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Kinetic study on the liquefaction of wood and its three cell wall component in polyhydric alcohols

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  • Zhang, Hairong
  • Yang, Huijuan
  • Guo, Haijun
  • Huang, Chao
  • Xiong, Lian
  • Chen, Xinde

Abstract

To better understand liquefaction of lignocellulosic biomass, wood and its three cell wall components (lignin, hemicellulose and cellulose) were subjected to a liquefaction process using polyethylene glycol (PEG 400)/glycerol as liquefaction solvent. On the basis of the experimental results obtained at different temperatures (140, 160, and 180°C), a kinetics of liquefaction of wood and its major cell wall components was presented, and the kinetic parameters were estimated. The values of total activation energy obtained in the liquefaction were about 44.31kJmol−1 of lignin, 40.49kJmol−1 of hemicellulose, 73.25kJmol−1 of cellulose and 63.93kJmol−1 of wood. Hemicellulose was the most susceptible component to liquefaction among the three cell wall components, followed by the lignin and cellulose.

Suggested Citation

  • Zhang, Hairong & Yang, Huijuan & Guo, Haijun & Huang, Chao & Xiong, Lian & Chen, Xinde, 2014. "Kinetic study on the liquefaction of wood and its three cell wall component in polyhydric alcohols," Applied Energy, Elsevier, vol. 113(C), pages 1596-1600.
    • Handle: RePEc:eee:appene:v:113:y:2014:i:c:p:1596-1600
    DOI: 10.1016/j.apenergy.2013.09.009
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    References listed on IDEAS

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    1. Rezzoug, Sid-Ahmed & Capart, Richard, 2002. "Liquefaction of wood in two successive steps: solvolysis in ethylene-glycol and catalytic hydrotreatment," Applied Energy, Elsevier, vol. 72(3-4), pages 631-644, July.
    2. Seljak, Tine & Rodman Oprešnik, Samuel & Kunaver, Matjaž & Katrašnik, Tomaž, 2012. "Wood, liquefied in polyhydroxy alcohols as a fuel for gas turbines," Applied Energy, Elsevier, vol. 99(C), pages 40-49.
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    1. Giacomo Fabbrizi & Tommaso Giannoni & Leonardo Lorenzi & Andrea Nicolini & Paola Iodice & Valentina Coccia & Gianluca Cavalaglio & Mattia Gelosia, 2022. "High Solid and Low Cellulase Enzymatic Hydrolysis of Cardoon Stems Pretreated by Acidified γ-Valerolactone/Water Solution," Energies, MDPI, vol. 15(7), pages 1-12, April.
    2. Mattia Gelosia & Alessandro Bertini & Marco Barbanera & Tommaso Giannoni & Andrea Nicolini & Franco Cotana & Gianluca Cavalaglio, 2020. "Acid-Assisted Organosolv Pre-Treatment and Enzymatic Hydrolysis of Cynara cardunculus L. for Glucose Production," Energies, MDPI, vol. 13(16), pages 1-10, August.
    3. Tommaso Giannoni & Mattia Gelosia & Alessandro Bertini & Giacomo Fabbrizi & Andrea Nicolini & Valentina Coccia & Paola Iodice & Gianluca Cavalaglio, 2021. "Fractionation of Cynara cardunculus L. by Acidified Organosolv Treatment for the Extraction of Highly Digestible Cellulose and Technical Lignin," Sustainability, MDPI, vol. 13(16), pages 1-16, August.

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