IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v15y2022i7p2437-d780033.html
   My bibliography  Save this article

A Perylenediimide-Based Zinc-Coordination Polymer for Photosensitized Singlet-Oxygen Generation

Author

Listed:
  • Simon N. Deger

    (Chair of Inorganic and Metal-Organic Chemistry, Catalysis Research Center, Ernst-Otto-Fischer-Straße 1, 85748 Garching, Germany
    These authors contributed equally to this work.)

  • Sebastian J. Weishäupl

    (Chair of Inorganic and Metal-Organic Chemistry, Catalysis Research Center, Ernst-Otto-Fischer-Straße 1, 85748 Garching, Germany
    These authors contributed equally to this work.)

  • Alexander Pöthig

    (Chair of Inorganic and Metal-Organic Chemistry, Catalysis Research Center, Ernst-Otto-Fischer-Straße 1, 85748 Garching, Germany)

  • Roland A. Fischer

    (Chair of Inorganic and Metal-Organic Chemistry, Catalysis Research Center, Ernst-Otto-Fischer-Straße 1, 85748 Garching, Germany)

Abstract

In the face of anthropogenic global warming the design and synthesis of materials, which enable energy transfer processes using sunlight as an energy source, are of high interest. Perylenediimides are a highly absorbing class of chromophores suitable for sunlight absorption and conversion. Therefore, metal–organic frameworks (MOFs) and coordination polymers (CPs) with incorporated organic perylene chromophores are highly interesting materials both for applied, but also fundamental, photophysical research. MOFs/CPs have the advantage of a modular adjustability of interchromophoric distances and angles, and the choice of metal nodes can be used to further tune the material towards the desired photophysical properties. In the present paper, we present a study using a reported organic perylenediimide (PDI) chromophore (H 2 tpdb) as a linker to be incorporated into coordination polymer and test towards applicability within the photochemical 1 O 2 generation. In detail, a novel zinc 2D -coordination polymer Zn(tpdb)(DMF) 3 is reported, which is synthesized using a solvothermal synthesis with Zn(NO 3 ) 2 and a ditopic organic perylene linker. Both the linker and Zn-CP are fully characterized, including SC-XRD, showing a strong aggregation of tightly packed chromophores in the solid state. The photophysical properties are examined and discussed, including the observed shifts within the absorption spectra of the CP are compared to the linker in solution. These shifts are mainly attributed to the for PDIs known H-type aggregation and an additional charge transfer in the framework structure, causing a limited quantum yield of the emission. Finally, the photosensitization of triplet oxygen to singlet oxygen using 1,3-diphenylisobenzofurane (DBPF) as a trapping agent is investigated both for the free linker and the Zn-CP, showing that the perylene chromophore is an efficient photosensitizer and its activity can, in principle, be retained after its incorporation in the coordination polymer.

