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Techno-Economic Assessment of Solar Hydrogen Production by Means of Thermo-Chemical Cycles

Author

Listed:
  • Massimo Moser

    (Department of Energy System Analysis, Institute of Engineering Thermodynamics, German Aerospace Center (DLR), Pfaffenwaldring 38, 70569 Stuttgart, Germany)

  • Matteo Pecchi

    (Department of Energy System Analysis, Institute of Engineering Thermodynamics, German Aerospace Center (DLR), Pfaffenwaldring 38, 70569 Stuttgart, Germany
    Faculty of Science and Technology, Free University of Bozen-Bolzano Universitätsplatz—Piazza Università, 5, 39100 Bozen-Bolzano, Italy)

  • Thomas Fend

    (Department of Solar Chemical Engineering, Institute of Solar Research, German Aerospace Center (DLR), Linder Höhe, 51147 Köln-Porz, Germany)

Abstract

This paper presents the system analysis and the techno-economic assessment of selected solar hydrogen production paths based on thermochemical cycles. The analyzed solar technology is Concentrated Solar Power (CSP). Solar energy is used in order to run a two-step thermochemical cycle based on two different red-ox materials, namely nickel-ferrite and cerium dioxide (ceria). Firstly, a flexible mathematical model has been implemented to design and to operate the system. The tool is able to perform annual yield calculations based on hourly meteorological data. Secondly, a sensitivity analysis over key-design and operational techno-economic parameters has been carried out. The main outcomes are presented and critically discussed. The technical comparison of nickel-ferrite and ceria cycles showed that the integration of a large number of reactors can be optimized by considering a suitable time displacement among the activation of the single reactors working in parallel. In addition the comparison demonstrated that ceria achieves higher efficiency than nickel-ferrite (13.4% instead 6.4%), mainly because of the different kinetics. This difference leads to a lower LCOH for ceria (13.06 €/kg and 6.68 €/kg in the base case and in the best case scenario, respectively).

Suggested Citation

  • Massimo Moser & Matteo Pecchi & Thomas Fend, 2019. "Techno-Economic Assessment of Solar Hydrogen Production by Means of Thermo-Chemical Cycles," Energies, MDPI, vol. 12(3), pages 1-17, January.
    • Handle: RePEc:gam:jeners:v:12:y:2019:i:3:p:352-:d:200192
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    References listed on IDEAS

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    2. Hoskins, Amanda L. & Millican, Samantha L. & Czernik, Caitlin E. & Alshankiti, Ibraheam & Netter, Judy C. & Wendelin, Timothy J. & Musgrave, Charles B. & Weimer, Alan W., 2019. "Continuous on-sun solar thermochemical hydrogen production via an isothermal redox cycle," Applied Energy, Elsevier, vol. 249(C), pages 368-376.
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