18. Khosa, Azhar Abbas & Han, Xinyue & Zhao, C.Y., 2024. "Experimental investigation of CaCO3/CaO reaction pair in a fixed bed reactor for CSP application," Renewable Energy, Elsevier, vol. 221(C).
    19. Donald Ukpanyang & Julio Terrados-Cepeda, 2022. "Decarbonizing Vehicle Transportation with Hydrogen from Biomass Gasification: An Assessment in the Nigerian Urban Environment," Energies, MDPI, vol. 15(9), pages 1-23, April.
    20. Wang, Heng & Zhao, Hongbin & Du, Huicheng & Zhao, Zefeng & Zhang, Taiheng, 2022. "Thermodynamic performance study of a new diesel-fueled CLHG/SOFC/STIG cogeneration system with CO2 recovery," Energy, Elsevier, vol. 246(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:202:y:2017:i:c:p:365-376. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.