Suggested Citation

  • Simon N. Deger & Sebastian J. Weishäupl & Alexander Pöthig & Roland A. Fischer, 2022. "A Perylenediimide-Based Zinc-Coordination Polymer for Photosensitized Singlet-Oxygen Generation," Energies, MDPI, vol. 15(7), pages 1-12, March.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:7:p:2437-:d:780033
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/15/7/2437/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/15/7/2437/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Hailian Li & Mohamed Eddaoudi & M. O'Keeffe & O. M. Yaghi, 1999. "Design and synthesis of an exceptionally stable and highly porous metal-organic framework," Nature, Nature, vol. 402(6759), pages 276-279, November.
    2. Theresa Eder & Thomas Stangl & Max Gmelch & Klaas Remmerssen & Dirk Laux & Sigurd Höger & John M. Lupton & Jan Vogelsang, 2017. "Switching between H- and J-type electronic coupling in single conjugated polymer aggregates," Nature Communications, Nature, vol. 8(1), pages 1-11, December.
    3. Stefanie Herbst & Bartolome Soberats & Pawaret Leowanawat & Matthias Stolte & Matthias Lehmann & Frank Würthner, 2018. "Self-assembly of multi-stranded perylene dye J-aggregates in columnar liquid-crystalline phases," Nature Communications, Nature, vol. 9(1), pages 1-9, December.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Li, Lirong & Jung, Han Sol & Lee, Jae Won & Kang, Yong Tae, 2022. "Review on applications of metal–organic frameworks for CO2 capture and the performance enhancement mechanisms," Renewable and Sustainable Energy Reviews, Elsevier, vol. 162(C).
    2. Choudhary, Ram Bilash & Ansari, Sarfaraz & Majumder, Mandira, 2021. "Recent advances on redox active composites of metal-organic framework and conducting polymers as pseudocapacitor electrode material," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    3. Yun Fan & Yu Shen & Jia Zhang & Xinglong Zhang & Zeqi Zhang & Hongfeng Li & Yong Peng & Jiena Weng & Ruijie Xie & Wenlei Zhang & Yu Han & Yawen Xiao & Suoying Zhang & Bing Zheng & Hao-Li Zhang & Sheng, 2024. "Wedging crystals to fabricate crystalline framework nanosheets via mechanochemistry," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    4. Qingju Wang & Jianbo Hu & Lifeng Yang & Zhaoqiang Zhang & Tian Ke & Xili Cui & Huabin Xing, 2022. "One-step removal of alkynes and propadiene from cracking gases using a multi-functional molecular separator," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    5. Xinhe Ye & Lai-Hon Chung & Kedi Li & Saili Zheng & Yan-Lung Wong & Zihao Feng & Yonghe He & Dandan Chu & Zhengtao Xu & Lin Yu & Jun He, 2022. "Organic radicals stabilization above 300 °C in Eu-based coordination polymers for solar steam generation," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    6. Tingting Lian & Li Xu & Diana Piankova & Jin-Lin Yang & Nadezda V. Tarakina & Yang Wang & Markus Antonietti, 2024. "Metal-organic framework derived crystalline nanocarbon for Fenton-like reaction," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    7. Usman, Muhammad R., 2022. "Hydrogen storage methods: Review and current status," Renewable and Sustainable Energy Reviews, Elsevier, vol. 167(C).
    8. Xueqiao Mei & Han Yuan & Chunhu Li, 2023. "Study on the MOF Frame Pt-TiO 2 Hybrid Photocatalyst and Its Photocatalytic Performance," Sustainability, MDPI, vol. 15(2), pages 1-14, January.
    9. Ahmed Hussain Jawhari, 2022. "Novel Nanomaterials for Hydrogen Production and Storage: Evaluating the Futurity of Graphene/Graphene Composites in Hydrogen Energy," Energies, MDPI, vol. 15(23), pages 1-16, November.
    10. Vasileios Ntouros & Ioannis Kousis & Anna Laura Pisello & Margarita Niki Assimakopoulos, 2022. "Binding Materials for MOF Monolith Shaping Processes: A Review towards Real Life Application," Energies, MDPI, vol. 15(4), pages 1-21, February.
    11. Lixia Wu & Yu Zhu & Jing Yuan & Xiaozhong Guo & Qianfeng Zhang, 2024. "Advances in Adsorption, Absorption, and Catalytic Materials for VOCs Generated in Typical Industries," Energies, MDPI, vol. 17(8), pages 1-30, April.
    12. Danxia Liu & Xiaolong Yang & Lin Zhang & Yiyan Tang & Huijun He & Meina Liang & Zhihong Tu & Hongxiang Zhu, 2022. "Immobilization of Biomass Materials for Removal of Refractory Organic Pollutants from Wastewater," IJERPH, MDPI, vol. 19(21), pages 1-22, October.
    13. Wang, Pengfei & Teng, Ying & Zhu, Jinlong & Bao, Wancheng & Han, Songbai & Li, Yun & Zhao, Yusheng & Xie, Heping, 2022. "Review on the synergistic effect between metal–organic frameworks and gas hydrates for CH4 storage and CO2 separation applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 167(C).
    14. Guoli Zhang & Jian Zhang & Yu Tao & Fuwei Gan & Geyu Lin & Juncong Liang & Chengshuo Shen & Yuebiao Zhang & Huibin Qiu, 2024. "Facile fabrication of recyclable robust noncovalent porous crystals from low-symmetry helicene derivative," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    15. Xinxing Peng & Philipp M. Pelz & Qiubo Zhang & Peican Chen & Lingyun Cao & Yaqian Zhang & Hong-Gang Liao & Haimei Zheng & Cheng Wang & Shi-Gang Sun & Mary C. Scott, 2022. "Observation of formation and local structures of metal-organic layers via complementary electron microscopy techniques," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    16. Asfahan, Hafiz M. & Sultan, Muhammad & Miyazaki, Takahiko & Saha, Bidyut B. & Askalany, Ahmed A. & Shahzad, Muhammad W. & Worek, William, 2022. "Recent development in adsorption desalination: A state of the art review," Applied Energy, Elsevier, vol. 328(C).
    17. Jyoti Shanker Pandey & Nicolas von Solms, 2022. "Metal–Organic Frameworks and Gas Hydrate Synergy: A Pandora’s Box of Unanswered Questions and Revelations," Energies, MDPI, vol. 16(1), pages 1-30, December.
    18. Mohammed, Ramy H. & Rezk, Ahmed & Askalany, Ahmed & Ali, Ehab S. & Zohir, A.E. & Sultan, Muhammad & Ghazy, Mohamed & Abdelkareem, Mohammad Ali & Olabi, A.G., 2021. "Metal-organic frameworks in cooling and water desalination: Synthesis and application," Renewable and Sustainable Energy Reviews, Elsevier, vol. 149(C).
    19. Daniil Salionov & Olesya O. Semivrazhskaya & Nicola P. M. Casati & Marco Ranocchiari & Saša Bjelić & René Verel & Jeroen A. Bokhoven & Vitaly L. Sushkevich, 2022. "Unraveling the molecular mechanism of MIL-53(Al) crystallization," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    20. Jiale Feng & Zhipeng Feng & Liang Xu & Haibing Meng & Xiao Chen & Mengmeng Ma & Lei Wang & Bin Song & Xuan Tang & Sheng Dai & Fei Wei & Tao Cheng & Boyuan Shen, 2024. "Real-space imaging for discovering a rotated node structure in metal-organic framework," Nature Communications, Nature, vol. 15(1), pages 1-8, December.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:15:y:2022:i:7:p:2437-:d:780033. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.