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Electrolyte design for lithium-ion batteries with a cobalt-free cathode and silicon oxide anode

Author

Listed:
  • Seongjae Ko

    (The University of Tokyo)

  • Xiao Han

    (The University of Tokyo)

  • Tatau Shimada

    (The University of Tokyo)

  • Norio Takenaka

    (The University of Tokyo)

  • Yuki Yamada

    (The University of Tokyo)

  • Atsuo Yamada

    (The University of Tokyo
    Sungkyunkwan University)

Abstract

Lithium-ion batteries (LIBs) to power electric vehicles play an increasingly important role in the transition to a carbon neutral transportation system. However, at present the chemistry of LIBs requires, among other elements, cobalt (Co), which will probably become scarce over time in addition to posing supply chain risks related to its single source, human rights and mining practices. To address this problem, we construct a LIB pairing a Co-free cathode with a silicon suboxide (SiOx) anode that possesses a high cut-off voltage of 4.9 V and sustains unprecedented 1,000 cycles. Underlying this favourable electrode combination is a rational electrolyte design based on 3.4 M LiFSI/FEMC featuring a shifted potential, which serves to aid formation of robust passivation layers on the anode and promote electrolyte stability against both reductive and oxidative degradations. Our electrolyte formulation offers a pathway towards both sustainable and high-performing LIBs, while the concept could be applied to other electrochemical energy technologies.

Suggested Citation

  • Seongjae Ko & Xiao Han & Tatau Shimada & Norio Takenaka & Yuki Yamada & Atsuo Yamada, 2023. "Electrolyte design for lithium-ion batteries with a cobalt-free cathode and silicon oxide anode," Nature Sustainability, Nature, vol. 6(12), pages 1705-1714, December.
    • Handle: RePEc:nat:natsus:v:6:y:2023:i:12:d:10.1038_s41893-023-01237-y
    DOI: 10.1038/s41893-023-01237-y
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    References listed on IDEAS

    as
    1. Qingquan Huang & Jiangxuan Song & Yue Gao & Daiwei Wang & Shuai Liu & Shufu Peng & Courtney Usher & Alan Goliaszewski & Donghai Wang, 2019. "Supremely elastic gel polymer electrolyte enables a reliable electrode structure for silicon-based anodes," Nature Communications, Nature, vol. 10(1), pages 1-7, December.
    2. Yuki Yamada & Jianhui Wang & Seongjae Ko & Eriko Watanabe & Atsuo Yamada, 2019. "Advances and issues in developing salt-concentrated battery electrolytes," Nature Energy, Nature, vol. 4(4), pages 269-280, April.
    3. Jie Xiao & Qiuyan Li & Yujing Bi & Mei Cai & Bruce Dunn & Tobias Glossmann & Jun Liu & Tetsuya Osaka & Ryuta Sugiura & Bingbin Wu & Jihui Yang & Ji-Guang Zhang & M. Stanley Whittingham, 2020. "Understanding and applying coulombic efficiency in lithium metal batteries," Nature Energy, Nature, vol. 5(8), pages 561-568, August.
    4. Jianhui Wang & Yuki Yamada & Keitaro Sodeyama & Ching Hua Chiang & Yoshitaka Tateyama & Atsuo Yamada, 2016. "Superconcentrated electrolytes for a high-voltage lithium-ion battery," Nature Communications, Nature, vol. 7(1), pages 1-9, November.
    5. Seongjae Ko & Tomohiro Obukata & Tatau Shimada & Norio Takenaka & Masanobu Nakayama & Atsuo Yamada & Yuki Yamada, 2022. "Electrode potential influences the reversibility of lithium-metal anodes," Nature Energy, Nature, vol. 7(12), pages 1217-1224, December.
    6. Arumugam Manthiram, 2020. "A reflection on lithium-ion battery cathode chemistry," Nature Communications, Nature, vol. 11(1), pages 1-9, December.
    7. William E. Gent & Grace M. Busse & Kurt Z. House, 2022. "The predicted persistence of cobalt in lithium-ion batteries," Nature Energy, Nature, vol. 7(12), pages 1132-1143, December.
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    Cited by:

    1. Norio Takenaka & Seongjae Ko & Atsushi Kitada & Atsuo Yamada, 2024. "Liquid Madelung energy accounts for the huge potential shift in electrochemical systems," Nature Communications, Nature, vol. 15(1), pages 1-8, December.

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