IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v172y2016icp96-106.html
   My bibliography  Save this article

Novel microstructured polyol–polystyrene composites for seasonal heat storage

Author

Listed:
  • Puupponen, Salla
  • Mikkola, Valtteri
  • Ala-Nissila, Tapio
  • Seppälä, Ari

Abstract

We propose a robust route to prepare novel supercooling microstructured phase change materials (PCMs) suitable for seasonal thermal energy storage (STES) or heat protection applications. Two supercooling polyols, erythritol and xylitol, are successfully prepared as novel microencapsulated PCM-polystyrene composites with polyol mass fractions of 62wt% and 67wt%, respectively, and average void diameter of ∼50μm. Thermal properties of the composites and bulk polyols are studied thoroughly with differential scanning calorimetry (DSC) and thermal conductivity analyzer. Significant differences in heat storage properties of microstructured and bulk PCM are observed. The heat release of microstructured erythritol is more controlled than that of bulk PCM, making the novel microengineered PCMs particularly interesting for STES. In the case of bulk PCM, the heat release may occur spontaneously due to crystallization by surface roughnesses or impurities, whereas these factors have only little impact on the crystallization of microstructured erythritol, making the novel composite more reliable for long-term heat storage purposes. In addition, microstructured polyol–polystyrene composites show anomalous enhancement in the specific heat as compared to bulk polyols. This enhancement may originate from strong polyol–surfactant interactions in the composites.

