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Mild oxidation of methane to methanol or acetic acid on supported isolated rhodium catalysts

Author

Listed:
  • Junjun Shan

    (Tufts University
    NICE America Research, Inc.)

  • Mengwei Li

    (Tufts University)

  • Lawrence F. Allard

    (Oak Ridge National Laboratory)

  • Sungsik Lee

    (Argonne National Laboratory)

  • Maria Flytzani-Stephanopoulos

    (Tufts University)

Abstract

Single-site isolated rhodium species anchored on zeolites or titanium dioxide are shown to catalyse the direct conversion of methane to methanol and acetic acid, using oxygen and carbon monoxide under mild conditions.

Suggested Citation

  • Junjun Shan & Mengwei Li & Lawrence F. Allard & Sungsik Lee & Maria Flytzani-Stephanopoulos, 2017. "Mild oxidation of methane to methanol or acetic acid on supported isolated rhodium catalysts," Nature, Nature, vol. 551(7682), pages 605-608, November.
    • Handle: RePEc:nat:nature:v:551:y:2017:i:7682:d:10.1038_nature24640
    DOI: 10.1038/nature24640
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    1. Pengfei Xie & Jing Ding & Zihao Yao & Tiancheng Pu & Peng Zhang & Zhennan Huang & Canhui Wang & Junlei Zhang & Noah Zecher-Freeman & Han Zong & Dashui Yuan & Shengwei Deng & Reza Shahbazian-Yassar & C, 2022. "Oxo dicopper anchored on carbon nitride for selective oxidation of methane," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    2. Wenqing Zhang & Dawei Xi & Yihong Chen & Aobo Chen & Yawen Jiang & Hengjie Liu & Zeyu Zhou & Hui Zhang & Zhi Liu & Ran Long & Yujie Xiong, 2023. "Light-driven flow synthesis of acetic acid from methane with chemical looping," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    3. Ashwani Kumar & Viet Q. Bui & Jinsun Lee & Lingling Wang & Amol R. Jadhav & Xinghui Liu & Xiaodong Shao & Yang Liu & Jianmin Yu & Yosep Hwang & Huong T. D. Bui & Sara Ajmal & Min Gyu Kim & Seong-Gon K, 2021. "Moving beyond bimetallic-alloy to single-atom dimer atomic-interface for all-pH hydrogen evolution," Nature Communications, Nature, vol. 12(1), pages 1-10, December.
    4. Philipp Keller & Michael A. Reiter & Patrick Kiefer & Thomas Gassler & Lucas Hemmerle & Philipp Christen & Elad Noor & Julia A. Vorholt, 2022. "Generation of an Escherichia coli strain growing on methanol via the ribulose monophosphate cycle," Nature Communications, Nature, vol. 13(1), pages 1-13, December.
    5. Mohamedali, Mohanned & Ayodele, Olumide & Ibrahim, Hussameldin, 2020. "Challenges and prospects for the photocatalytic liquefaction of methane into oxygenated hydrocarbons," Renewable and Sustainable Energy Reviews, Elsevier, vol. 131(C).
    6. Xiao Sun & Xuanye Chen & Cong Fu & Qingbo Yu & Xu-Sheng Zheng & Fei Fang & Yuanxu Liu & Junfa Zhu & Wenhua Zhang & Weixin Huang, 2022. "Molecular oxygen enhances H2O2 utilization for the photocatalytic conversion of methane to liquid-phase oxygenates," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    7. Bin Li & Jiali Mu & Guifa Long & Xiangen Song & Ende Huang & Siyue Liu & Yao Wei & Fanfei Sun & Siquan Feng & Qiao Yuan & Yutong Cai & Jian Song & Wenrui Dong & Weiqing Zhang & Xueming Yang & Li Yan &, 2024. "Water-participated mild oxidation of ethane to acetaldehyde," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    8. Yang, Le & Lin, Hongju & Fang, Zhihao & Yang, Yanhui & Liu, Xiaohao & Ouyang, Gangfeng, 2023. "Recent advances on methane partial oxidation toward oxygenates under mild conditions," Renewable and Sustainable Energy Reviews, Elsevier, vol. 184(C).
    9. Huaning Jiang & Weiwei Yang & Mingquan Xu & Erqing Wang & Yi Wei & Wei Liu & Xiaokang Gu & Lixuan Liu & Qian Chen & Pengbo Zhai & Xiaolong Zou & Pulickel M. Ajayan & Wu Zhou & Yongji Gong, 2022. "Single atom catalysts in Van der Waals gaps," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    10. Xinxuan Duan & Qihao Sha & Pengsong Li & Tianshui Li & Guotao Yang & Wei Liu & Ende Yu & Daojin Zhou & Jinjie Fang & Wenxing Chen & Yizhen Chen & Lirong Zheng & Jiangwen Liao & Zeyu Wang & Yaping Li &, 2024. "Dynamic chloride ion adsorption on single iridium atom boosts seawater oxidation catalysis," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    11. Luning Chen & Pragya Verma & Kaipeng Hou & Zhiyuan Qi & Shuchen Zhang & Yi-Sheng Liu & Jinghua Guo & Vitalie Stavila & Mark D. Allendorf & Lansun Zheng & Miquel Salmeron & David Prendergast & Gabor A., 2022. "Reversible dehydrogenation and rehydrogenation of cyclohexane and methylcyclohexane by single-site platinum catalyst," Nature Communications, Nature, vol. 13(1), pages 1-9, December.

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