IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v15y2024i1d10.1038_s41467-024-52692-w.html
   My bibliography  Save this article

Exploring the influence of cell configurations on Cu catalyst reconstruction during CO2 electroreduction

Author

Listed:
  • Woong Choi

    (Korea Institute of Science and Technology
    Gyeongsang National University)

  • Younghyun Chae

    (Korea Institute of Science and Technology
    University of Science and Technology (UST))

  • Ershuai Liu

    (Lawrence Berkeley National Laboratory)

  • Dongjin Kim

    (Korea Institute of Science and Technology
    Korea University)

  • Walter S. Drisdell

    (Lawrence Berkeley National Laboratory)

  • Hyung-suk Oh

    (Korea Institute of Science and Technology
    Sungkyunkwan University (SKKU))

  • Jai Hyun Koh

    (Korea Institute of Science and Technology
    University of Science and Technology (UST))

  • Dong Ki Lee

    (Korea Institute of Science and Technology
    Yonsei University
    Korea University)

  • Ung Lee

    (Korea Institute of Science and Technology
    University of Science and Technology (UST)
    Korea University)

  • Da Hye Won

    (Korea Institute of Science and Technology
    University of Science and Technology (UST)
    Kyung Hee University)

Abstract

Membrane electrode assembly (MEA) cells incorporating Cu catalysts are effective for generating C2+ chemicals via the CO2 reduction reaction (CO2RR). However, the impact of MEA configuration on the inevitable reconstruction of Cu catalysts during CO2RR remains underexplored, despite its considerable potential to affect CO2RR efficacy. Herein, we demonstrate that MEA cells prompt a unique reconstruction of Cu, in contrast to H-type cells, which subsequently influences CO2RR outcomes. Utilizing three Cu-based catalysts, specifically engineered with different nanostructures, we identify contrasting selectivity trends in the production of C2+ chemicals between H-type and MEA cells. Operando X-ray absorption spectroscopy, alongside ex-situ analyses in both cell types, indicates that MEA cells facilitate the reduction of Cu2O, resulting in altered Cu surfaces compared to those in H-type cells. Time-resolved CO2RR studies, supported by Operando analysis, further highlight that significant Cu reconstruction within MEA cells is a primary factor leading to the deactivation of CO2RR into C2+ chemicals.