Suggested Citation

  • Puupponen, Salla & Mikkola, Valtteri & Ala-Nissila, Tapio & Seppälä, Ari, 2016. "Novel microstructured polyol–polystyrene composites for seasonal heat storage," Applied Energy, Elsevier, vol. 172(C), pages 96-106.
    • Handle: RePEc:eee:appene:v:172:y:2016:i:c:p:96-106
    DOI: 10.1016/j.apenergy.2016.03.023
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261916303348
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2016.03.023?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Zhou, D. & Zhao, C.Y. & Tian, Y., 2012. "Review on thermal energy storage with phase change materials (PCMs) in building applications," Applied Energy, Elsevier, vol. 92(C), pages 593-605.
    2. Wang, Lijiu & Meng, Duo, 2010. "Fatty acid eutectic/polymethyl methacrylate composite as form-stable phase change material for thermal energy storage," Applied Energy, Elsevier, vol. 87(8), pages 2660-2665, August.
    3. Warzoha, Ronald J. & Weigand, Rebecca M. & Fleischer, Amy S., 2015. "Temperature-dependent thermal properties of a paraffin phase change material embedded with herringbone style graphite nanofibers," Applied Energy, Elsevier, vol. 137(C), pages 716-725.
    4. Li, Min & Kao, Hongtao & Wu, Zhishen & Tan, Jinmiao, 2011. "Study on preparation and thermal property of binary fatty acid and the binary fatty acids/diatomite composite phase change materials," Applied Energy, Elsevier, vol. 88(5), pages 1606-1612, May.
    5. Konuklu, Yeliz & Paksoy, Halime O. & Unal, Murat, 2015. "Nanoencapsulation of n-alkanes with poly(styrene-co-ethylacrylate) shells for thermal energy storage," Applied Energy, Elsevier, vol. 150(C), pages 335-340.
    6. Cheng, Wenlong & Xie, Biao & Zhang, Rongming & Xu, Zhiming & Xia, Yuting, 2015. "Effect of thermal conductivities of shape stabilized PCM on under-floor heating system," Applied Energy, Elsevier, vol. 144(C), pages 10-18.
    7. Sharma, Atul & Tyagi, V.V. & Chen, C.R. & Buddhi, D., 2009. "Review on thermal energy storage with phase change materials and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(2), pages 318-345, February.
    8. Hawlader, M. N. A. & Uddin, M. S. & Khin, Mya Mya, 2003. "Microencapsulated PCM thermal-energy storage system," Applied Energy, Elsevier, vol. 74(1-2), pages 195-202, January.
    9. Paksoy, H.O & Andersson, O & Abaci, S & Evliya, H & Turgut, B, 2000. "Heating and cooling of a hospital using solar energy coupled with seasonal thermal energy storage in an aquifer," Renewable Energy, Elsevier, vol. 19(1), pages 117-122.
    10. Novo, Amaya V. & Bayon, Joseba R. & Castro-Fresno, Daniel & Rodriguez-Hernandez, Jorge, 2010. "Review of seasonal heat storage in large basins: Water tanks and gravel-water pits," Applied Energy, Elsevier, vol. 87(2), pages 390-397, February.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Liu, Huan & Jing, Jianwei & Liu, Jianxin & Wang, Xiaodong, 2024. "Sugar alcohol-based phase change materials for thermal energy storage: Optimization design and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 199(C).
    2. Chen, J. & Zhang, P., 2017. "Preparation and characterization of nano-sized phase change emulsions as thermal energy storage and transport media," Applied Energy, Elsevier, vol. 190(C), pages 868-879.
    3. Gianluca Coccia & Alessia Aquilanti & Sebastiano Tomassetti & Pio Francesco Muciaccia & Giovanni Di Nicola, 2021. "Experimental Analysis of Nucleation Triggering in a Thermal Energy Storage Based on Xylitol Used in a Portable Solar Box Cooker," Energies, MDPI, vol. 14(18), pages 1-21, September.
    4. Turunen, Konsta & Yazdani, Maryam Roza & Puupponen, Salla & Santasalo-Aarnio, Annukka & Seppälä, Ari, 2020. "Cold-crystallizing erythritol-polyelectrolyte: Scaling up reliable long-term heat storage material," Applied Energy, Elsevier, vol. 266(C).
    5. Englmair, Gerald & Moser, Christoph & Furbo, Simon & Dannemand, Mark & Fan, Jianhua, 2018. "Design and functionality of a segmented heat-storage prototype utilizing stable supercooling of sodium acetate trihydrate in a solar heating system," Applied Energy, Elsevier, vol. 221(C), pages 522-534.
    6. Turunen, Konsta & Mikkola, Valtteri & Laukkanen, Timo & Seppälä, Ari, 2023. "Long-term thermal energy storage prototype of cold-crystallizing erythritol-polyelectrolyte," Applied Energy, Elsevier, vol. 332(C).
    7. Shao, Xue-Feng & Wang, Chao & Yang, Yong-Jian & Feng, Biao & Zhu, Zi-Qin & Wang, Wu-Jun & Zeng, Yi & Fan, Li-Wu, 2018. "Screening of sugar alcohols and their binary eutectic mixtures as phase change materials for low-to-medium temperature latent heat storage. (Ⅰ): Non-isothermal melting and crystallization behaviors," Energy, Elsevier, vol. 160(C), pages 1078-1090.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Memon, Shazim Ali, 2014. "Phase change materials integrated in building walls: A state of the art review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 31(C), pages 870-906.
