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Maximizing fuel production rates in isothermal solar thermochemical fuel production

Author

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  • Davenport, Timothy C.
  • Yang, Chih-Kai
  • Kucharczyk, Christopher J.
  • Ignatowich, Michael J.
  • Haile, Sossina M.

Abstract

Production of chemical fuels by isothermal pressure-swing cycles has recently generated significant interest. In this process a reactive oxide is cyclically exposed to an inert gas, which induces partial reduction of the oxide, and to an oxidizing gas of either H2O or CO2, which reoxidizes the oxide, releasing H2 or CO. At sufficiently high temperatures and sufficiently low gas flow rates, both the reduction and oxidation steps become limited only by the flow of gas across the material and not by material kinetic factors. In this contribution, we develop a numerical model describing fuel production rates in this gas-phase limited regime. The implications of this behavior are explored under all possible isothermal pressure-swing cycling conditions, and the outcome is optimized in terms of fuel production rate as well as fuel conversion and utilization of input gas of all types. Fuel production rate is maximized at infinitesimally small cycle times and attains a value that is independent of material thermodynamics. Gas utilization is maximized at infinitesimally small gas inputs, but the values can be made independent of cycle time, depending on manipulation of flow conditions. Gas-phase conditions (temperature, oxidant and reductant gas partial pressures, and CO2 vs H2O as oxidant) have a strong impact on fuel production metrics. Under realistic, finite cycle times, material thermodynamics play a measurable role in establishing fuel production rates.

Suggested Citation

  • Davenport, Timothy C. & Yang, Chih-Kai & Kucharczyk, Christopher J. & Ignatowich, Michael J. & Haile, Sossina M., 2016. "Maximizing fuel production rates in isothermal solar thermochemical fuel production," Applied Energy, Elsevier, vol. 183(C), pages 1098-1111.
  • Handle: RePEc:eee:appene:v:183:y:2016:i:c:p:1098-1111
    DOI: 10.1016/j.apenergy.2016.09.012
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    References listed on IDEAS

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    1. Agrafiotis, Christos & Roeb, Martin & Sattler, Christian, 2015. "A review on solar thermal syngas production via redox pair-based water/carbon dioxide splitting thermochemical cycles," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 254-285.
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    1. Lin, Meng & Reinhold, Jan & Monnerie, Nathalie & Haussener, Sophia, 2018. "Modeling and design guidelines for direct steam generation solar receivers," Applied Energy, Elsevier, vol. 216(C), pages 761-776.
    2. Kong, Hui & Hao, Yong & Jin, Hongguang, 2018. "Isothermal versus two-temperature solar thermochemical fuel synthesis: A comparative study," Applied Energy, Elsevier, vol. 228(C), pages 301-308.
    3. Mao, Yanpeng & Gao, Yibo & Dong, Wei & Wu, Han & Song, Zhanlong & Zhao, Xiqiang & Sun, Jing & Wang, Wenlong, 2020. "Hydrogen production via a two-step water splitting thermochemical cycle based on metal oxide – A review," Applied Energy, Elsevier, vol. 267(C).
    4. Yadav, Deepak & Banerjee, Rangan, 2022. "Thermodynamic and economic analysis of the solar carbothermal and hydrometallurgy routes for zinc production," Energy, Elsevier, vol. 247(C).
    5. Gao, Yibo & Mao, Yanpeng & Song, Zhanlong & Zhao, Xiqiang & Sun, Jing & Wang, Wenlong & Chen, Guifang & Chen, Shouyan, 2020. "Efficient generation of hydrogen by two-step thermochemical cycles: Successive thermal reduction and water splitting reactions using equal-power microwave irradiation and a high entropy material," Applied Energy, Elsevier, vol. 279(C).
    6. Lidor, A. & Fend, T. & Roeb, M. & Sattler, C., 2021. "High performance solar receiver–reactor for hydrogen generation," Renewable Energy, Elsevier, vol. 179(C), pages 1217-1232.
    7. Stéphane Abanades, 2022. "Redox Cycles, Active Materials, and Reactors Applied to Water and Carbon Dioxide Splitting for Solar Thermochemical Fuel Production: A Review," Energies, MDPI, vol. 15(19), pages 1-28, September.
    8. Jiang, Boshu & Guene Lougou, Bachirou & Zhang, Hao & Geng, Boxi & Wu, Lianxuan & Shuai, Yong, 2022. "Preparation and solar thermochemical properties analysis of NiFe2O4@SiC/ @Si3N4 for high-performance CO2-splitting," Applied Energy, Elsevier, vol. 328(C).

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