IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v204y2017icp403-412.html
   My bibliography  Save this article

Molten sodium-fluoride-promoted high-performance Li4SiO4-based CO2 sorbents at low CO2 concentrations

Author

Listed:
  • Wang, Ke
  • Zhou, Zhongyun
  • Zhao, Pengfei
  • Yin, Zeguang
  • Su, Zhen
  • Sun, Ji

Abstract

Highly efficient NaF-doped Li4SiO4 sorbents were synthesized by sacrificial carbon template technology to overcome their typical kinetic limitations at low CO2 concentrations. The samples were characterized by XRD, SEM, N2 adsorption, XPS, differential scanning calorimetry (DSC), and thermogravimetric analyses (dynamic and isothermic). The results showed that co-doped sodium and fluorine were substituted for lithium and oxygen, respectively. Such doped features induced a high concentration of Li-O sites on the molten surface when absorbing CO2 in a relatively wide temperature range (475–575°C). This favorable characteristic greatly facilitated surface chemisorption processes, accelerated the transport of Li+ and O2−, and decreased the CO2 diffusion resistance. Therefore, 3wt.% NaF doping was used to reach a maximum absorption capacity (>33.0wt.%) in a wide temperature range (475–575°C) in 15vol.% CO2. Moreover, the high capacity was maintained over 10 sorption/desorption cycles, suggesting that NaF-doped Li4SiO4 sorbents have high potential for CO2 capture.