    2. Parameshwaran, R. & Kalaiselvam, S. & Harikrishnan, S. & Elayaperumal, A., 2012. "Sustainable thermal energy storage technologies for buildings: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 2394-2433.
    3. Alva, Guruprasad & Huang, Xiang & Liu, Lingkun & Fang, Guiyin, 2017. "Synthesis and characterization of microencapsulated myristic acid–palmitic acid eutectic mixture as phase change material for thermal energy storage," Applied Energy, Elsevier, vol. 203(C), pages 677-685.
    4. Ahmed Hassan & Mohammad Shakeel Laghari & Yasir Rashid, 2016. "Micro-Encapsulated Phase Change Materials: A Review of Encapsulation, Safety and Thermal Characteristics," Sustainability, MDPI, vol. 8(10), pages 1-32, October.
    5. Kumar, Ashish & Saha, Sandip K., 2020. "Experimental and numerical study of latent heat thermal energy storage with high porosity metal matrix under intermittent heat loads," Applied Energy, Elsevier, vol. 263(C).
    6. Rao, Zhonghao & Wang, Shuangfeng & Peng, Feifei, 2012. "Self diffusion of the nano-encapsulated phase change materials: A molecular dynamics study," Applied Energy, Elsevier, vol. 100(C), pages 303-308.
    7. Cai, Yibing & Gao, Chuntao & Zhang, Ting & Zhang, Zhen & Wei, Qufu & Du, Jinmei & Hu, Yuan & Song, Lei, 2013. "Influences of expanded graphite on structural morphology and thermal performance of composite phase change materials consisting of fatty acid eutectics and electrospun PA6 nanofibrous mats," Renewable Energy, Elsevier, vol. 57(C), pages 163-170.
    8. Yataganbaba, Alptug & Ozkahraman, Bengi & Kurtbas, Irfan, 2017. "Worldwide trends on encapsulation of phase change materials: A bibliometric analysis (1990–2015)," Applied Energy, Elsevier, vol. 185(P1), pages 720-731.
    9. Merlin, Kevin & Soto, Jérôme & Delaunay, Didier & Traonvouez, Luc, 2016. "Industrial waste heat recovery using an enhanced conductivity latent heat thermal energy storage," Applied Energy, Elsevier, vol. 183(C), pages 491-503.
    10. Liu, Yang & Zheng, Ruowei & Li, Ji, 2022. "High latent heat phase change materials (PCMs) with low melting temperature for thermal management and storage of electronic devices and power batteries: Critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
    11. Giro-Paloma, Jessica & Oncins, Gerard & Barreneche, Camila & Martínez, Mònica & Fernández, A. Inés & Cabeza, Luisa F., 2013. "Physico-chemical and mechanical properties of microencapsulated phase change material," Applied Energy, Elsevier, vol. 109(C), pages 441-448.
    12. Zhao, Pin & Yue, Qinyan & He, Hongtao & Gao, Baoyu & Wang, Yan & Li, Qian, 2014. "Study on phase diagram of fatty acids mixtures to determine eutectic temperatures and the corresponding mixing proportions," Applied Energy, Elsevier, vol. 115(C), pages 483-490.
    13. Jamekhorshid, A. & Sadrameli, S.M. & Farid, M., 2014. "A review of microencapsulation methods of phase change materials (PCMs) as a thermal energy storage (TES) medium," Renewable and Sustainable Energy Reviews, Elsevier, vol. 31(C), pages 531-542.
    14. Tatsidjodoung, Parfait & Le Pierrès, Nolwenn & Luo, Lingai, 2013. "A review of potential materials for thermal energy storage in building applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 18(C), pages 327-349.
    15. Chen, Weiwang & Weng, Wenguo, 2016. "Ultrafine lauric–myristic acid eutectic/poly (meta-phenylene isophthalamide) form-stable phase change fibers for thermal energy storage by electrospinning," Applied Energy, Elsevier, vol. 173(C), pages 168-176.
    16. Khan, Mohammed Mumtaz A. & Saidur, R. & Al-Sulaiman, Fahad A., 2017. "A review for phase change materials (PCMs) in solar absorption refrigeration systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 76(C), pages 105-137.
    17. Yang, Xiaohu & Feng, Shangsheng & Zhang, Qunli & Chai, Yue & Jin, Liwen & Lu, Tian Jian, 2017. "The role of porous metal foam on the unidirectional solidification of saturating fluid for cold storage," Applied Energy, Elsevier, vol. 194(C), pages 508-521.
    18. Ioan Sarbu & Calin Sebarchievici, 2018. "A Comprehensive Review of Thermal Energy Storage," Sustainability, MDPI, vol. 10(1), pages 1-32, January.
    19. Golestaneh, S.I. & Mosallanejad, A. & Karimi, G. & Khorram, M. & Khashi, M., 2016. "Fabrication and characterization of phase change material composite fibers with wide phase-transition temperature range by co-electrospinning method," Applied Energy, Elsevier, vol. 182(C), pages 409-417.
    20. Ye, Hong & Long, Linshuang & Zhang, Haitao & Zou, Ruqiang, 2014. "The performance evaluation of shape-stabilized phase change materials in building applications using energy saving index," Applied Energy, Elsevier, vol. 113(C), pages 1118-1126.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:172:y:2016:i:c:p:96-106. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.