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Effects of waste cooking oil-based biodiesel on the toxic organic pollutant emissions from a diesel engine

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Listed:
  • Chang, Yu-Cheng
  • Lee, Wen-Jhy
  • Wang, Lin-Chi
  • Yang, Hsi-Hsien
  • Cheng, Man-Ting
  • Lu, Jau-Huai
  • Tsai, Ying I.
  • Young, Li-Hao

Abstract

This study describes a method for reducing the emissions of toxic organic pollutants from heavy duty diesel engines fueled by biodiesel produced from waste cooking oil (WCO). An analytical method was developed to simultaneously measure five pollutants from one exhaust sample, namely polycyclic aromatic hydrocarbons (PAHs), polychlorined dibenzo-p-dixins and dibenzofurans (PCDD/Fs), polychlorinated biphenyls (PCBs), polybrominated dibenzo-p-dioxins and dibenzofurans (PBDD/Fs) and polybrominated diphenyl ethers (PBDEs). As yet, no data regarding PBDD/F emissions from mobile sources has been reported in the literature. The mass concentrations in the exhaust, in order, were PAHs≫PBDEs≫PBDD/Fs>PCBs>PCDD/Fs, while for the pollutants having dioxin-like toxicity, their toxicity concentrations, in order, were PCDD/Fs>PBDD/Fs>PCBs. These concentrations were two to four orders higher than those in the atmosphere. Even though the chlorine content in the WCO-based biodiesel was five times higher than that of fossil diesel, the reduction in the emission factors of the aforesaid pollutants increased along with the percentage of biodiesel. For example, B20 achieved a 49–73% and 61–83% reduction in mass and toxicity, respectively. In conclusion, the use of WCO-based biodiesel not only solves the problem of waste oil disposal, but also reduces the toxic organic pollutant emissions from diesel engines.

Suggested Citation

  • Chang, Yu-Cheng & Lee, Wen-Jhy & Wang, Lin-Chi & Yang, Hsi-Hsien & Cheng, Man-Ting & Lu, Jau-Huai & Tsai, Ying I. & Young, Li-Hao, 2014. "Effects of waste cooking oil-based biodiesel on the toxic organic pollutant emissions from a diesel engine," Applied Energy, Elsevier, vol. 113(C), pages 631-638.
    • Handle: RePEc:eee:appene:v:113:y:2014:i:c:p:631-638
    DOI: 10.1016/j.apenergy.2013.08.005
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    2. Mwangi, John Kennedy & Lee, Wen-Jhy & Chang, Yu-Cheng & Chen, Chia-Yang & Wang, Lin-Chi, 2015. "An overview: Energy saving and pollution reduction by using green fuel blends in diesel engines," Applied Energy, Elsevier, vol. 159(C), pages 214-236.
    3. Cao, Leichang & Wang, Jieni & Liu, Cheng & Chen, Yanwei & Liu, Kuojin & Han, Sheng, 2014. "Ethylene vinyl acetate copolymer: A bio-based cold flow improver for waste cooking oil derived biodiesel blends," Applied Energy, Elsevier, vol. 132(C), pages 163-167.
    4. Sokač, Tea & Gojun, Martin & Tušek, Ana Jurinjak & Šalić, Anita & Zelić, Bruno, 2020. "Purification of biodiesel produced by lipase catalysed transesterification by ultrafiltration: Selection of membranes and analysis of membrane blocking mechanisms," Renewable Energy, Elsevier, vol. 159(C), pages 642-651.
    5. Solaimuthu, C. & Ganesan, V. & Senthilkumar, D. & Ramasamy, K.K., 2015. "Emission reductions studies of a biodiesel engine using EGR and SCR for agriculture operations in developing countries," Applied Energy, Elsevier, vol. 138(C), pages 91-98.
    6. Chiatti, Giancarlo & Chiavola, Ornella & Palmieri, Fulvio, 2017. "Vibration and acoustic characteristics of a city-car engine fueled with biodiesel blends," Applied Energy, Elsevier, vol. 185(P1), pages 664-670.
    7. Lim, Cheolsoo & Lee, Jongtae & Hong, Jihyung & Song, Changkeun & Han, Jinseok & Cha, Jun-Seok, 2014. "Evaluation of regulated and unregulated emissions from a diesel powered vehicle fueled with diesel/biodiesel blends in Korea," Energy, Elsevier, vol. 77(C), pages 533-541.
    8. Chen, Chia-Yang & Lee, Wen-Jhy & Wang, Lin-Chi & Chang, Yu-Cheng & Yang, Hsi-Hsien & Young, Li-Hao & Lu, Jau-Huai & Tsai, Ying I. & Cheng, Man-Ting & Mwangi, John Kennedy, 2017. "Impact of high soot-loaded and regenerated diesel particulate filters on the emissions of persistent organic pollutants from a diesel engine fueled with waste cooking oil-based biodiesel," Applied Energy, Elsevier, vol. 191(C), pages 35-43.

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