IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v113y2014icp751-757.html
   My bibliography  Save this article

Effect of a homogeneous combustion catalyst on the characteristics of diesel soot emitted from a compression ignition engine

Author

Listed:
  • Ma, Yu
  • Zhu, Mingming
  • Zhang, Dongke

Abstract

The effect of a ferrous picrate based homogeneous combustion catalyst (FPC), known to improve diesel combustion efficiency, on the morphological and chemical characteristics of diesel soot was studied in detail. Diesel soot samples emitted from a laboratory CI engine fuelled with a commercial diesel, with and without FPC doping, were collected and characterised using a combination of several advanced analytical techniques including a TEM fitted with EELS, an FT-IR, and a solid state 13C NMR, in addition to elemental analysis. Compared to the soot from the reference diesel, the soot particle sizes of both primary soot and aggregates from the FPC treated diesel were consistently smaller and decreased with increasing FPC dosage. Both types of soot showed similar fractal dimensions, indicating that there were no apparent changes in the formation mechanisms of the primary soot particles and their agglomeration processes. Furthermore, the types of the carbon bonds and organic functional groups in the soot were virtually unaffected by FPC, as indicated by the similar degrees of graphitisation and indistinguishable chemical structures in the two types of soot. However, the soot from the FPC treated diesel showed slightly higher C/H and C/O ratios than those from the reference diesel. Based on these observations, it was speculated that FPC enhanced the diesel combustion process, leaving fewer soot precursors, and also promoted the oxidation of soot particles, resulting in smaller sizes of the primary soot and aggregates and reduced the overall soot emissions.