Suggested Citation

  • Wang, Ke & Zhou, Zhongyun & Zhao, Pengfei & Yin, Zeguang & Su, Zhen & Sun, Ji, 2017. "Molten sodium-fluoride-promoted high-performance Li4SiO4-based CO2 sorbents at low CO2 concentrations," Applied Energy, Elsevier, vol. 204(C), pages 403-412.
    • Handle: RePEc:eee:appene:v:204:y:2017:i:c:p:403-412
    DOI: 10.1016/j.apenergy.2017.07.072
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261917309455
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2017.07.072?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Wang, Ke & Zhou, Zhongyun & Zhao, Pengfei & Yin, Zeguang & Su, Zhen & Sun, Ji, 2016. "Synthesis of a highly efficient Li4SiO4 ceramic modified with a gluconic acid-based carbon coating for high-temperature CO2 capture," Applied Energy, Elsevier, vol. 183(C), pages 1418-1427.
    2. Ben-Mansour, R. & Habib, M.A. & Bamidele, O.E. & Basha, M. & Qasem, N.A.A. & Peedikakkal, A. & Laoui, T. & Ali, M., 2016. "Carbon capture by physical adsorption: Materials, experimental investigations and numerical modeling and simulations – A review," Applied Energy, Elsevier, vol. 161(C), pages 225-255.
    3. Theo, Wai Lip & Lim, Jeng Shiun & Hashim, Haslenda & Mustaffa, Azizul Azri & Ho, Wai Shin, 2016. "Review of pre-combustion capture and ionic liquid in carbon capture and storage," Applied Energy, Elsevier, vol. 183(C), pages 1633-1663.
    4. Wang, Ke & Hu, Xiumeng & Zhao, Pengfei & Yin, Zeguang, 2016. "Natural dolomite modified with carbon coating for cyclic high-temperature CO2 capture," Applied Energy, Elsevier, vol. 165(C), pages 14-21.
    5. Sanna, Aimaro & Ramli, Ili & Mercedes Maroto-Valer, M., 2015. "Development of sodium/lithium/fly ash sorbents for high temperature post-combustion CO2 capture," Applied Energy, Elsevier, vol. 156(C), pages 197-206.
    6. Wee, Jung-Ho, 2013. "A review on carbon dioxide capture and storage technology using coal fly ash," Applied Energy, Elsevier, vol. 106(C), pages 143-151.
    7. Erans, María & Manovic, Vasilije & Anthony, Edward J., 2016. "Calcium looping sorbents for CO2 capture," Applied Energy, Elsevier, vol. 180(C), pages 722-742.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Wang, Ke & Zhou, Zhongyun & Zhao, Pengfei & Yin, Zeguang & Su, Zhen & Sun, Ji, 2016. "Synthesis of a highly efficient Li4SiO4 ceramic modified with a gluconic acid-based carbon coating for high-temperature CO2 capture," Applied Energy, Elsevier, vol. 183(C), pages 1418-1427.
    2. Antzaras, Andy N. & Lemonidou, Angeliki A., 2022. "Recent advances on materials and processes for intensified production of blue hydrogen," Renewable and Sustainable Energy Reviews, Elsevier, vol. 155(C).
    3. Shi, Jiewen & Li, Yingjie & Zhang, Qing & Ma, Xiaotong & Duan, Lunbo & Zhou, Xingang, 2017. "CO2 capture performance of a novel synthetic CaO/sepiolite sorbent at calcium looping conditions," Applied Energy, Elsevier, vol. 203(C), pages 412-421.
    4. Li, Xiangyu & Wang, Zhiqing & Feng, Ru & Huang, Jiejie & Fang, Yitian, 2021. "CO2 capture on aminosilane functionalized alumina-extracted residue of catalytic gasification coal ash," Energy, Elsevier, vol. 221(C).
    5. Costa, Alexis & Coppitters, Diederik & Dubois, Lionel & Contino, Francesco & Thomas, Diane & De Weireld, Guy, 2024. "Energy, exergy, economic and environmental (4E) analysis of a cryogenic carbon purification unit with membrane for oxyfuel cement plant flue gas," Applied Energy, Elsevier, vol. 357(C).
    6. A. G. Olabi & Tabbi Wilberforce & Enas Taha Sayed & Nabila Shehata & Abdul Hai Alami & Hussein M. Maghrabie & Mohammad Ali Abdelkareem, 2022. "Prospect of Post-Combustion Carbon Capture Technology and Its Impact on the Circular Economy," Energies, MDPI, vol. 15(22), pages 1-38, November.
    7. Chi, Changyun & Li, Yingjie & Zhang, Wan & Wang, Zeyan, 2019. "Synthesis of a hollow microtubular Ca/Al sorbent with high CO2 uptake by hard templating," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    8. Chen, S.J. & Zhu, M. & Fu, Y. & Huang, Y.X. & Tao, Z.C. & Li, W.L., 2017. "Using 13X, LiX, and LiPdAgX zeolites for CO2 capture from post-combustion flue gas," Applied Energy, Elsevier, vol. 191(C), pages 87-98.
    9. Ma, Xiaotong & Li, Yingjie & Duan, Lunbo & Anthony, Edward & Liu, Hantao, 2018. "CO2 capture performance of calcium-based synthetic sorbent with hollow core-shell structure under calcium looping conditions," Applied Energy, Elsevier, vol. 225(C), pages 402-412.
    10. Zhang, Wan & Li, Yingjie & He, Zirui & Ma, Xiaotong & Song, Haiping, 2017. "CO2 capture by carbide slag calcined under high-concentration steam and energy requirement in calcium looping conditions," Applied Energy, Elsevier, vol. 206(C), pages 869-878.
    11. Nur Syahirah Mohamed Hatta & Mohamed Kheireddine Aroua & Farihahusnah Hussin & Lai Ti Gew, 2022. "A Systematic Review of Amino Acid-Based Adsorbents for CO 2 Capture," Energies, MDPI, vol. 15(10), pages 1-34, May.
    12. Li, Hongwei & Tang, Zhigang & Li, Na & Cui, Longpeng & Mao, Xian-zhong, 2020. "Mechanism and process study on steel slag enhancement for CO2 capture by seawater," Applied Energy, Elsevier, vol. 276(C).
    13. Parvez, Ashak Mahmud & Hafner, Selina & Hornberger, Matthias & Schmid, Max & Scheffknecht, Günter, 2021. "Sorption enhanced gasification (SEG) of biomass for tailored syngas production with in-situ CO2 capture: Current status, process scale-up experiences and outlook," Renewable and Sustainable Energy Reviews, Elsevier, vol. 141(C).
    14. Li, Hongwei & Tang, Zhigang & He, Zhimin & Gui, Xia & Cui, Longpeng & Mao, Xian-zhong, 2020. "Structure-activity relationship for CO2 absorbent," Energy, Elsevier, vol. 197(C).
    15. Zhang, Fengyuan & Wang, Xiaolin & Lou, Xia & Lipiński, Wojciech, 2021. "The effect of sodium dodecyl sulfate and dodecyltrimethylammonium chloride on the kinetics of CO2 hydrate formation in the presence of tetra-n-butyl ammonium bromide for carbon capture applications," Energy, Elsevier, vol. 227(C).
    16. Han, Sang-Jun & Im, Hye Jin & Wee, Jung-Ho, 2015. "Leaching and indirect mineral carbonation performance of coal fly ash-water solution system," Applied Energy, Elsevier, vol. 142(C), pages 274-282.
    17. Dongdong Fang & Lihui Zhang & Linjiang Zou & Feng Duan, 2021. "Effect of leaching parameters on the composition of adsorbents derived from steel slag and their CO2 capture characteristics," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 11(5), pages 924-938, October.
    18. Khan, Mohd Atiqueuzzaman & Ngo, Huu Hao & Guo, Wenshan & Liu, Yiwen & Zhang, Xinbo & Guo, Jianbo & Chang, Soon Woong & Nguyen, Dinh Duc & Wang, Jie, 2018. "Biohydrogen production from anaerobic digestion and its potential as renewable energy," Renewable Energy, Elsevier, vol. 129(PB), pages 754-768.
    19. Zhihua Zhang, 2015. "Techno-Economic Assessment of Carbon Capture and Storage Facilities Coupled to Coal-Fired Power Plants," Energy & Environment, , vol. 26(6-7), pages 1069-1080, November.
    20. Muhammad Asif & Muhammad Suleman & Ihtishamul Haq & Syed Asad Jamal, 2018. "Post‐combustion CO2 capture with chemical absorption and hybrid system: current status and challenges," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 8(6), pages 998-1031, December.

    More about this item

    Keywords

    CO2 capture; NaF doping; Carbon template; Li4SiO4;
    All these keywords.

    JEL classification:

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:204:y:2017:i:c:p:403-412. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.