IDEAS home Printed from https://ideas.repec.org/a/wly/greenh/v8y2018i2p309-323.html
   My bibliography  Save this article

Sustainable coffee†based CO2 adsorbents: toward a greener production via hydrothermal carbonization

Author

Listed:
  • Nausika Querejeta
  • M. Victoria Gil
  • Fernando Rubiera
  • Covadonga Pevida

Abstract

Activated carbons for adsorption of CO2 under flue gas conditions were prepared by means of hydrothermal carbonization (HTC) and subsequent CO2 activation of spent coffee grounds. The HTC of the samples consisted of their heating at moderate temperature with a high water content in autoclave. A preliminary screening concluded that 1:2 biomass/water ratio (spent coffee grounds as received) and no chemicals added during HTC with further activation in CO2 at 800°C for 1 h are suitable conditions to produce the CO2 adsorbents. In addition, the response surface methodology (RSM) successfully evaluated the combined effect of HTC temperature and dwell time, to maximize the CO2 capture capacity within the experimental region. Both the lowest temperature and dwell time (120°C, 3 h) resulted in the maximum CO2 capture capacity (2.95 wt.%). Two activated carbons (ACs) were then produced: one via hydrothermal carbonization optimized by means of response surface methodology (RSM) followed by CO2 activation (HC†Co) and the other one by single†step CO2 activation as described in the Group's patent ES2526259 (AC†Co). Analysis of the features and performances of the two ACs revealed superior chemical and textural characteristics on HC†Co for CO2 adsorption under post†combustion capture conditions; HTC process is the sole responsible of this enhancement. Moreover, the proposed methodology to produce CO2 adsorbents from spent coffee grounds represents a more energy†efficient approach. © 2017 Society of Chemical Industry and John Wiley & Sons, Ltd.

Suggested Citation

  • Nausika Querejeta & M. Victoria Gil & Fernando Rubiera & Covadonga Pevida, 2018. "Sustainable coffee†based CO2 adsorbents: toward a greener production via hydrothermal carbonization," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 8(2), pages 309-323, April.
    • Handle: RePEc:wly:greenh:v:8:y:2018:i:2:p:309-323
    DOI: 10.1002/ghg.1740
    as

