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Thermodynamic analysis of methanol synthesis combining straw gasification and electrolysis via the low temperature circulating fluid bed gasifier and a char bed gas cleaning unit

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  • Butera, Giacomo
  • Gadsbøll, Rasmus Østergaard
  • Ravenni, Giulia
  • Ahrenfeldt, Jesper
  • Henriksen, Ulrik Birk
  • Clausen, Lasse Røngaard

Abstract

The phase-out of fossil fuels in the heavy transportation sector will require energy-dense biofuels like methanol, and will likely require that a wide range of biomasses are utilized. In this framework, gasification of straw and subsequent upgrading to methanol represents a potentially advantageous conversion route. In this study, the established low-temperature circulating fluid bed (LTCFB) gasifier is coupled to a partial oxidation (POX) and char bed reactor, which enables a relatively robust and effective conversion of tars - making the product gas suitable for methanol synthesis. Five scenarios producing methanol via traditional air-separation units and electrolysis were thermodynamically modeled and analyzed in Aspen Plus. The analysis showed state-of-the-art biomass-to-methanol energy efficiencies up to 54–56% and overall carbon conversions above 57%. A parametric analysis on the POX temperature revealed the potential to increase efficiency and the carbon conversion up to 58% and 68%, respectively. The proposed systems outperform alternative systems framed on straw gasification, and exceed in terms of efficiency and overall carbon conversion other solutions based on wood-gasification.

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  • Butera, Giacomo & Gadsbøll, Rasmus Østergaard & Ravenni, Giulia & Ahrenfeldt, Jesper & Henriksen, Ulrik Birk & Clausen, Lasse Røngaard, 2020. "Thermodynamic analysis of methanol synthesis combining straw gasification and electrolysis via the low temperature circulating fluid bed gasifier and a char bed gas cleaning unit," Energy, Elsevier, vol. 199(C).
    • Handle: RePEc:eee:energy:v:199:y:2020:i:c:s0360544220305120
    DOI: 10.1016/j.energy.2020.117405
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    3. Butera, Giacomo & Fendt, Sebastian & Jensen, Søren H. & Ahrenfeldt, Jesper & Clausen, Lasse R., 2020. "Flexible methanol production units coupling solid oxide cells and thermochemical biomass conversion via different gasification technologies," Energy, Elsevier, vol. 208(C).
    4. Chengjiang Li & Tingwen Jia & Shiyuan Wang & Xiaolin Wang & Michael Negnevitsky & Honglei Wang & Yujie Hu & Weibin Xu & Na Zhou & Gang Zhao, 2023. "Methanol Vehicles in China: A Review from a Policy Perspective," Sustainability, MDPI, vol. 15(12), pages 1-22, June.
    5. Li, Chengjiang & Jia, Tingwen & Wang, Honglei & Wang, Xiaolin & Negnevitsky, Michael & Hu, Yu-jie & Zhao, Gang & Wang, Liang, 2023. "Assessing the prospect of deploying green methanol vehicles in China from energy, environmental and economic perspectives," Energy, Elsevier, vol. 263(PE).

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