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Kinetic modeling of liquid generation from oil shale in fixed bed retort

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  • Al-Ayed, Omar S.
  • Suliman, Mohd R.
  • Rahman, Nafi Abdel

Abstract

Kinetics of shale oil generation in a fixed bed retort is modeled using a second order rate equation. Samples from Ellajjun oil shale deposits are tested in 350-550 °C temperatures range. In each run, 400 g are charged to reactor and heated in a range of 2.2-10 °C min-1. Shale oil liquid is condensed at 0 ± 2 °C and its rate measured as function of time and temperature. Increasing heating rate from 2.2 to 10 °C min-1 decreased activation energy from 115 to 71.2 kJ mol-1 and frequency factor from 2.85 x 107 to 9.0 x 103 correspondingly. The generated data are modeled using Coats and Redfern differential and integral models. Good agreement has been obtained.

Suggested Citation

  • Al-Ayed, Omar S. & Suliman, Mohd R. & Rahman, Nafi Abdel, 2010. "Kinetic modeling of liquid generation from oil shale in fixed bed retort," Applied Energy, Elsevier, vol. 87(7), pages 2273-2277, July.
    • Handle: RePEc:eee:appene:v:87:y:2010:i:7:p:2273-2277
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    References listed on IDEAS

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    1. Al-Ayed, Omar S. & Matouq, M. & Anbar, Z. & Khaleel, Adnan M. & Abu-Nameh, Eyad, 2010. "Oil shale pyrolysis kinetics and variable activation energy principle," Applied Energy, Elsevier, vol. 87(4), pages 1269-1272, April.
    2. Jaber, J. O. & Probert, S. D., 1999. "Pyrolysis and gasification kinetics of Jordanian oil-shales," Applied Energy, Elsevier, vol. 63(4), pages 269-286, August.
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    Cited by:

    1. Niu, Mengting & Wang, Sha & Han, Xiangxin & Jiang, Xiumin, 2013. "Yield and characteristics of shale oil from the retorting of oil shale and fine oil-shale ash mixtures," Applied Energy, Elsevier, vol. 111(C), pages 234-239.
    2. Ziad Abu El-Rub & Joanna Kujawa & Samer Al-Gharabli, 2020. "Pyrolysis Kinetic Parameters of Omari Oil Shale Using Thermogravimetric Analysis," Energies, MDPI, vol. 13(16), pages 1-13, August.
    3. Wang, Qing & Zhao, Weizhen & Liu, Hongpeng & Jia, Chunxia & Li, Shaohua, 2011. "Interactions and kinetic analysis of oil shale semi-coke with cornstalk during co-combustion," Applied Energy, Elsevier, vol. 88(6), pages 2080-2087, June.
    4. Kang, Zhiqin & Zhao, Yangsheng & Yang, Dong, 2020. "Review of oil shale in-situ conversion technology," Applied Energy, Elsevier, vol. 269(C).

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