Suggested Citation

  • Ma, Yu & Zhu, Mingming & Zhang, Dongke, 2014. "Effect of a homogeneous combustion catalyst on the characteristics of diesel soot emitted from a compression ignition engine," Applied Energy, Elsevier, vol. 113(C), pages 751-757.
  • Handle: RePEc:eee:appene:v:113:y:2014:i:c:p:751-757
    DOI: 10.1016/j.apenergy.2013.08.028
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261913006636
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.apenergy.2013.08.028?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Knecht, Walter, 2008. "Diesel engine development in view of reduced emission standards," Energy, Elsevier, vol. 33(2), pages 264-271.
    2. Zhu, Mingming & Ma, Yu & Zhang, Dongke, 2012. "Effect of a homogeneous combustion catalyst on the combustion characteristics and fuel efficiency in a diesel engine," Applied Energy, Elsevier, vol. 91(1), pages 166-172.
    3. Ma, Yu & Zhu, Mingming & Zhang, Dongke, 2013. "The effect of a homogeneous combustion catalyst on exhaust emissions from a single cylinder diesel engine," Applied Energy, Elsevier, vol. 102(C), pages 556-562.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Setyawan, Hendrix Y. & Zhu, Mingming & Zhang, Zhezi & Zhang, Dongke, 2016. "Ignition and combustion characteristics of single droplets of a crude glycerol in comparison with pure glycerol, petroleum diesel, biodiesel and ethanol," Energy, Elsevier, vol. 113(C), pages 153-159.
    2. Saxena, Vishal & Kumar, Niraj & Saxena, Vinod Kumar, 2019. "Multi-objective optimization of modified nanofluid fuel blends at different TiO2 nanoparticle concentration in diesel engine: Experimental assessment and modeling," Applied Energy, Elsevier, vol. 248(C), pages 330-353.
    3. Rajaeifar, Mohammad Ali & Abdi, Reza & Tabatabaei, Meisam, 2017. "Expanded polystyrene waste application for improving biodiesel environmental performance parameters from life cycle assessment point of view," Renewable and Sustainable Energy Reviews, Elsevier, vol. 74(C), pages 278-298.
    4. He-Ming Dong & Qian Du & Dun Li & Zhao-Yang Cui & Jian-Min Gao & Shao-Hua Wu, 2019. "Impacts of Organic Structures and Inherent Minerals of Coal on Soot Formation during Pyrolysis," Energies, MDPI, vol. 12(23), pages 1-16, November.
    5. Wang, Yuesen & Liang, Xingyu & Shu, Gequn & Wang, Xiangxiang & Sun, Xiuxiu & Liu, Changwen, 2014. "Effect of lubricant oil additive on size distribution, morphology, and nanostructure of diesel particulate matter," Applied Energy, Elsevier, vol. 130(C), pages 33-40.
    6. Wu, Shaohua & Yang, Wenming & Xu, Hongpeng & Jiang, Yu, 2019. "Investigation of soot aggregate formation and oxidation in compression ignition engines with a pseudo bi-variate soot model," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    7. Zhang, Zhi-Hui & Balasubramanian, Rajasekhar, 2015. "Influence of an iron-based fuel-borne catalyst on physicochemical and toxicological characteristics of particulate emissions from a diesel engine," Applied Energy, Elsevier, vol. 146(C), pages 270-278.
    8. Lao, Chung Ting & Akroyd, Jethro & Eaves, Nickolas & Smith, Alastair & Morgan, Neal & Nurkowski, Daniel & Bhave, Amit & Kraft, Markus, 2020. "Investigation of the impact of the configuration of exhaust after-treatment system for diesel engines," Applied Energy, Elsevier, vol. 267(C).
    9. Orihuela, M. Pilar & Chacartegui, Ricardo & Martínez-Fernández, Julián, 2020. "New biomorphic filters to face upcoming particulate emissions policies: A review of the FIL-BIO-DIESEL project," Energy, Elsevier, vol. 201(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Zhang, Zhi-Hui & Balasubramanian, Rajasekhar, 2015. "Influence of an iron-based fuel-borne catalyst on physicochemical and toxicological characteristics of particulate emissions from a diesel engine," Applied Energy, Elsevier, vol. 146(C), pages 270-278.
    2. Marcin Tkaczyk & Zbigniew J. Sroka & Konrad Krakowian & Radoslaw Wlostowski, 2020. "Experimental Study of the Effect of Fuel Catalytic Additive on Specific Fuel Consumption and Exhaust Emissions in Diesel Engine," Energies, MDPI, vol. 14(1), pages 1-14, December.
    3. Ma, Yu & Zhu, Mingming & Zhang, Dongke, 2013. "The effect of a homogeneous combustion catalyst on exhaust emissions from a single cylinder diesel engine," Applied Energy, Elsevier, vol. 102(C), pages 556-562.
