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Real-space imaging for discovering a rotated node structure in metal-organic framework

Author

Listed:
  • Jiale Feng

    (Soochow University
    Soochow University)

  • Zhipeng Feng

    (Soochow University
    Soochow University)

  • Liang Xu

    (Soochow University
    Soochow University)

  • Haibing Meng

    (Taiyuan University of Technology)

  • Xiao Chen

    (Tsinghua University)

  • Mengmeng Ma

    (Soochow University
    Soochow University)

  • Lei Wang

    (Soochow University
    Soochow University)

  • Bin Song

    (Soochow University
    Soochow University)

  • Xuan Tang

    (East China University of Science and Technology)

  • Sheng Dai

    (East China University of Science and Technology)

  • Fei Wei

    (Tsinghua University)

  • Tao Cheng

    (Soochow University
    Soochow University)

  • Boyuan Shen

    (Soochow University
    Soochow University)

Abstract

Resolving the detailed structures of metal organic frameworks is of great significance for understanding their structure-property relation. Real-space imaging methods could exhibit superiority in revealing not only the local structure but also the bulk symmetry of these complex porous materials, compared to reciprocal-space diffraction methods, despite the technical challenges. Here we apply a low-dose imaging technique to clearly resolve the atomic structures of building units in a metal-organic framework, MIL-125. An unexpected node structure is discovered by directly imaging the rotation of Ti-O nodes, different from the unrotated structure predicted by previous X-ray diffraction. The imaged structure and symmetry can be confirmed by the structural simulations and energy calculations. Then, the distribution of node rotation from the edge to the center of a MIL-125 particle is revealed by the image analysis of Ti-O rotation. The related defects and surface terminations in MIL-125 are also investigated in the real-space images. These results not only unraveled the node symmetry in MIL-125 with atomic resolution but also inspired further studies on discovering more unpredicted structural changes in other porous materials by real-space imaging methods.

Suggested Citation

  • Jiale Feng & Zhipeng Feng & Liang Xu & Haibing Meng & Xiao Chen & Mengmeng Ma & Lei Wang & Bin Song & Xuan Tang & Sheng Dai & Fei Wei & Tao Cheng & Boyuan Shen, 2024. "Real-space imaging for discovering a rotated node structure in metal-organic framework," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
  • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-51384-9
    DOI: 10.1038/s41467-024-51384-9
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    References listed on IDEAS

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