Suggested Citation

  • Woong Choi & Younghyun Chae & Ershuai Liu & Dongjin Kim & Walter S. Drisdell & Hyung-suk Oh & Jai Hyun Koh & Dong Ki Lee & Ung Lee & Da Hye Won, 2024. "Exploring the influence of cell configurations on Cu catalyst reconstruction during CO2 electroreduction," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-52692-w
    DOI: 10.1038/s41467-024-52692-w
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-024-52692-w
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-024-52692-w?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Jonggeol Na & Bora Seo & Jeongnam Kim & Chan Woo Lee & Hyunjoo Lee & Yun Jeong Hwang & Byoung Koun Min & Dong Ki Lee & Hyung-Suk Oh & Ung Lee, 2019. "General technoeconomic analysis for electrochemical coproduction coupling carbon dioxide reduction with organic oxidation," Nature Communications, Nature, vol. 10(1), pages 1-13, December.
    2. Ruiz-López, Estela & Gandara-Loe, Jesús & Baena-Moreno, Francisco & Reina, Tomas Ramirez & Odriozola, José Antonio, 2022. "Electrocatalytic CO2 conversion to C2 products: Catalysts design, market perspectives and techno-economic aspects," Renewable and Sustainable Energy Reviews, Elsevier, vol. 161(C).
    3. Jianfeng Huang & Nicolas Hörmann & Emad Oveisi & Anna Loiudice & Gian Luca De Gregorio & Oliviero Andreussi & Nicola Marzari & Raffaella Buonsanti, 2018. "Potential-induced nanoclustering of metallic catalysts during electrochemical CO2 reduction," Nature Communications, Nature, vol. 9(1), pages 1-9, December.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Kaili Yao & Jun Li & Adnan Ozden & Haibin Wang & Ning Sun & Pengyu Liu & Wen Zhong & Wei Zhou & Jieshu Zhou & Xi Wang & Hanqi Liu & Yongchang Liu & Songhua Chen & Yongfeng Hu & Ziyun Wang & David Sint, 2024. "In situ copper faceting enables efficient CO2/CO electrolysis," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    2. Xin, Liyong & Yu, Wei & Liu, Chao & Liu, Lang & Wang, Shukun & Li, Xiaoxiao & Liu, Yu, 2023. "Thermal stability of a mixed working fluid (R513A) for organic Rankine cycle," Energy, Elsevier, vol. 263(PF).
    3. Jun Qi & Yadong Du & Qi Yang & Na Jiang & Jiachun Li & Yi Ma & Yangjun Ma & Xin Zhao & Jieshan Qiu, 2023. "Energy-saving and product-oriented hydrogen peroxide electrosynthesis enabled by electrochemistry pairing and product engineering," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    4. Jing Xue & Xue Dong & Chunxiao Liu & Jiawei Li & Yizhou Dai & Weiqing Xue & Laihao Luo & Yuan Ji & Xiao Zhang & Xu Li & Qiu Jiang & Tingting Zheng & Jianping Xiao & Chuan Xia, 2024. "Turning copper into an efficient and stable CO evolution catalyst beyond noble metals," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    5. Shengqin Liu & Yangxin Jin & Shuquan Huang & Qi Zhu & Shan Shao & Jason Chun-Ho Lam, 2024. "One-pot redox cascade paired electrosynthesis of gamma-butyrolactone from furoic acid," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    6. Shikai Liu & Yuheng Li & Di Wang & Shibo Xi & Haoming Xu & Yulin Wang & Xinzhe Li & Wenjie Zang & Weidong Liu & Mengyao Su & Katherine Yan & Adam C. Nielander & Andrew B. Wong & Jiong Lu & Thomas F. J, 2024. "Alkali cation-induced cathodic corrosion in Cu electrocatalysts," Nature Communications, Nature, vol. 15(1), pages 1-14, December.
    7. Yuyang Pan & Huiyan Zhang & Bowen Zhang & Feng Gong & Jianyong Feng & Huiting Huang & Srinivas Vanka & Ronglei Fan & Qi Cao & Mingrong Shen & Zhaosheng Li & Zhigang Zou & Rui Xiao & Sheng Chu, 2023. "Renewable formate from sunlight, biomass and carbon dioxide in a photoelectrochemical cell," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    8. Fenghui Ye & Shishi Zhang & Qingqing Cheng & Yongde Long & Dong Liu & Rajib Paul & Yunming Fang & Yaqiong Su & Liangti Qu & Liming Dai & Chuangang Hu, 2023. "The role of oxygen-vacancy in bifunctional indium oxyhydroxide catalysts for electrochemical coupling of biomass valorization with CO2 conversion," Nature Communications, Nature, vol. 14(1), pages 1-14, December.
