IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v14y2023i1d10.1038_s41467-023-40590-6.html
   My bibliography  Save this article

Imaging the dynamic influence of functional groups on metal-organic frameworks

Author

Listed:
  • Boyang Liu

    (Tsinghua University
    Nanjing University of Science and Technology)

  • Xiao Chen

    (Tsinghua University
    Ordos Laboratory)

  • Ning Huang

    (Tsinghua University
    Sinopec Economics and Development Research Institute Company Limited)

  • Shaoxiong Liu

    (Tsinghua University)

  • Yu Wang

    (Tsinghua University)

  • Xiaocheng Lan

    (Tsinghua University)

  • Fei Wei

    (Tsinghua University)

  • Tiefeng Wang

    (Tsinghua University)

Abstract

Metal-organic frameworks (MOFs) with different functional groups have wide applications, while the understanding of functionalization influences remains insufficient. Previous researches focused on the static changes in electronic structure or chemical environment, while it is unclear in the aspect of dynamic influence, especially in the direct imaging of dynamic changes after functionalization. Here we use integrated differential phase contrast scanning transmission electron microscopy (iDPC-STEM) to directly ‘see’ the rotation properties of benzene rings in the linkers of UiO-66, and observe the high correlation between local rigidity and the functional groups on the organic linkers. The rigidity is then correlated to the macroscopic properties of CO2 uptake, indicating that functionalization can change the capability through not only static electronic effects, but also dynamic rotation properties. To the best of our knowledge this is the first example of a technique to directly image the rotation properties of linkers in MOFs, which provides an approach to study the local flexibility and paves the way for potential applications in capturing, separation and molecular machine.

Suggested Citation

  • Boyang Liu & Xiao Chen & Ning Huang & Shaoxiong Liu & Yu Wang & Xiaocheng Lan & Fei Wei & Tiefeng Wang, 2023. "Imaging the dynamic influence of functional groups on metal-organic frameworks," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-40590-6
    DOI: 10.1038/s41467-023-40590-6
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-023-40590-6
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-023-40590-6?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Sheng Zhou & Osama Shekhah & Adrian Ramírez & Pengbo Lyu & Edy Abou-Hamad & Jiangtao Jia & Jiantang Li & Prashant M. Bhatt & Zhiyuan Huang & Hao Jiang & Tian Jin & Guillaume Maurin & Jorge Gascon & Mo, 2022. "Asymmetric pore windows in MOF membranes for natural gas valorization," Nature, Nature, vol. 606(7915), pages 706-712, June.
    2. Boyuan Shen & Xiao Chen & Kui Shen & Hao Xiong & Fei Wei, 2020. "Imaging the node-linker coordination in the bulk and local structures of metal-organic frameworks," Nature Communications, Nature, vol. 11(1), pages 1-8, December.
    3. Boyuan Shen & Huiqiu Wang & Hao Xiong & Xiao Chen & Eric G. T. Bosch & Ivan Lazić & Weizhong Qian & Fei Wei, 2022. "Atomic imaging of zeolite-confined single molecules by electron microscopy," Nature, Nature, vol. 607(7920), pages 703-707, July.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Mengmeng Ma & Xuliang Zhang & Xiao Chen & Hao Xiong & Liang Xu & Tao Cheng & Jianyu Yuan & Fei Wei & Boyuan Shen, 2023. "In situ imaging of the atomic phase transition dynamics in metal halide perovskites," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    2. Linjing Tong & Siming Huang & Yujian Shen & Suya Liu & Xiaomin Ma & Fang Zhu & Guosheng Chen & Gangfeng Ouyang, 2022. "Atomically unveiling the structure-activity relationship of biomacromolecule-metal-organic frameworks symbiotic crystal," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    3. Ying Wang & Vinod K. Paidi & Weizhen Wang & Yong Wang & Guangri Jia & Tingyu Yan & Xiaoqiang Cui & Songhua Cai & Jingxiang Zhao & Kug-Seung Lee & Lawrence Yoon Suk Lee & Kwok-Yin Wong, 2024. "Spatial engineering of single-atom Fe adjacent to Cu-assisted nanozymes for biomimetic O2 activation," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    4. Yu Zhou & Xinyu Zhang & Guan Sheng & Shengda Wang & Muqing Chen & Guilin Zhuang & Yihan Zhu & Pingwu Du, 2023. "A metal-free photoactive nitrogen-doped carbon nanosolenoid with broad absorption in visible region for efficient photocatalysis," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    5. Guusje Delen & Matteo Monai & Katarina Stančiaková & Bettina Baumgartner & Florian Meirer & Bert M. Weckhuysen, 2023. "Structure sensitivity in gas sorption and conversion on metal-organic frameworks," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    6. Jiyu Cui & Fang Wu & Wen Zhang & Lifeng Yang & Jianbo Hu & Yin Fang & Peng Ye & Qiang Zhang & Xian Suo & Yiming Mo & Xili Cui & Huajun Chen & Huabin Xing, 2023. "Direct prediction of gas adsorption via spatial atom interaction learning," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    7. Huiqiu Wang & Boyuan Shen & Xiao Chen & Hao Xiong & Hongmei Wang & Wenlong Song & Chaojie Cui & Fei Wei & Weizhong Qian, 2022. "Modulating inherent lewis acidity at the intergrowth interface of mortise-tenon zeolite catalyst," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    8. JianHao Qian & HengAn Wu & FengChao Wang, 2023. "A generalized Knudsen theory for gas transport with specular and diffuse reflections," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    9. Tanmoy Maity & Pratibha Malik & Sumit Bawari & Soumya Ghosh & Jagannath Mondal & Ritesh Haldar, 2023. "Chemically routed interpore molecular diffusion in metal-organic framework thin films," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    10. Shanshan Hong & Maria Vincenzo & Alberto Tiraferri & Erica Bertozzi & Radosław Górecki & Bambar Davaasuren & Xiang Li & Suzana P. Nunes, 2024. "Precision ion separation via self-assembled channels," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    11. Xinxing Peng & Philipp M. Pelz & Qiubo Zhang & Peican Chen & Lingyun Cao & Yaqian Zhang & Hong-Gang Liao & Haimei Zheng & Cheng Wang & Shi-Gang Sun & Mary C. Scott, 2022. "Observation of formation and local structures of metal-organic layers via complementary electron microscopy techniques," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    12. Hai Liu & Xinxi Huang & Yang Wang & Baian Kuang & Wanbin Li, 2024. "Nanowire-assisted electrochemical perforation of graphene oxide nanosheets for molecular separation," Nature Communications, Nature, vol. 15(1), pages 1-11, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-40590-6. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.