    Download full text from publisher

    File URL: https://doi.org/10.1002/ghg.1740
    Download Restriction: no
    File URL: https://libkey.io/10.1002/ghg.1740?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Zhao, Peitao & Shen, Yafei & Ge, Shifu & Chen, Zhenqian & Yoshikawa, Kunio, 2014. "Clean solid biofuel production from high moisture content waste biomass employing hydrothermal treatment," Applied Energy, Elsevier, vol. 131(C), pages 345-367.
    2. Kambo, Harpreet Singh & Dutta, Animesh, 2015. "A comparative review of biochar and hydrochar in terms of production, physico-chemical properties and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 45(C), pages 359-378.
    3. Plaza, M.G. & González, A.S. & Pevida, C. & Pis, J.J. & Rubiera, F., 2012. "Valorisation of spent coffee grounds as CO2 adsorbents for postcombustion capture applications," Applied Energy, Elsevier, vol. 99(C), pages 272-279.
    4. Plaza, M.G. & Durán, I. & Rubiera, F. & Pevida, C., 2015. "CO2 adsorbent pellets produced from pine sawdust: Effect of coal tar pitch addition," Applied Energy, Elsevier, vol. 144(C), pages 182-192.
    5. Hao, Wenming & Björkman, Eva & Lilliestråle, Malte & Hedin, Niklas, 2013. "Activated carbons prepared from hydrothermally carbonized waste biomass used as adsorbents for CO2," Applied Energy, Elsevier, vol. 112(C), pages 526-532.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. René A. Garrido & Camila Lagos & Carolina Luna & Jaime Sánchez & Georgina Díaz, 2021. "Study of the Potential Uses of Hydrochar from Grape Pomace and Walnut Shells Generated from Hydrothermal Carbonization as an Alternative for the Revalorization of Agri-Waste in Chile," Sustainability, MDPI, vol. 13(22), pages 1-10, November.
    2. García, R. & Gil, M.V. & Fanjul, A. & González, A. & Majada, J. & Rubiera, F. & Pevida, C., 2021. "Residual pyrolysis biochar as additive to enhance wood pellets quality," Renewable Energy, Elsevier, vol. 180(C), pages 850-859.
    3. Marcelina Sołtysik & Izabela Majchrzak-Kucęba & Dariusz Wawrzyńczak, 2022. "Bio-Waste as a Substitute for the Production of Carbon Dioxide Adsorbents: A Review," Energies, MDPI, vol. 15(19), pages 1-23, September.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Aragón-Briceño, C.I. & Pozarlik, A.K. & Bramer, E.A. & Niedzwiecki, Lukasz & Pawlak-Kruczek, H. & Brem, G., 2021. "Hydrothermal carbonization of wet biomass from nitrogen and phosphorus approach: A review," Renewable Energy, Elsevier, vol. 171(C), pages 401-415.
    2. Kambo, Harpreet Singh & Dutta, Animesh, 2015. "A comparative review of biochar and hydrochar in terms of production, physico-chemical properties and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 45(C), pages 359-378.
    3. Briongos, J.V. & Taramona, S. & Gómez-Hernández, J. & Mulone, V. & Santana, D., 2021. "Solar and biomass hybridization through hydrothermal carbonization," Renewable Energy, Elsevier, vol. 177(C), pages 268-279.
    4. Wang, Tengfei & Zhai, Yunbo & Zhu, Yun & Li, Caiting & Zeng, Guangming, 2018. "A review of the hydrothermal carbonization of biomass waste for hydrochar formation: Process conditions, fundamentals, and physicochemical properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 90(C), pages 223-247.
    5. Zhang, Chaoyue & Ma, Xiaoqian & Chen, Xinfei & Tian, Yunlong & Zhou, Yi & Lu, Xiaoluan & Huang, Tao, 2020. "Conversion of water hyacinth to value-added fuel via hydrothermal carbonization," Energy, Elsevier, vol. 197(C).
    6. Mäkelä, Mikko & Yoshikawa, Kunio, 2016. "Simulating hydrothermal treatment of sludge within a pulp and paper mill," Applied Energy, Elsevier, vol. 173(C), pages 177-183.
    7. Shen, Yafei & Yu, Shili & Ge, Shun & Chen, Xingming & Ge, Xinlei & Chen, Mindong, 2017. "Hydrothermal carbonization of medical wastes and lignocellulosic biomass for solid fuel production from lab-scale to pilot-scale," Energy, Elsevier, vol. 118(C), pages 312-323.
    8. Zhuang, Xiuzheng & Liu, Jianguo & Zhang, Qi & Wang, Chenguang & Zhan, Hao & Ma, Longlong, 2022. "A review on the utilization of industrial biowaste via hydrothermal carbonization," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    9. Liu, Tianyu & Wen, Chang & Li, Changkang & Yan, Kai & Li, Rui & Jing, Zhenqi & Zhang, Bohan & Ma, Jingjing, 2022. "Integrated water washing and carbonization pretreatment of typical herbaceous and woody biomass: Fuel properties, combustion behaviors, and techno-economic assessments," Renewable Energy, Elsevier, vol. 200(C), pages 218-233.
    10. Afolabi, Oluwasola O.D. & Sohail, M. & Cheng, Yu-Ling, 2020. "Optimisation and characterisation of hydrochar production from spent coffee grounds by hydrothermal carbonisation," Renewable Energy, Elsevier, vol. 147(P1), pages 1380-1391.
    11. Yuan, Xiangzhou & Wang, Junyao & Deng, Shuai & Suvarna, Manu & Wang, Xiaonan & Zhang, Wei & Hamilton, Sara Triana & Alahmed, Ammar & Jamal, Aqil & Park, Ah-Hyung Alissa & Bi, Xiaotao & Ok, Yong Sik, 2022. "Recent advancements in sustainable upcycling of solid waste into porous carbons for carbon dioxide capture," Renewable and Sustainable Energy Reviews, Elsevier, vol. 162(C).
    12. Plaza, M.G. & Durán, I. & Rubiera, F. & Pevida, C., 2015. "CO2 adsorbent pellets produced from pine sawdust: Effect of coal tar pitch addition," Applied Energy, Elsevier, vol. 144(C), pages 182-192.
    13. Giuseppe Maggiotto & Gianpiero Colangelo & Marco Milanese & Arturo de Risi, 2023. "Thermochemical Technologies for the Optimization of Olive Wood Biomass Energy Exploitation: A Review," Energies, MDPI, vol. 16(19), pages 1-17, September.
    14. Zhang, Zhikun & Zhu, Zongyuan & Shen, Boxiong & Liu, Lina, 2019. "Insights into biochar and hydrochar production and applications: A review," Energy, Elsevier, vol. 171(C), pages 581-598.
    15. Xue‐Fei Wang & Long Xiong & Li Li & Jun‐Jun Zhong, 2020. "Effect of heat treatment temperature on CO2 capture of nitrogen‐enriched porous carbon fibers," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 10(2), pages 461-471, April.
    16. Zhang, Minkai & Guo, Yincheng, 2013. "Rate based modeling of absorption and regeneration for CO2 capture by aqueous ammonia solution," Applied Energy, Elsevier, vol. 111(C), pages 142-152.
    17. Yao, Zhongliang & Ma, Xiaoqian & Xiao, Zhiyuan, 2020. "The effect of two pretreatment levels on the pyrolysis characteristics of water hyacinth," Renewable Energy, Elsevier, vol. 151(C), pages 514-527.
    18. Suiuay, Chokchai & Laloon, Kittipong & Katekaew, Somporn & Senawong, Kritsadang & Noisuwan, Phakamat & Sudajan, Somposh, 2020. "Effect of gasoline-like fuel obtained from hard-resin of Yang (Dipterocarpus alatus) on single cylinder gasoline engine performance and exhaust emissions," Renewable Energy, Elsevier, vol. 153(C), pages 634-645.
    19. Tobias Pröll & Florian Zerobin, 2019. "Biomass-based negative emission technology options with combined heat and power generation," Mitigation and Adaptation Strategies for Global Change, Springer, vol. 24(7), pages 1307-1324, October.
    20. Siti Zaharah Roslan & Siti Fairuz Zainudin & Alijah Mohd Aris & Khor Bee Chin & Mohibah Musa & Ahmad Rafizan Mohamad Daud & Syed Shatir A. Syed Hassan, 2023. "Hydrothermal Carbonization of Sewage Sludge into Solid Biofuel: Influences of Process Conditions on the Energetic Properties of Hydrochar," Energies, MDPI, vol. 16(5), pages 1-16, March.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:wly:greenh:v:8:y:2018:i:2:p:309-323. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Wiley Content Delivery (email available below). General contact details of provider: https://doi.org/10.1002/(ISSN)2152-3878 .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.