    9. Ruiz-López, Estela & Gandara-Loe, Jesús & Baena-Moreno, Francisco & Reina, Tomas Ramirez & Odriozola, José Antonio, 2022. "Electrocatalytic CO2 conversion to C2 products: Catalysts design, market perspectives and techno-economic aspects," Renewable and Sustainable Energy Reviews, Elsevier, vol. 161(C).
    10. Ahmed M. Abdellah & Fatma Ismail & Oliver W. Siig & Jie Yang & Carmen M. Andrei & Liza-Anastasia DiCecco & Amirhossein Rakhsha & Kholoud E. Salem & Kathryn Grandfield & Nabil Bassim & Robert Black & G, 2024. "Impact of palladium/palladium hydride conversion on electrochemical CO2 reduction via in-situ transmission electron microscopy and diffraction," Nature Communications, Nature, vol. 15(1), pages 1-15, December.
    11. Pribyl-Kranewitter, B. & Beard, A. & Gîjiu, C.L. & Dinculescu, D. & Schmidt, T.J., 2022. "Influence of low-temperature electrolyser design on economic and environmental potential of CO and HCOOH production: A techno-economic assessment," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    12. Young-Jin Ko & Chulwan Lim & Junyoung Jin & Min Gyu Kim & Ji Yeong Lee & Tae-Yeon Seong & Kwan-Young Lee & Byoung Koun Min & Jae-Young Choi & Taegeun Noh & Gyu Weon Hwang & Woong Hee Lee & Hyung-Suk O, 2024. "Extrinsic hydrophobicity-controlled silver nanoparticles as efficient and stable catalysts for CO2 electrolysis," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    13. Hugo-Pieter Iglesias van Montfort & Mengran Li & Erdem Irtem & Maryam Abdinejad & Yuming Wu & Santosh K. Pal & Mark Sassenburg & Davide Ripepi & Siddhartha Subramanian & Jasper Biemolt & Thomas E. Ruf, 2023. "Non-invasive current collectors for improved current-density distribution during CO2 electrolysis on super-hydrophobic electrodes," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    14. Xiaoyi Jiang & Le Ke & Kai Zhao & Xiaoyu Yan & Hongbo Wang & Xiaojuan Cao & Yuchen Liu & Lingjiao Li & Yifei Sun & Zhiping Wang & Dai Dang & Ning Yan, 2024. "Integrating hydrogen utilization in CO2 electrolysis with reduced energy loss," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    15. Li Zhang & Xiaoju Yang & Qing Yuan & Zhiming Wei & Jie Ding & Tianshu Chu & Chao Rong & Qiao Zhang & Zhenkun Ye & Fu-Zhen Xuan & Yueming Zhai & Bowei Zhang & Xuan Yang, 2023. "Elucidating the structure-stability relationship of Cu single-atom catalysts using operando surface-enhanced infrared absorption spectroscopy," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    16. Kezia Megagita Gerby Langie & Kyungjae Tak & Changsoo Kim & Hee Won Lee & Kwangho Park & Dongjin Kim & Wonsang Jung & Chan Woo Lee & Hyung-Suk Oh & Dong Ki Lee & Jai Hyun Koh & Byoung Koun Min & Da Hy, 2022. "Toward economical application of carbon capture and utilization technology with near-zero carbon emission," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    17. Kannangara, Miyuru & Shadbahr, Jalil & Vasudev, Madhav & Yang, Jianjun & Zhang, Lei & Bensebaa, Farid & Lees, Eric & Simpson, Grace & Berlinguette, Curtis & Cai, Jingjing & Nishikawa, Emily & McCoy, S, 2022. "A standardized methodology for economic and carbon footprint assessment of CO2 to transport fuels: Comparison of novel bicarbonate electrolysis with competing pathways," Applied Energy, Elsevier, vol. 325(C).
    18. Ke Xie & Adnan Ozden & Rui Kai Miao & Yuhang Li & David Sinton & Edward H. Sargent, 2022. "Eliminating the need for anodic gas separation in CO2 electroreduction systems via liquid-to-liquid anodic upgrading," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    19. Chen, Jiateng & Xu, Le & Shen, Boxiong, 2024. "Recent advances in tandem electrocatalysis of carbon dioxide: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 199(C).
    20. Philipp Grosse & Aram Yoon & Clara Rettenmaier & Antonia Herzog & See Wee Chee & Beatriz Roldan Cuenya, 2021. "Dynamic transformation of cubic copper catalysts during CO2 electroreduction and its impact on catalytic selectivity," Nature Communications, Nature, vol. 12(1), pages 1-11, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-52692-w. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.