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Technoeconomic assessment of lignocellulosic ethanol production via DME (dimethyl ether) hydrocarbonylation

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  • Haro, P.
  • Ollero, P.
  • Villanueva Perales, A.L.
  • Reyes Valle, C.

Abstract

In this study, a new thermochemical route to produce lignocellulosic ethanol based on DME (dimethyl ether) hydrocarbonylation is proposed and economically assessed. The process is designed and evaluated using current kinetic laboratory data for hydrocarbonylation reactions. Only available technologies or those expected to be available in the short term are considered for the process design, which involves biomass pretreatment and gasification (indirect circulating fluidized bed), gas clean-up and conditioning, methanol synthesis, DME production by methanol dehydration and DME hydrocarbonylation. The process is designed to be both energy self-sufficient and electrical energy neutral. For a plant size of 2140 dry tonnes/day of wood chip (500 MWHHV) the minimum selling price of ethanol (for a 10% rate of return and a biomass price of 66 $/dry tonne) ranges from 0.555 to 0.592 USD2010/L of automotive grade ethanol with fixed capital costs between 333 and 352 M USD2010. Energy efficiency of biomass to ethanol ranges from 44.35 to 45.53% (high heating value basis). These results compare favorably with the “state of the art” production of ethanol via biochemical pathway from lignocellulosic biomass, revealing that the DME hydrocarbonylation route is a promising one that could be cost-competitive in the near future.

Suggested Citation

  • Haro, P. & Ollero, P. & Villanueva Perales, A.L. & Reyes Valle, C., 2012. "Technoeconomic assessment of lignocellulosic ethanol production via DME (dimethyl ether) hydrocarbonylation," Energy, Elsevier, vol. 44(1), pages 891-901.
    • Handle: RePEc:eee:energy:v:44:y:2012:i:1:p:891-901
    DOI: 10.1016/j.energy.2012.05.004
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    1. Villanueva Perales, A.L. & Reyes Valle, C. & Ollero, P. & Gómez-Barea, A., 2011. "Technoeconomic assessment of ethanol production via thermochemical conversion of biomass by entrained flow gasification," Energy, Elsevier, vol. 36(7), pages 4097-4108.
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    2. Haro, P. & Ollero, P. & Villanueva Perales, A.L. & Gómez-Barea, A., 2013. "Thermochemical biorefinery based on dimethyl ether as intermediate: Technoeconomic assessment," Applied Energy, Elsevier, vol. 102(C), pages 950-961.
    3. Fornell, Rickard & Berntsson, Thore & Åsblad, Anders, 2013. "Techno-economic analysis of a kraft pulp-mill-based biorefinery producing both ethanol and dimethyl ether," Energy, Elsevier, vol. 50(C), pages 83-92.
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    5. Gutiérrez, R.E. & Guerra, K. & Haro, P., 2022. "Exploring the techno-economic feasibility of new bioeconomy concepts: Solar-assisted thermochemical biorefineries," Applied Energy, Elsevier, vol. 322(C).
    6. Azize Ayol & Luciana Peixoto & Tugba Keskin & Haris Nalakath Abubackar, 2021. "Reactor Designs and Configurations for Biological and Bioelectrochemical C1 Gas Conversion: A Review," IJERPH, MDPI, vol. 18(21), pages 1-36, November.

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