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Stabilizing NiFe sites by high-dispersity of nanosized and anionic Cr species toward durable seawater oxidation

Author

Listed:
  • Zhengwei Cai

    (Shandong Normal University)

  • Jie Liang

    (University of Electronic Science and Technology of China)

  • Zixiao Li

    (University of Electronic Science and Technology of China)

  • Tingyu Yan

    (Harbin Normal University)

  • Chaoxin Yang

    (Shandong Normal University)

  • Shengjun Sun

    (Shandong Normal University)

  • Meng Yue

    (Shandong Normal University)

  • Xuwei Liu

    (University of Electronic Science and Technology of China)

  • Ting Xie

    (University of Electronic Science and Technology of China)

  • Yan Wang

    (University of Electronic Science and Technology of China)

  • Tingshuai Li

    (University of Electronic Science and Technology of China)

  • Yongsong Luo

    (Shandong Normal University)

  • Dongdong Zheng

    (Shandong Normal University)

  • Qian Liu

    (Chengdu University)

  • Jingxiang Zhao

    (Harbin Normal University)

  • Xuping Sun

    (Shandong Normal University
    University of Electronic Science and Technology of China
    Sichuan University)

  • Bo Tang

    (Shandong Normal University
    Laoshan Laboratory)

Abstract

Electrocatalytic H2 production from seawater, recognized as a promising technology utilizing offshore renewables, faces challenges from chloride-induced reactions and corrosion. Here, We introduce a catalytic surface where OH– dominates over Cl– in adsorption and activation, which is crucial for O2 production. Our NiFe-based anode, enhanced by nearby Cr sites, achieves low overpotentials and selective alkaline seawater oxidation. It outperforms the RuO2 counterpart in terms of lifespan in scaled-up stacks, maintaining stability for over 2500 h in three-electrode tests. Ex situ/in situ analyses reveal that Cr(III) sites enrich OH–, while Cl– is repelled by Cr(VI) sites, both of which are well-dispersed and close to NiFe, enhancing charge transfer and overall electrode performance. Such multiple effects fundamentally boost the activity, selectively, and chemical stability of the NiFe-based electrode. This development marks a significant advance in creating durable, noble-metal-free electrodes for alkaline seawater electrolysis, highlighting the importance of well-distributed catalytic sites.

Suggested Citation

  • Zhengwei Cai & Jie Liang & Zixiao Li & Tingyu Yan & Chaoxin Yang & Shengjun Sun & Meng Yue & Xuwei Liu & Ting Xie & Yan Wang & Tingshuai Li & Yongsong Luo & Dongdong Zheng & Qian Liu & Jingxiang Zhao , 2024. "Stabilizing NiFe sites by high-dispersity of nanosized and anionic Cr species toward durable seawater oxidation," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
  • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-51130-1
    DOI: 10.1038/s41467-024-51130-1
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    References listed on IDEAS

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