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Bio-syngas to gasoline and olefins via DME – A comprehensive techno-economic assessment

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  • Haro, Pedro
  • Trippe, Frederik
  • Stahl, Ralph
  • Henrich, Edmund

Abstract

The conversion of low-grade lignocellulosic biomass such as residual wood or straw to synthetic fuels and chemicals is currently being developed within the bioliq® concept (at the Karlsruhe Institute of Technology – KIT, Germany). The aim of this study is to model and assess three different synthesis process concepts with DME (dimethyl ether) as a platform chemical. The process concepts are designed and assessed using existing technologies, as well as the previous studies for pyrolysis and gasification sections. The respective considered products in the selected concepts are synthetic gasoline, ethylene and propylene. Using biomass for these applications can reduce fossil CO2 emissions by replacing non-renewable carbon sources. The techno-economic assessment concludes that total energy efficiency ranges between 37.5% and 41.1% for the production of gasoline and olefins, respectively. The resulting specific production cost in the gasoline concept is 72% higher than the current market price. In the olefins concept the difference to the current market prices of ethylene and propylene is reduced to 40%. The specific production costs in the gasoline and ethylene concept are 59% higher than current market prices. The possibility to sequestrate CO2 within the considered concepts at costs of 39€/t allow additional revenues from sequestrated CO2. In order to meet current market prices, the implications of sequestrated CO2, mineral oil tax reduction and the combination of both kinds of subsidies are evaluated in this study.

Suggested Citation

  • Haro, Pedro & Trippe, Frederik & Stahl, Ralph & Henrich, Edmund, 2013. "Bio-syngas to gasoline and olefins via DME – A comprehensive techno-economic assessment," Applied Energy, Elsevier, vol. 108(C), pages 54-65.
    • Handle: RePEc:eee:appene:v:108:y:2013:i:c:p:54-65
    DOI: 10.1016/j.apenergy.2013.03.015
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    References listed on IDEAS

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    Cited by:

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    2. Narvaez, A. & Chadwick, D. & Kershenbaum, L., 2019. "Performance of small-medium scale polygeneration systems for dimethyl ether and power production," Energy, Elsevier, vol. 188(C).
    3. Xiang, Dong & Qian, Yu & Man, Yi & Yang, Siyu, 2014. "Techno-economic analysis of the coal-to-olefins process in comparison with the oil-to-olefins process," Applied Energy, Elsevier, vol. 113(C), pages 639-647.
    4. Salman, Chaudhary Awais & Naqvi, Muhammad & Thorin, Eva & Yan, Jinyue, 2018. "Gasification process integration with existing combined heat and power plants for polygeneration of dimethyl ether or methanol: A detailed profitability analysis," Applied Energy, Elsevier, vol. 226(C), pages 116-128.
    5. Zimmer, Tobias & Rudi, Andreas & Müller, Ann-Kathrin & Fröhling, Magnus & Schultmann, Frank, 2017. "Modeling the impact of competing utilization paths on biomass-to-liquid (BtL) supply chains," Applied Energy, Elsevier, vol. 208(C), pages 954-971.
    6. Xiang, Dong & Xiang, Junjie & Sun, Zhe & Cao, Yan, 2017. "The integrated coke-oven gas and pulverized coke gasification for methanol production with highly efficient hydrogen utilization," Energy, Elsevier, vol. 140(P1), pages 78-91.
    7. Elsido, Cristina & Martelli, Emanuele & Kreutz, Thomas, 2019. "Heat integration and heat recovery steam cycle optimization for a low-carbon lignite/biomass-to-jet fuel demonstration project," Applied Energy, Elsevier, vol. 239(C), pages 1322-1342.
    8. Kuo, Yen-Ting & Almansa, G. Aranda & Vreugdenhil, B.J., 2018. "Catalytic aromatization of ethylene in syngas from biomass to enhance economic sustainability of gas production," Applied Energy, Elsevier, vol. 215(C), pages 21-30.
    9. Tanmay Chaturvedi & Ana I. Torres & George Stephanopoulos & Mette Hedegaard Thomsen & Jens Ejbye Schmidt, 2020. "Developing Process Designs for Biorefineries—Definitions, Categories, and Unit Operations," Energies, MDPI, vol. 13(6), pages 1-22, March.
    10. Kang, Yinhu & Wang, Quanhai & Lu, Xiaofeng & Wan, Hu & Ji, Xuanyu & Wang, Hu & Guo, Qiang & Yan, Jin & Zhou, Jinliang, 2015. "Experimental and numerical study on NOx and CO emission characteristics of dimethyl ether/air jet diffusion flame," Applied Energy, Elsevier, vol. 149(C), pages 204-224.
    11. Haro, Pedro & Aracil, Cristina & Vidal-Barrero, Fernando & Ollero, Pedro, 2015. "Rewarding of extra-avoided GHG emissions in thermochemical biorefineries incorporating Bio-CCS," Applied Energy, Elsevier, vol. 157(C), pages 255-266.
    12. Lausselet, Carine & Cherubini, Francesco & Oreggioni, Gabriel David & del Alamo Serrano, Gonzalo & Becidan, Michael & Hu, Xiangping & Rørstad, Per Kr. & Strømman, Anders Hammer, 2017. "Norwegian Waste-to-Energy: Climate change, circular economy and carbon capture and storage," Resources, Conservation & Recycling, Elsevier, vol. 126(C), pages 50-61.
    13. Patel, Madhumita & Zhang, Xiaolei & Kumar, Amit, 2016. "Techno-economic and life cycle assessment on lignocellulosic biomass thermochemical conversion technologies: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 53(C), pages 1486-1499.
    14. Man, Yi & Yang, Siyu & Zhang, Jun & Qian, Yu, 2014. "Conceptual design of coke-oven gas assisted coal to olefins process for high energy efficiency and low CO2 emission," Applied Energy, Elsevier, vol. 133(C), pages 197-205.
    15. Butera, Giacomo & Gadsbøll, Rasmus Østergaard & Ravenni, Giulia & Ahrenfeldt, Jesper & Henriksen, Ulrik Birk & Clausen, Lasse Røngaard, 2020. "Thermodynamic analysis of methanol synthesis combining straw gasification and electrolysis via the low temperature circulating fluid bed gasifier and a char bed gas cleaning unit," Energy, Elsevier, vol. 199(C).
    16. Haro, Pedro & Aracil, Cristina & Vidal-Barrero, Fernando & Ollero, Pedro, 2015. "Balance and saving of GHG emissions in thermochemical biorefineries," Applied Energy, Elsevier, vol. 147(C), pages 444-455.
    17. Nugroho, Yohanes Kristianto & Zhu, Liandong & Heavey, Cathal, 2022. "Building an agent-based techno-economic assessment coupled with life cycle assessment of biomass to methanol supply chains," Applied Energy, Elsevier, vol. 309(C).
    18. Perkins, Greg & Bhaskar, Thallada & Konarova, Muxina, 2018. "Process development status of fast pyrolysis technologies for the manufacture of renewable transport fuels from biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 90(C), pages 292-315.
    19. Uddin, Md Mosleh & Simson, Amanda & Wright, Mark Mba, 2020. "Techno-economic and greenhouse gas emission analysis of dimethyl ether production via the bi-reforming pathway for transportation fuel," Energy, Elsevier, vol. 211(C).

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