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Polarization phenomena of hydrogen-rich gas in high-permeance Pd and Pd–Cu membrane tubes

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  • Chen, Wei-Hsin
  • Hsia, Ming-Hsien
  • Chi, Yen-Hsun
  • Lin, Yu-Li
  • Yang, Chang-Chung

Abstract

Concentration polarization, a retarding effect upon hydrogen permeation across a membrane, will affect the performance of hydrogen separation. To recognize the concentration polarization behavior of hydrogen-rich gas in high-permeance membrane tubes, three palladium-based membranes with two pure palladium (Pd) membranes and one Pd–Cu alloy membrane are tested. Three important parameters, consisting of the H2 partial pressure difference, the flow rate at the exit of the retentate side and the H2 concentration in the feed gas mixture (H2+N2), are taken into account. A comparison to pure H2 permeation suggests that the concentration polarization is clearly exhibited when the gas mixture is fed. Decreasing the H2 concentration in the feed gas tends to deteriorate the polarization phenomenon. The sensitivity of polarization to H2 concentration is higher when its concentration in the feed gas is larger. For the gas mixtures with 50 and 75vol% of H2, the permeances of the membranes are reduced by 1–2 orders of magnitude. The permeances of the membranes are also affected a bit when the H2 partial pressure difference or the flow rate is altered.

Suggested Citation

  • Chen, Wei-Hsin & Hsia, Ming-Hsien & Chi, Yen-Hsun & Lin, Yu-Li & Yang, Chang-Chung, 2014. "Polarization phenomena of hydrogen-rich gas in high-permeance Pd and Pd–Cu membrane tubes," Applied Energy, Elsevier, vol. 113(C), pages 41-50.
    • Handle: RePEc:eee:appene:v:113:y:2014:i:c:p:41-50
    DOI: 10.1016/j.apenergy.2013.07.014
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    Cited by:

    1. Chen, Wei-Hsin & Tsai, Ching-Wei & Lin, Yu-Li, 2017. "Numerical studies of the influences of bypass on hydrogen separation in a multichannel Pd membrane system," Renewable Energy, Elsevier, vol. 104(C), pages 259-270.
    2. Yang, Wei-Wei & Tang, Xin-Yuan & Ma, Xu & Li, Jia-Chen & Xu, Chao & He, Ya-Ling, 2023. "Rapid prediction, optimization and design of solar membrane reactor by data-driven surrogate model," Energy, Elsevier, vol. 285(C).
    3. Chen, Wei-Hsin & Escalante, Jamin, 2020. "Influence of vacuum degree on hydrogen permeation through a Pd membrane in different H2/N2 gas mixtures," Renewable Energy, Elsevier, vol. 155(C), pages 1245-1263.
    4. Wei Feng & Qingyuan Wang & Xiaodong Zhu & Qingquan Kong & Jiejie Wu & Peipei Tu, 2018. "Influence of Hydrogen Sulfide and Redox Reactions on the Surface Properties and Hydrogen Permeability of Pd Membranes," Energies, MDPI, vol. 11(5), pages 1-10, May.
    5. Ribeirinha, P. & Abdollahzadeh, M. & Pereira, A. & Relvas, F. & Boaventura, M. & Mendes, A., 2018. "High temperature PEM fuel cell integrated with a cellular membrane methanol steam reformer: Experimental and modelling," Applied Energy, Elsevier, vol. 215(C), pages 659-669.
    6. Ribeirinha, P. & Abdollahzadeh, M. & Boaventura, M. & Mendes, A., 2017. "H2 production with low carbon content via MSR in packed bed membrane reactors for high-temperature polymeric electrolyte membrane fuel cell," Applied Energy, Elsevier, vol. 188(C), pages 409-419.
    7. Tang, Xin-Yuan & Yang, Wei-Wei & Ma, Xu & He, Ya-Ling, 2024. "Bionic leaf-inspired catalyst bed structure for solar membrane reactor aiming at efficient hydrogen production and separation," Applied Energy, Elsevier, vol. 355(C).
    8. Chen, Wei-Hsin & Kuo, Pei-Chi & Lin, Yu-Li, 2019. "Evolutionary computation for maximizing CO2 and H2 separation in multiple-tube palladium-membrane systems," Applied Energy, Elsevier, vol. 235(C), pages 299-310.

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