    4. Saxena, Vishal & Kumar, Niraj & Saxena, Vinod Kumar, 2019. "Multi-objective optimization of modified nanofluid fuel blends at different TiO2 nanoparticle concentration in diesel engine: Experimental assessment and modeling," Applied Energy, Elsevier, vol. 248(C), pages 330-353.
    5. Wong, Ka In & Wong, Pak Kin & Cheung, Chun Shun & Vong, Chi Man, 2013. "Modeling and optimization of biodiesel engine performance using advanced machine learning methods," Energy, Elsevier, vol. 55(C), pages 519-528.
    6. Li, Dun & Gao, Jianmin & Zhao, Ziqi & Du, Qian & Dong, Heming & Cui, Zhaoyang, 2022. "Effects of iron on coal pyrolysis-derived soot formation," Energy, Elsevier, vol. 249(C).
    7. EL-Seesy, Ahmed I. & Hassan, Hamdy, 2019. "Investigation of the effect of adding graphene oxide, graphene nanoplatelet, and multiwalled carbon nanotube additives with n-butanol-Jatropha methyl ester on a diesel engine performance," Renewable Energy, Elsevier, vol. 132(C), pages 558-574.
    8. Zhu, Mingming & Ma, Yu & Zhang, Dongke, 2012. "Effect of a homogeneous combustion catalyst on the combustion characteristics and fuel efficiency in a diesel engine," Applied Energy, Elsevier, vol. 91(1), pages 166-172.
    9. Serrano, J. & Jiménez-Espadafor, F.J. & Lora, A. & Modesto-López, L. & Gañán-Calvo, A. & López-Serrano, J., 2019. "Experimental analysis of NOx reduction through water addition and comparison with exhaust gas recycling," Energy, Elsevier, vol. 168(C), pages 737-752.
    10. El-Seesy, Ahmed I. & Hassan, Hamdy & Ookawara, S., 2018. "Effects of graphene nanoplatelet addition to jatropha Biodiesel–Diesel mixture on the performance and emission characteristics of a diesel engine," Energy, Elsevier, vol. 147(C), pages 1129-1152.
    11. Sarvestani, Nasrin Sabet & Tabasizadeh, Mohammad & Abbaspour Fard, Mohammad Hossein & Nayebzadeh, Hamed & Van, Thuy Chu & Jafari, Mohammad & Bodisco, Timothy A. & Ristovski, Zoran & Brown, Richard J., 2021. "Effects of enhanced fuel with Mg-doped Fe3O4 nanoparticles on combustion of a compression ignition engine: Influence of Mg cation concentration," Renewable and Sustainable Energy Reviews, Elsevier, vol. 141(C).
    12. Usón, Alfonso Aranda & Capilla, Antonio Valero & Bribián, Ignacio Zabalza & Scarpellini, Sabina & Sastresa, Eva Llera, 2011. "Energy efficiency in transport and mobility from an eco-efficiency viewpoint," Energy, Elsevier, vol. 36(4), pages 1916-1923.
    13. Zhu, Mingming & Ma, Yu & Zhang, Dongke, 2011. "An experimental study of the effect of a homogeneous combustion catalyst on fuel consumption and smoke emission in a diesel engine," Energy, Elsevier, vol. 36(10), pages 6004-6009.
    14. Payri, F. & Broatch, A. & Serrano, J.R. & Piqueras, P., 2011. "Experimental–theoretical methodology for determination of inertial pressure drop distribution and pore structure properties in wall-flow diesel particulate filters (DPFs)," Energy, Elsevier, vol. 36(12), pages 6731-6744.
    15. Hosseini, Seyyed Hassan & Taghizadeh-Alisaraei, Ahmad & Ghobadian, Barat & Abbaszadeh-Mayvan, Ahmad, 2017. "Effect of added alumina as nano-catalyst to diesel-biodiesel blends on performance and emission characteristics of CI engine," Energy, Elsevier, vol. 124(C), pages 543-552.
    16. Chen, Zaiwang & Cai, Yikang & Xu, Guangfu & Duan, Huiquan & Jia, Ming, 2022. "Exploring the potential of water injection (WI) in a high-load diesel engine under different fuel injection strategies," Energy, Elsevier, vol. 243(C).
    17. Bergek, Anna & Berggren, Christian, 2014. "The impact of environmental policy instruments on innovation: A review of energy and automotive industry studies," Ecological Economics, Elsevier, vol. 106(C), pages 112-123.
    18. Othman, Mohd Fahmi & Adam, Abdullah & Najafi, G. & Mamat, Rizalman, 2017. "Green fuel as alternative fuel for diesel engine: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 694-709.
    19. Hamisu Adamu Dandajeh & Midhat Talibi & Nicos Ladommatos & Paul Hellier, 2019. "Influence of Combustion Characteristics and Fuel Composition on Exhaust PAHs in a Compression Ignition Engine," Energies, MDPI, vol. 12(13), pages 1-19, July.
    20. Benajes, Jesús & Novella, Ricardo & García, Antonio & Arthozoul, Simon, 2011. "The role of in-cylinder gas density and oxygen concentration on late spray mixing and soot oxidation processes," Energy, Elsevier, vol. 36(3), pages 1599-1611.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:113:y:2014:i:c:p:751-757. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.