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Yield and characteristics of shale oil from the retorting of oil shale and fine oil-shale ash mixtures

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  • Niu, Mengting
  • Wang, Sha
  • Han, Xiangxin
  • Jiang, Xiumin

Abstract

For exploring and optimizing the oil shale fluidized bed retort with fine oil-shale ash as a solid heat carrier, retorting experiments of oil shale and fine oil-shale ash mixtures were conducted in a lab-scale retorting reactor to investigate the effects of fine oil-shale ash on shale oil. Oil shale samples were obtained from Dachengzi Mine, China, and mixed with fine oil-shale ash in the ash/shale mass ratios of 0:1, 1:4, 1:2, 1:1, 2:1 and 4:1. The experimental retorting temperature was enhanced from room temperature to 520°C and the average heating rate was 12°Cmin−1. It was found that, with the increase of the oil-shale ash fraction, the shale oil yield first increased and then decreased obviously, whereas the gas yield appeared conversely. Shale oil was analyzed for the elemental analysis, presenting its atomic H/C ratio of 1.78–1.87. Further, extraction and simulated distillation of shale oil were also conducted to explore the quality of shale oil. As a result, the ash/shale mixing mass ratio of 1:2 was recommended only for the consideration of increasing the yield and quality of shale oil.

Suggested Citation

  • Niu, Mengting & Wang, Sha & Han, Xiangxin & Jiang, Xiumin, 2013. "Yield and characteristics of shale oil from the retorting of oil shale and fine oil-shale ash mixtures," Applied Energy, Elsevier, vol. 111(C), pages 234-239.
    • Handle: RePEc:eee:appene:v:111:y:2013:i:c:p:234-239
    DOI: 10.1016/j.apenergy.2013.04.089
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    2. Han, Xiangxin & Niu, Mengting & Jiang, Xiumin, 2014. "Combined fluidized bed retorting and circulating fluidized bed combustion system of oil shale: 2. Energy and economic analysis," Energy, Elsevier, vol. 74(C), pages 788-794.
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