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Thermodynamic and kinetic analysis of an integrated solar thermochemical energy storage system for dry-reforming of methane

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  • Xie, Tao
  • Xu, Kai-Di
  • He, Ya-Ling
  • Wang, Kun
  • Yang, Bo-Lun

Abstract

Thermodynamic analysis for an integrated solar thermochemical energy storage system was conducted to examine its energy and chemical conversion performances. Detailed mathematical description for the transportation process of radiation energy was given to obtain the input solar power to the solar receiver/reactor. Plug-flow model was used to determine the species concentrations and temperature distributions of the solar reactor combined with kinetic models. Then concentrations of species and temperature at outlet of solar reactor were used in the overall thermodynamic model to investigate the effects of key parameters on thermal performance of the system. The results shown that each of the key parameters (initial molar flow rate, diameter and length of reactor, initial molar ratio of CH4/CO2, and absorption coefficient) produced both of positive and negative influences on energy and chemical conversion performances. In order to fully utilize the input energy and feed gas, mass transfer/heat transfer and chemical reaction rate should match with each other. So in both single factor analysis and transient operation condition analysis, the operation parameters were optimized which significantly improved the cycle work efficiency ηcycle (from 17.72% to 34.04% on 12:00 of Summer Solstice, and from 19.53% to 33.37% on 12:00 of Winter Solstice).

Suggested Citation

  • Xie, Tao & Xu, Kai-Di & He, Ya-Ling & Wang, Kun & Yang, Bo-Lun, 2018. "Thermodynamic and kinetic analysis of an integrated solar thermochemical energy storage system for dry-reforming of methane," Energy, Elsevier, vol. 164(C), pages 937-950.
    • Handle: RePEc:eee:energy:v:164:y:2018:i:c:p:937-950
    DOI: 10.1016/j.energy.2018.08.209
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    References listed on IDEAS

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    1. Agrafiotis, Christos & Roeb, Martin & Sattler, Christian, 2015. "A review on solar thermal syngas production via redox pair-based water/carbon dioxide splitting thermochemical cycles," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 254-285.
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    Cited by:

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    2. Cabeza, Luisa F. & de Gracia, Alvaro & Zsembinszki, Gabriel & Borri, Emiliano, 2021. "Perspectives on thermal energy storage research," Energy, Elsevier, vol. 231(C).
    3. Zhang, Hao & Shuai, Yong & Lougou, Bachirou Guene & Jiang, Boshu & Wang, Fuqiang & Cheng, Ziming & Tan, Heping, 2020. "Effects of multilayer porous ceramics on thermochemical energy conversion and storage efficiency in solar dry reforming of methane reactor," Applied Energy, Elsevier, vol. 265(C).
    4. Chistyakov, A.V. & Nikolaev, S.A. & Zharova, P.A. & Tsodikov, M.V. & Manenti, F., 2019. "Linear α-alcohols production from supercritical ethanol over Cu/Al2O3 catalyst," Energy, Elsevier, vol. 166(C), pages 569-576.
    5. Wang, Hongsheng & Wang, Bingzheng & Qi, Xingyu & Wang, Jian & Yang, Rufan & Li, Duanxing & Hu, Xuejiao, 2021. "Innovative non–oxidative methane dehydroaromatization via solar membrane reactor," Energy, Elsevier, vol. 216(C).

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