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Boosting oxygen evolution reaction by FeNi hydroxide-organic framework electrocatalyst toward alkaline water electrolyzer

Author

Listed:
  • Yuzhen Chen

    (Yangzhou University)

  • Qiuhong Li

    (Yangzhou University)

  • Yuxing Lin

    (Xiamen University)

  • Jiao Liu

    (Yangzhou University)

  • Jing Pan

    (Yangzhou University)

  • Jingguo Hu

    (Yangzhou University)

  • Xiaoyong Xu

    (Yangzhou University)

Abstract

The oxygen evolution reaction plays a vital role in modern energy conversion and storage, and developing cost-efficient oxygen evolution reaction catalysts with industrially relevant activity and durability is highly desired but still challenging. Here, we report an efficient and durable FeNi hydroxide organic framework nanosheet array catalyst that competently affords long-term oxygen evolution reaction at industrial-grade current densities in alkaline electrolyte. The desirable high-intensity performance is attributed to three aspects as follows. First, two-dimensional nanosheet porous arrays with maximum specific surface facilitate mass/charge transfer to accommodate high-current-density catalysis. Second, in situ derived FeNi hydroxide motifs offer bimetallic synergistic catalysis centers with high intrinsic activity. Third, carboxyl ligands alleviate metal oxidation favorable for charge tolerability against peroxidation dissolution under strong polarization. As a result, this catalyst requires an overpotential of only 280 mV to deliver high current density up to 1 A/cm2 with long durability over 1000 h. Moreover, an alkaline water electrolyzer with this catalyst alternative demonstrates an increased economic effectiveness compared to commercial levels at present.

Suggested Citation

  • Yuzhen Chen & Qiuhong Li & Yuxing Lin & Jiao Liu & Jing Pan & Jingguo Hu & Xiaoyong Xu, 2024. "Boosting oxygen evolution reaction by FeNi hydroxide-organic framework electrocatalyst toward alkaline water electrolyzer," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
  • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-51521-4
    DOI: 10.1038/s41467-024-51521-4
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    References listed on IDEAS

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